US5071819A
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US
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Sulfur and nitrogen-containing hydrocarbons and process of using same in recovering and concentrating desired ions from solutions thereof
Assignee: Brigham Young University
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Filing: 1988-08-26
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Granted: 1991-12-10
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Expires: 2008-08-26
Abstract
Abstract The invention has compositions of matter and process aspects. The compositions of matter aspects relate to a class of new organic compounds, viz., intermediates which are sulfur and nitrogen containing hydrocarbons covalently bonded to trialkoxysilane and those intermediates covalently bonded to a solid inorganic support such as silica. The process aspect comprises two processes, viz., (1) a process for making the new class of compounds, and (2) the process of removing and/or concentrating certain ions such as noble metal ions and other transition metal ions, from solutions thereof admixed with other ions which may be present in much higher concentrations by forming a complex of the desired ion(s) with a compound as stated, e.g., by flowing the solution through a column packed with the compound, breaking the complex, e.g., by flowing a receiving liquid through the column to remove the desired ion(s) in solution in the receiving liquid and recovering the desired ion(s) from the receiving liquid.
Inventors
- 👤 Byron J. Tarbet
- 👤 Ronald L. Bruening
- 👤 Jerald S. Bradshaw
- 👤 Reed M. Izatt
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 04:30
CPC Classifications
B; B01; B01J; B01J45/00; B01J20/00; B01J20/30; B01J20/3092; B01J20/32; B01J20/3202; B01J20/3204; B01J20/3214; B01J20/3217; B01J20/3219; B01J20/3231; B01J20/3242; B01J20/3244; B01J20/3246; B01J20/3257; B01J20/3259; B01J20/3263; B01J2220/00; B01J2220/50; B01J2220/58
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
291 words
A compound of formula ##STR4## wherein A and B are members selected from the group consisting of N(R 3 ), N(R 3 )CH 2 , O, OCH 2 , S and SCH 2 , with the further proviso that if A is selected from the group consisting of O, OCH 2 , S and SCH 2 then B must be selected from the group consisting of N(R 3 ) and N(R 3 )CH 2 ; D is a member selected from the group consisting of H, SH, OH, NH(R 3 ), lower alkyl and N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ; X is a member selected from the group consisting of Cl, O-matrix, OCH 3 and OC 2 H 5 ; Y and Z are members selected from the group consisting of Cl, O-matrix, OCH 3 , OC 2 H 5 , methyl, ethyl and halogenated substituents thereof; R 1 is a member selected from the group consisting of H, SH, OH, lower alkyl and aryl; R 2 is a member selected from the group consisting of H and lower alkyl; R 3 is a member selected from the group consisting of H and [(CH 2 ) f E] g R 4 , where E is selected from the group consisting of S, Se and Te; and R 4 is a member selected from the group consisting of H, lower alkyl and aryl; a is from 2 to about 10; c is 4; d is from 0 to about 2000; f is from 2 to about 10; g is from 1 to about 10; and matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania or nickel oxide.
Claim 2
Dependent Claim
291 words
A compound of formula ##STR4## wherein A and B are members selected from the group consisting of N(R 3 ), N(R 3 )CH 2 , O, OCH 2 , S and SCH 2 , with the further proviso that if A is selected from the group consisting of O, OCH 2 , S and SCH 2 then B must be selected from the group consisting of N(R 3 ) and N(R 3 )CH 2 ; D is a member selected from the group consisting of H, SH, OH, NH(R 3 ), lower alkyl and N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ; X is a member selected from the group consisting of Cl, O-matrix, OCH 3 and OC 2 H 5 ; Y and Z are members selected from the group consisting of Cl, O-matrix, OCH 3 , OC 2 H 5 , methyl, ethyl and halogenated substituents thereof; R 1 is a member selected from the group consisting of H, SH, OH, lower alkyl and aryl; R 2 is a member selected from the group consisting of H and lower alkyl; R 3 is a member selected from the group consisting of H and [(CH 2 ) f E] g R 4 , where E is selected from the group consisting of S, Se and Te; and R 4 is a member selected from the group consisting of H, lower alkyl and aryl; a is from 2 to about 10; c is 4; d is from 0 to about 2000; f is from 2 to about 10; g is from 1 to about 10; and matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania or nickel oxide.
