Patent US5082891A successfully refreshed from Google Patents.
US5082891A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Curable resin composition containing dispersed particles of a cured silicone rubber
Assignee: DuPont Toray Specialty Materials KK
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Filing: 1989-12-13
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Granted: 1992-01-21
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Expires: 2009-12-13
Abstract
Abstract The curable resin composition of the present invention consists of a curable resin having uniformly dispersed therein particles of a cured silicone rubber obtained from an organosiloxane composition curable by a platinum-catalyzed hydrosilation reaction, wherein said organosiloxane composition contains reaction products of an ethylenically unsaturated epoxy compound and an ethylenically unsaturated aromatic compound with the organohydrogenpolysiloxane present in said organosiloxane composition. Either or both of the epoxy compound and the aromatic compound can be prereacted with a portion of the silicon-bonded hydrogen atoms of the organohydrogenpolysiloxane.
Inventors
- 👤 Yoshitsugu Morita
- 👤 Noriyasu Yokoyama
- 👤 Keiji Yoshida
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 06:25
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08L101/00; C08G; C08G77/00; C08G77/04; C08G77/12; C08G77/14; C08G77/20; C08G77/70
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
302 words
In an improved curable resin composition comprising (I) 100 parts by weight of a curable resin selected from the group consisting of phenolic resins, formaldehyde resins, xylene resins, furan resins, urea resins, imide resins, melamine resins, alkyd resins, aniline resins, sulfonamide resins, silicone resins, epoxy resins, and copolymers obtained by reacting two or more of these resins, and (II) from 0.1 to 100 parts by weight of uniformly dispersed, finely divided particles of a cured silicone rubber exhibiting a particle diameter not exceeding 1 millimeter, where said particles are obtained by curing an organosiloxane composition comprising (A) 100 parts by weight of an organopolysiloxane having at least two silicon-bonded lower alkenyl groups in each molecule, (B) from 0.3 to 100 parts by weight of an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms in each molecule, and (C) an amount of a platinum-containing catalyst sufficient to promote curing of said silicone rubber, the improvement comprising the presence in the curable organosiloxane composition of either (1) from 0.1 to 50 parts by weight of (D) an aliphatically unsaturated epoxide compound or a reaction product of from 0.1 to 50 parts by weight of said epoxide compound with a quantity of said organohydrogenpolysiloxane in excess of that required to react with said organopolysiloxane; and from 0.1 to 100 parts by weight of (E) an aromatic hydrocarbon containing at least one aliphatically unsaturated group per molecule or a reaction product of said aromatic hydrocarbon with a quantity of said organohydrogenpolysiloxane in excess of that required to react with said organopolysiloxane, or (2) a reaction product of from 0.1 to 50 parts by weight of said epoxide compound and from 0.1 to 100 parts by weight of said aromatic hydrocarbon with a quantity of said organohydrogenpolysiloxane in excess of that required to react with said organopolysiloxane.
Claim 2
Dependent Claim
302 words
In an improved curable resin composition comprising (I) 100 parts by weight of a curable resin selected from the group consisting of phenolic resins, formaldehyde resins, xylene resins, furan resins, urea resins, imide resins, melamine resins, alkyd resins, aniline resins, sulfonamide resins, silicone resins, epoxy resins, and copolymers obtained by reacting two or more of these resins, and (II) from 0.1 to 100 parts by weight of uniformly dispersed, finely divided particles of a cured silicone rubber exhibiting a particle diameter not exceeding 1 millimeter, where said particles are obtained by curing an organosiloxane composition comprising (A) 100 parts by weight of an organopolysiloxane having at least two silicon-bonded lower alkenyl groups in each molecule, (B) from 0.3 to 100 parts by weight of an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms in each molecule, and (C) an amount of a platinum-containing catalyst sufficient to promote curing of said silicone rubber, the improvement comprising the presence in the curable organosiloxane composition of either (1) from 0.1 to 50 parts by weight of (D) an aliphatically unsaturated epoxide compound or a reaction product of from 0.1 to 50 parts by weight of said epoxide compound with a quantity of said organohydrogenpolysiloxane in excess of that required to react with said organopolysiloxane; and from 0.1 to 100 parts by weight of (E) an aromatic hydrocarbon containing at least one aliphatically unsaturated group per molecule or a reaction product of said aromatic hydrocarbon with a quantity of said organohydrogenpolysiloxane in excess of that required to react with said organopolysiloxane, or (2) a reaction product of from 0.1 to 50 parts by weight of said epoxide compound and from 0.1 to 100 parts by weight of said aromatic hydrocarbon with a quantity of said organohydrogenpolysiloxane in excess of that required to react with said organopolysiloxane.
Claim 3
Dependent Claim
113 words
A curable resin composition according to claim 1 where the viscosity of ingredient A is from 0.05 to 100 Pa.s at 25° C., the viscosity of ingredient B is from 0.001 to 10 Pa.s, the concentration of ingredient C is equivalent to from 0.1 to 1000 parts of platinum metal per million parts by weight of ingredient A, ingredient D is allyl glycidyl ether, vinylcyclohexene monoxide, glycidyl acrylate, glycidyl methacrylate, ##STR4## where m and n are positive integers, ingredient E is ##STR5## the diameter of said microparticulate silicone rubber is less than 300 microns, and the concentration of said microparticulate silicone rubber in said curable resin composition is from 0.5 to 70 parts.
Claim 4
Dependent Claim
102 words
A composition according to claim 2 where said resin is a phenolic, imide, epoxy, or a silicone resin, the viscosity of ingredient A is from 0.05 to 10 Pa.s, the hydrocarbon radicals of ingredient A are methyl and vinyl, the concentration of ingredient B is from 0.3 to 100 parts by weight per 100 parts of ingredient A, the organosiloxane composition contains a filler, the concentration of ingredient C is equivalent to from 0.5 to 200 parts by weight per one million parts by weight of ingredient A, and the diameter of the cured silicone rubber particles does not exceed 50 microns.
Claim 5
Dependent Claim
57 words
A composition according to claim 3 where ingredient A is a dimethylvinylsiloxy-terminated dimethylpolysiloxane, ingredient B is a methylhydrogenpolysiloxane, ingredient C is chloroplatinic acid, and prior to being added to said organosiloxane composition at least one of said epoxy compound and said aromatic compound at prereacted with a portion of the silicon-bonded hydrogen atoms present in the organohydrogenpolysiloxane.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-01-20 | 1995-07-22 | 1996-01-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-01-20 | 1999-07-22 | 2000-01-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-01-20 | 2003-07-22 | 2004-01-21 | $7700.00 | Window Closed / Lapsed |