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US5084067A
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3-substituted para-amino phenols and their use as oxidation dye precursors in compositions for dyeing kerafinous fibers
Assignee: L' O R E A L
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Filing: 1989-02-28
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Granted: 1992-01-28
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Expires: 2009-02-28
Abstract
Abstract 3-Substituted para-aminophenols of general formula: <IMAGE> (I) where X=H, halogen; Y=O-, -S-; R=alkyl, hydroxyalkyl, C1-4 aminoalkyl or C3-C6 polyhydroxyalkyl; with the proviso that, when X=H, R is not methyl, and when X=H and Y=O, R is not ethyl; process for preparing them, intermediate compounds of formula: <IMAGE> (II) where X1=halogen, Y and R have the meaning stated above; with the proviso that, when Y=O, R is not methyl, and when R=aminoalkyl, X1 can also denote hydrogen; dyeing compositions containing one or more compounds of formula (I), and a process for dyeing human hair.
Inventors
- 👤 Alex Junino
- 👤 Alain Genet
- 👤 Gerard Lang
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 02:51
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/415; A61Q; A61Q5/00; A61Q5/10; C; C07; C07C; C07C205/00; C07C205/27; C07C205/35; C07C205/36; C07C205/37; C07C217/00; C07C217/78; C07C217/80; C07C217/82; C07C217/84; C07C323/00; C07C323/23; C07C323/31; C07C323/33; C07C323/35; C07C323/36
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
45 words
3-Substituted para-aminophenols of the formula: ##STR14## in which X denotes a hydrogen or halogen atoms, Y denotes an oxygen or sulphur atom and R denotes a C 1-4 hydroxyalkyl, C 3 -C 6 polyhydroxyalkyl or C 1 -C 4 aminoalkyl radical, and the corresponding salts.
Claim 2
Dependent Claim
45 words
3-Substituted para-aminophenols of the formula: ##STR14## in which X denotes a hydrogen or halogen atoms, Y denotes an oxygen or sulphur atom and R denotes a C 1-4 hydroxyalkyl, C 3 -C 6 polyhydroxyalkyl or C 1 -C 4 aminoalkyl radical, and the corresponding salts.
Claim 3
Dependent Claim
75 words
3-Substituted para-aminophenols of formula (I) according to claim 1, wherein X denotes a hydrogen or halogen atom, Y denotes an oxygen or sulphur atom and R denotes a C 1 -C 4 hydroxyalkyl, C 3 -C 6 polyhydroxyalkyl or C 1 -C 4 aminoalkyl radical, with the proviso that, when X denotes a hydrogen atom, R denotes a C 1 -C 4 hydroxyalkyl, C 3 -C 6 polyhydroxyalkyl or C 1 -C 4 aminoalkyl radical.
Claim 4
Dependent Claim
18 words
Substituted para-aminophenols according to claim 1 selected from the group consisting of: 4-amino-3-(β-hydroxyethoxy)phenol, 4-amino-3-(β-hydroxyethylthio)phenol, 4-amino-6-chloro-3-(βhydroxyethoxy)phenol, 4-amino-6-chloro-3-(methylthio)phenol, and 4-amino-6-chloro-3-(βaminoethylthio)phenol.
Claim 5
Dependent Claim
63 words
Dyeing composition for dying keratinous fibres, and especially human hair, comprising in an aqueous vehicle, one or more compounds of formula (I): ##STR15## in which X denotes a hydrogen or halogen atom, Y denotes an oxygen or sulphur atom and R denotes a C 1 -C 4 hydroxyalkyl, C 3 -C 6 polyhydroxyalkyl or C 1 -C 4 aminoalkyl radical, or salts thereof.
Claim 6
Dependent Claim
63 words
Dyeing composition for dying keratinous fibres, and especially human hair, comprising in an aqueous vehicle, one or more compounds of formula (I): ##STR15## in which X denotes a hydrogen or halogen atom, Y denotes an oxygen or sulphur atom and R denotes a C 1 -C 4 hydroxyalkyl, C 3 -C 6 polyhydroxyalkyl or C 1 -C 4 aminoalkyl radical, or salts thereof.
Claim 7
Dependent Claim
22 words
Composition according to claim 4, further comprising oxidation dye precursors selected from the group consisting of para phenylenediamines, para-aminophenols, ortho-phenylenediamines and ortho-aminophenols.
Claim 8
Dependent Claim
9 words
Composition according to claim 4 also comprising a coupler.
Claim 9
Dependent Claim
41 words
Composition according to claim 6 also comprising a coupler is selected from the group consisting of metadiphenols, meta-anminophenols, meta-phenylenediamines, meta-acylaminophenols, meta-ureidophenols, meta-carbalcoxyaminophenols, alpha-naphtol, couplers possessing an active methylene group such as 7/8-keto compounds and pyrazolones, 2,3-methylenedioxyphenol, 3,4-methylenedioxyaniline, 2-bromo-4,5-methylenedioxyphenol, 2-chloro-4,5-methylenedioxyphenol and 2-methoxy-4,5-methylenedioxyaniline.
Claim 10
Dependent Claim
12 words
Composition according to claim 4 further comprising one or more direct dyes.
Claim 11
Dependent Claim
27 words
Composition according to claim 8, wherein the direct dyes are selected from the group consisting of azo dyes, anthraquinone dyes and nitro derivatives of the benzene series.
Claim 12
Dependent Claim
25 words
Composition according to claim 4, containing from 0.02 to 6% by weight of compound of formula (I) relative to the total weight of the composition.
Claim 13
Dependent Claim
32 words
Composition according to claim 6 wherein the total weight of the oxidation dye precursors and the couplers is from 0.1 to 7% by weight of the total weight of the dyeing composition.
Claim 14
Dependent Claim
38 words
Composition according to claim 4 further comprising adjuvants selected from the group consisting of anionic, cationic, nonionic, amphoteric, and zwitterionic surfactants, and mixtures thereof, organic solvents, thickening agents, antioxidants, penetrating agents, sequestring agents, buffers, perfumes and alkalinizing agents.
Claim 15
Dependent Claim
13 words
Dyeing composition according to claim 4 having a pH from 8 to 11.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1995-01-27 | 1995-07-29 | 1996-01-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-01-27 | 1999-07-29 | 2000-01-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-01-27 | 2003-07-29 | 2004-01-28 | $7700.00 | Window Closed / Lapsed |