Claim 3
Dependent Claim
11 words
A compound as defined in claim 1 wherein a is 3.
Claim 4
Dependent Claim
11 words
A compound as defined in claim 1 wherein d is 0.
Claim 5
Dependent Claim
12 words
A compound as defined in claim 1 wherein R 1 is OH.
Claim 6
Dependent Claim
12 words
A compound as defined in claim 1 wherein R 2 is H.
Claim 7
Dependent Claim
11 words
A compound as defined in claim 1 wherein A contains nitrogen.
Claim 8
Dependent Claim
11 words
A compound as defined in claim 1 wherein B contains nitrogen.
Claim 9
Dependent Claim
59 words
A compound as defined in claim 1 wherein a is 3, b is 1, d is 1, R 1 is OH, R 2 is H, A contains nitrogen, d is 0 so that B is absent, D is N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ, and X, Y and Z are each O-matrix.
Claim 10
Dependent Claim
54 words
A compound as defined in claim 1 wherein a is 3, b is 1, d is 1, R 1 is OH, R 2 is H, A contains nitrogen, B contains nitrogen, D is N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ, and X, Y and Z are each O-matrix.
Claim 11
Dependent Claim
290 words
A compound of formula ##STR5## wherein A and B are members selected from the group consisting of N(R 3 ), N(R 3 )CH 2 , O, OCH 2 , S and SCH 2 , with the further proviso that if A is selected from the group consisting of O, OCH 2 , S and SCH 2 then B must be selected from the group consisting of N(R 3 ) and N(R 3 )CH 2 ; D is a member selected from the group consisting of NH(R 3 ) and N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ; X is a member selected from the group consisting of Cl, O-matrix, OCH 3 and OC 2 H 5 ; Y and Z are members selected from the group consisting of Cl, O-matrix, OCH 3 , OC 2 H 5 , methyl, ethyl and halogenated substituents thereof; R 1 is a member selected from the group consisting of H, SH, OH, lower alkyl and aryl; R 2 is a member selected from the group consisting of H and lower alkyl; R 3 is a member selected from the group consisting of H and [(CH 2 ) f E] g R 4 , where E is selected from the group consisting of S, Se and Te; and R 4 is a member selected from the group consisting of H, lower alkyl and aryl; a is from 2 to about 10; c is from 1 to about 2000; d is from 0 to about 2000; f is from 2 to about 10; g is from 1 to about 10; and matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania or nickel oxide.
Claim 12
Dependent Claim
290 words
A compound of formula ##STR5## wherein A and B are members selected from the group consisting of N(R 3 ), N(R 3 )CH 2 , O, OCH 2 , S and SCH 2 , with the further proviso that if A is selected from the group consisting of O, OCH 2 , S and SCH 2 then B must be selected from the group consisting of N(R 3 ) and N(R 3 )CH 2 ; D is a member selected from the group consisting of NH(R 3 ) and N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ; X is a member selected from the group consisting of Cl, O-matrix, OCH 3 and OC 2 H 5 ; Y and Z are members selected from the group consisting of Cl, O-matrix, OCH 3 , OC 2 H 5 , methyl, ethyl and halogenated substituents thereof; R 1 is a member selected from the group consisting of H, SH, OH, lower alkyl and aryl; R 2 is a member selected from the group consisting of H and lower alkyl; R 3 is a member selected from the group consisting of H and [(CH 2 ) f E] g R 4 , where E is selected from the group consisting of S, Se and Te; and R 4 is a member selected from the group consisting of H, lower alkyl and aryl; a is from 2 to about 10; c is from 1 to about 2000; d is from 0 to about 2000; f is from 2 to about 10; g is from 1 to about 10; and matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania or nickel oxide.
