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US5071733A Expired / Lapsed US ⏱️ 0.0 years remaining

Patterned thin film and process for preparing the same

Assignee: Kanegafuchi Chemical Industry Co Ltd
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Filing: 1989-12-29
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Granted: 1991-12-10
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Expires: 2009-12-29
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Abstract

Abstract A patterned thin film suitable for use in electric and electronic devices, prepared from a polymer or a mixture of the polymer and other known compounds capable of forming a thin film by LB technique, said polymer having linear recurring units wherein an organic group R 1 having at least 2 carbon atoms and a valence of at least 2 is combined alternately with an organic group R 2 having at least 2 carbon atoms and a valence of at least 2 through a bivalent group formed by a reaction of an acid group A containing a hetero atom and a basic group B containing a hetero atom, and wherein a hydrocarbon-containing group R 3 having 10 to 30 carbon atoms which may contain a substituent group, is linked by covalent or ionic bond to said recurring units, the number of groups R 3 being at least 2 per 10 recurring units. The patterned thin film is prepared by building up a layer or layers of the polymer or a mixture of the polymer and a compound capable of forming a film by LB technique onto a substrate according to the LB technique, irradiating patternwise the built-up film with high energy rays, and developing the irradiated film, or by forming the built-up film in the same manner as above on a patterned, removal film formed on a substrate, and removing the patterned film from the substrate, and if desired, by further subjecting the obtained pattern to a reaction to convert the polymer, when it has a structure as a precursor, into a polymer having a 5-membered or 6-membered heterocyclic structure.

Inventors

  • 👤 Masakazu Uekita
  • 👤 Hiroshi Awaji
  • 👤 Makoto Murata
  • 👤 Satoshi Mizunuma

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 21:46
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/68; H10P14/683; B; B05; B05D; B05D1/00; B05D1/18; B05D1/20; B05D1/202; B82; B82Y; B82Y30/00; B82Y40/00; G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/414; H10D; H10D1/00; H10D1/60; H10D1/68; H10D64/00; H10D64/60; H10D64/66; H10D64/68; H10D64/691; H10K; H10K30/00; H10K30/354; H10K50/00; H10K50/10; H10K50/11; H10K71/00; H10K71/20; H10K85/00; H10K85/10; H10K85/111; H10K85/154; H10K85/60; H10K85/615; H10K85/621; H10K85/701; H10N; H10N60/00; H10N60/80; H10N60/805; H10N70/00; H10P14/63; H10P14/6326; H10P14/6342; H10P14/6344; H10P14/65; H10P14/6516; H10P14/6536; H10P14/6538; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02E10/549; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31721

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 188 words
A process for preparing a patterned thin film which comprises building up at least one layer of a polymer or a mixture of said polymer and another compound capable of forming a thin film by a Langmuir-Blodgett technique onto a substrate by a Langmuir-Blodgett technique, irradiating patternwise the built-up film with a high energy ray, and developing the irradiated film by applying to the irradiated film a liquid which causes the irradiated portions of the film to dissolve, said polymer having linear recurring units wherein an organic group R 1 having at least 2 carbon atoms and a valence of at least 2 is combined alternately with an organic group R 2 having at least 2 carbon atoms and a valence of at least 2 through a bivalent group formed by reaction of an acid group A containing a hetero atom and a basic group B containing a hetero atom, and wherein a hydrocarbon-containing group R 3 having 10 to 30 carbon atoms is linked by covalent or ionic bonding to said recurring units, the number of group R 3 being at least 2 per 10 recurring units.
Claim 2
Dependent Claim 188 words
A process for preparing a patterned thin film which comprises building up at least one layer of a polymer or a mixture of said polymer and another compound capable of forming a thin film by a Langmuir-Blodgett technique onto a substrate by a Langmuir-Blodgett technique, irradiating patternwise the built-up film with a high energy ray, and developing the irradiated film by applying to the irradiated film a liquid which causes the irradiated portions of the film to dissolve, said polymer having linear recurring units wherein an organic group R 1 having at least 2 carbon atoms and a valence of at least 2 is combined alternately with an organic group R 2 having at least 2 carbon atoms and a valence of at least 2 through a bivalent group formed by reaction of an acid group A containing a hetero atom and a basic group B containing a hetero atom, and wherein a hydrocarbon-containing group R 3 having 10 to 30 carbon atoms is linked by covalent or ionic bonding to said recurring units, the number of group R 3 being at least 2 per 10 recurring units.
Claim 3
Dependent Claim 227 words
A process for preparing a patterned, heat resistant thin film which comprises building up according to a Langmuir-Blodgett technique at least one layer of a polymer or a mixture of said polymer and another compound capable of forming a thin film by a Langmuir-Blodgett technique on a substrate, irradiating patternwise the built-up film with a higher energy ray, developing the irradiated film by applying to the irradiated film a liquid which causes the irradiated portions of the film to dissolve, and subjecting the remaining built-up film to a reaction to form a 5-membered or 6-membered heterocyclic ring, said polymer having linear recurring units wherein an organic group R 1 having at least 2 carbon atoms and a valence of at least 3 is combined alternately with an organic group R 2 having at least 2 carbon atoms and a valence of at least 2 through a bivalent group formed by reaction of an acid group A containing a hetero atom and a basic group B containing a hetero atom, and wherein a hydrocarbon-containing group R 3 having 10 to 30 carbon atoms is linked by covalent or ionic bonding to said recurring units, the number of groups R 3 being at least 2 per 10 recurring units, and said recurring units having a precursor structure capable of forming a 5-membered or 6-membered ring containing a hetero atom.
Claim 4
Dependent Claim 227 words
A process for preparing a patterned, heat resistant thin film which comprises building up according to a Langmuir-Blodgett technique at least one layer of a polymer or a mixture of said polymer and another compound capable of forming a thin film by a Langmuir-Blodgett technique on a substrate, irradiating patternwise the built-up film with a higher energy ray, developing the irradiated film by applying to the irradiated film a liquid which causes the irradiated portions of the film to dissolve, and subjecting the remaining built-up film to a reaction to form a 5-membered or 6-membered heterocyclic ring, said polymer having linear recurring units wherein an organic group R 1 having at least 2 carbon atoms and a valence of at least 3 is combined alternately with an organic group R 2 having at least 2 carbon atoms and a valence of at least 2 through a bivalent group formed by reaction of an acid group A containing a hetero atom and a basic group B containing a hetero atom, and wherein a hydrocarbon-containing group R 3 having 10 to 30 carbon atoms is linked by covalent or ionic bonding to said recurring units, the number of groups R 3 being at least 2 per 10 recurring units, and said recurring units having a precursor structure capable of forming a 5-membered or 6-membered ring containing a hetero atom.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-12-09 1995-06-10 1995-12-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-12-09 1999-06-10 1999-12-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-12-09 2003-06-10 2003-12-10 $7700.00 Window Closed / Lapsed

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