Claim 13
Dependent Claim
25 words
A compound as defined in claim 10 wherein D is NR 3 CH 2 CH(R 1 )CH 2 O(CH 2 ) a Si(O-matrix) 3 .
Claim 14
Dependent Claim
23 words
A compound as defined in claim 10 wherein D is N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ.
Claim 15
Dependent Claim
273 words
A compound of formula ##STR6## wherein A and B are members selected from the group consisting of N(R 3 ), N(R 3 )CH 2 , O, OCH 2 , S and SCH 2 , with the further proviso that if A is selected from the group consisting of O, OCH 2 , S and SCH 2 then B must be selected from the group consisting of N(R 3 ) and N(R 3 )CH 2 ; D is a member selected from the group consisting of H, SH, OH, NH(R 3 ) lower alkyl and N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ; X is a member selected from the group consisting of Cl, O-matrix, OCH 3 and OC 2 H 5 ; Y and Z are O-matrix; R 1 is a member selected from the group consisting of H, SH, OH, lower alkyl and aryl; R 2 is a member selected from the group consisting of H and lower alkyl; R 3 is a member selected from the group consisting of H and [(CH 2 ) f E] g R 4 , where E is selected from the group consisting of S, Se and Te; and R 4 is a member selected from the group consisting of H, lower alkyl and aryl; a is from 2 to about 10; c is from 1 to about 2000; d is from 0 to about 2000; f is from 2 to about 10; g is from 1 to about 10; and matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania or nickel oxide.
Claim 16
Dependent Claim
273 words
A compound of formula ##STR6## wherein A and B are members selected from the group consisting of N(R 3 ), N(R 3 )CH 2 , O, OCH 2 , S and SCH 2 , with the further proviso that if A is selected from the group consisting of O, OCH 2 , S and SCH 2 then B must be selected from the group consisting of N(R 3 ) and N(R 3 )CH 2 ; D is a member selected from the group consisting of H, SH, OH, NH(R 3 ) lower alkyl and N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ; X is a member selected from the group consisting of Cl, O-matrix, OCH 3 and OC 2 H 5 ; Y and Z are O-matrix; R 1 is a member selected from the group consisting of H, SH, OH, lower alkyl and aryl; R 2 is a member selected from the group consisting of H and lower alkyl; R 3 is a member selected from the group consisting of H and [(CH 2 ) f E] g R 4 , where E is selected from the group consisting of S, Se and Te; and R 4 is a member selected from the group consisting of H, lower alkyl and aryl; a is from 2 to about 10; c is from 1 to about 2000; d is from 0 to about 2000; f is from 2 to about 10; g is from 1 to about 10; and matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania or nickel oxide.
Claim 17
Dependent Claim
11 words
A compound as defined in claim 13 wherein X is O-matrix.
Claim 18
Dependent Claim
292 words
A compound of formula ##STR7## wherein A and B are members selected from the group consisting of N(R 3 ), N(R 3 )CH 2 , O, OCH 2 , S and SCH 2 , with the further proviso that if A is selected from the group consisting of O, OCH 2 , S and SCH 2 then B must be selected from the group consisting of N(R 3 ) and N(R 3 )CH 2 ; D is a member selected from the group consisting of H, SH, OH, NH(R 3 ) lower alkyl and N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ; X is a member selected from the group consisting of Cl, O-matrix, OCH 3 and OC 2 H 5 ; Y and Z are members selected from the group consisting of Cl, O-matrix, OCH 3 , OC 2 H 5 , methyl, ethyl and halogenated substituents thereof; R 1 is a member selected from the group consisting of phenyl, naphthyl and pyridyl; R 2 is a member selected from the group consisting of H and lower alkyl; R 3 is a member selected from the group consisting of H and [(CH 2 ) f E] g R 4 , where E is selected from the group consisting of S, Se and Te; and R 4 is a member selected from the group consisting of H, lower alkyl and aryl; a is from 2 to about 10; c is from 1 to about 2000; d is from 0 to about 2000; f is from 2 to about 10; g is from 1 to about 10; and matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania or nickel oxide.
Claim 19
Dependent Claim
292 words
A compound of formula ##STR7## wherein A and B are members selected from the group consisting of N(R 3 ), N(R 3 )CH 2 , O, OCH 2 , S and SCH 2 , with the further proviso that if A is selected from the group consisting of O, OCH 2 , S and SCH 2 then B must be selected from the group consisting of N(R 3 ) and N(R 3 )CH 2 ; D is a member selected from the group consisting of H, SH, OH, NH(R 3 ) lower alkyl and N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ; X is a member selected from the group consisting of Cl, O-matrix, OCH 3 and OC 2 H 5 ; Y and Z are members selected from the group consisting of Cl, O-matrix, OCH 3 , OC 2 H 5 , methyl, ethyl and halogenated substituents thereof; R 1 is a member selected from the group consisting of phenyl, naphthyl and pyridyl; R 2 is a member selected from the group consisting of H and lower alkyl; R 3 is a member selected from the group consisting of H and [(CH 2 ) f E] g R 4 , where E is selected from the group consisting of S, Se and Te; and R 4 is a member selected from the group consisting of H, lower alkyl and aryl; a is from 2 to about 10; c is from 1 to about 2000; d is from 0 to about 2000; f is from 2 to about 10; g is from 1 to about 10; and matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania or nickel oxide.
Claim 20
Dependent Claim
288 words
A compound of formula ##STR8## wherein A and B are members selected from the group consisting of N(R 3 ), N(R 3 )CH 2 , O, OCH 2 , S and SCH 2 , with the further proviso that if A is selected from the group consisting of O, OCH 2 , S and SCH 2 then B must be selected from the group consisting of N(R 3 ) and N(R 3 )CH 2 ; D is a member selected from the group consisting of H, SH, OH, NH(R 3 ) lower alkyl and N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ; X is a member selected from the group consisting of Cl, O-matrix, OCH 3 and OC 2 H 5 ; Y and Z are members selected from the group consisting of Cl, O-matrix, OCH 3 , OC 2 H 5 , methyl, ethyl and halogenated substituents thereof; R 1 is a member selected from the group consisting of H, SH, OH, lower alkyl and aryl; R 2 is a member selected from the group consisting of H and lower alkyl; R 3 is a member selected from the group consisting of H and [(CH 2 ) f E] g R 4 , where E is selected from the group conssiting of S, Se and Te; and R 4 is a member selected from the group consisting of H, lower alkyl and aryl; a is from 2 to about 10; c is from 1 to about 2000; f is from 2 to about 10; g is from 1 to about 10; and matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania or nickel oxide.
Claim 21
Dependent Claim
288 words
A compound of formula ##STR8## wherein A and B are members selected from the group consisting of N(R 3 ), N(R 3 )CH 2 , O, OCH 2 , S and SCH 2 , with the further proviso that if A is selected from the group consisting of O, OCH 2 , S and SCH 2 then B must be selected from the group consisting of N(R 3 ) and N(R 3 )CH 2 ; D is a member selected from the group consisting of H, SH, OH, NH(R 3 ) lower alkyl and N(R 3 )CH 2 CH(R 1 )CH 2 O(CH 2 ) a SiXYZ; X is a member selected from the group consisting of Cl, O-matrix, OCH 3 and OC 2 H 5 ; Y and Z are members selected from the group consisting of Cl, O-matrix, OCH 3 , OC 2 H 5 , methyl, ethyl and halogenated substituents thereof; R 1 is a member selected from the group consisting of H, SH, OH, lower alkyl and aryl; R 2 is a member selected from the group consisting of H and lower alkyl; R 3 is a member selected from the group consisting of H and [(CH 2 ) f E] g R 4 , where E is selected from the group conssiting of S, Se and Te; and R 4 is a member selected from the group consisting of H, lower alkyl and aryl; a is from 2 to about 10; c is from 1 to about 2000; f is from 2 to about 10; g is from 1 to about 10; and matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania or nickel oxide.
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