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US5071722A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for preparing cadmium hydroxide, and alkaline secondary battery and method for charging the same

Assignee: Japan Storage Battery Co Ltd
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Filing: 1989-11-15
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Granted: 1991-12-10
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Expires: 2009-11-15
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Abstract

Abstract The present invention provides a process for easily preparing gamma -Cd(OH)2. The present invention facilitates improvement in the charge/discharge performance and energy density of an alkaline secondary battery having a cadmium electrode including gamma -Cd(OH)2. The present invention provides superrapid-chargeable batteries, such as a nickel-cadmium alkaline secondary battery having a cadmium electrode including gamma -Cd(OH)2 in which the weight of cadmium hydroxide contained in the negative electrode is 0.95 times as much as the weight of nickel hydroxide contained in the positive electrode, a manganese dioxide-cadmium alkaline secondary battery in which the weight of cadmium hydroxide contained in the negative electrode is not more than 0.84 times as much as the weight of manganese dioxide contained in the positive electrode, and a silver oxide-cadmium alkaline secondary battery in which the weight of cadmium hydroxide contained in the negative electrode is not more than 1.36 times as much as the weight of silver contained in the positive electrode.

Inventors

  • 👤 Koji Yoshimura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 23:06
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/24; H01M4/246; C; C01; C01G; C01G11/00; H01M10/00; H01M10/34; H01M10/42; H01M10/44; H01M4/36; H01M4/48; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 24 words
A process for preparing cadmium hydroxide in which cadmium oxide is to react with an alkaline aqueous solution containing hydroxyethylcellulose or water containing hydroxyethylcellulose.
Claim 2
Dependent Claim 24 words
A process for preparing cadmium hydroxide in which cadmium oxide is to react with an alkaline aqueous solution containing hydroxyethylcellulose or water containing hydroxyethylcellulose.
Claim 3
Dependent Claim 27 words
A process for preparing cadmium hydroxide in which a mixture containing hydroxyethylcellulose and cadmium oxide is caused to react with an alkaline aqueous solution containing sodium hydroxide.
Claim 4
Dependent Claim 27 words
A process for preparing cadmium hydroxide in which a mixture containing hydroxyethylcellulose and cadmium oxide is caused to react with an alkaline aqueous solution containing sodium hydroxide.
Claim 5
Dependent Claim 22 words
A process for preparing cadmium hydroxide according to claim 1, in which cadmium oxide is aquated in the presence of metallic cadmium.
Claim 6
Dependent Claim 22 words
A process for preparing cadmium hydroxide according to claim 2, in which cadmium oxide is aquated in the presence of metallic cadmium.
Claim 7
Dependent Claim 57 words
A nickel-cadmium alkaline secondary battery having a nickel hydroxide positive electrode and a cadmium negative electrode, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 0.95 times as much as the weight of nickel hydroxide contained in said positive electrode, and in which γ-Cd(OH) 2 exists in said negative electrode.
Claim 8
Dependent Claim 57 words
A nickel-cadmium alkaline secondary battery having a nickel hydroxide positive electrode and a cadmium negative electrode, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 0.95 times as much as the weight of nickel hydroxide contained in said positive electrode, and in which γ-Cd(OH) 2 exists in said negative electrode.
Claim 9
Dependent Claim 76 words
A manganese dioxide-cadmium alkaline secondary battery having a positive electrode including manganese dioxide as a main active matter and a negative electrode including metallic cadmium as a main active material, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 0.84 times as much as the weight of manganese dioxide contained in said positive electrode when said battery is discharged, and in which γ-Cd(OH) 2 exists in said negative electrode.
Claim 10
Dependent Claim 76 words
A manganese dioxide-cadmium alkaline secondary battery having a positive electrode including manganese dioxide as a main active matter and a negative electrode including metallic cadmium as a main active material, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 0.84 times as much as the weight of manganese dioxide contained in said positive electrode when said battery is discharged, and in which γ-Cd(OH) 2 exists in said negative electrode.
Claim 11
Dependent Claim 94 words
A manganese dioxide-cadmium alkaline secondary battery having a positive electrode including manganese dioxide as a main active material and nickel hydroxide, and a negative electrode including metallic cadmium as a main active material cadmium hydroxide, in which the weight of cadmium hydroxide contained in said negative electrode is not more than the sum of 0.84 times as much as the weight of manganese dioxide and 0.95 times as much as the weight of nickel hydroxide in said positive electrode when said battery is discharged, and in which γ-Cd(OH) 2 exists in said negative electrode.
Claim 12
Dependent Claim 94 words
A manganese dioxide-cadmium alkaline secondary battery having a positive electrode including manganese dioxide as a main active material and nickel hydroxide, and a negative electrode including metallic cadmium as a main active material cadmium hydroxide, in which the weight of cadmium hydroxide contained in said negative electrode is not more than the sum of 0.84 times as much as the weight of manganese dioxide and 0.95 times as much as the weight of nickel hydroxide in said positive electrode when said battery is discharged, and in which γ-Cd(OH) 2 exists in said negative electrode.
Claim 13
Dependent Claim 57 words
A silver oxide-cadmium alkaline secondary battery having a silver oxide positive electrode and a cadmium negative electrode, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 1.36 times as much as the weight of silver contained in said positive electrode, and in which γ-Cd(OH) 2 exists in said negative electrode.
Claim 14
Dependent Claim 57 words
A silver oxide-cadmium alkaline secondary battery having a silver oxide positive electrode and a cadmium negative electrode, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 1.36 times as much as the weight of silver contained in said positive electrode, and in which γ-Cd(OH) 2 exists in said negative electrode.
Claim 15
Independent Claim 94 words
A method for charging a nickel cadmium alkaline secondary battery having a nickel hydroxide positive electrode and a cadmium negative electrode, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 0.95 times as much as the weight of nickel hydroxide contained in said positive electrode, and in which γ-Cd(OH) 2 exists in said negative electrode, in which an initial charging current is established so as to be not more than 1 CA on the basis of the theoretical capacity of cadmium hydroxide contained in the negative electrode.
Claim 16
Independent Claim 94 words
A method for charging a nickel cadmium alkaline secondary battery having a nickel hydroxide positive electrode and a cadmium negative electrode, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 0.95 times as much as the weight of nickel hydroxide contained in said positive electrode, and in which γ-Cd(OH) 2 exists in said negative electrode, in which an initial charging current is established so as to be not more than 1 CA on the basis of the theoretical capacity of cadmium hydroxide contained in the negative electrode.
Claim 17
Independent Claim 112 words
A method for charging a manganese dioxide-cadmium alkaline secondary battery having a positive electrode including manganese dioxide as a main active material and a negative electrode including metallic cadmium as a main active matter, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 0.84 times as much as the weight of manganese dioxide contained in said positive electrode when said battery is discharged, and in which γ-Cd(OH) 2 exists in said negative electrode, in which an initial charging current is established so as to be not more than 1 CA on the basis of the theoretical capacity of cadmium hydroxide contained in the negative electrode.
Claim 18
Independent Claim 112 words
A method for charging a manganese dioxide-cadmium alkaline secondary battery having a positive electrode including manganese dioxide as a main active material and a negative electrode including metallic cadmium as a main active matter, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 0.84 times as much as the weight of manganese dioxide contained in said positive electrode when said battery is discharged, and in which γ-Cd(OH) 2 exists in said negative electrode, in which an initial charging current is established so as to be not more than 1 CA on the basis of the theoretical capacity of cadmium hydroxide contained in the negative electrode.
Claim 19
Independent Claim 131 words
A method for charging a manganese dioxide-cadmium alkaline secondary battery having a positive electrode including manganese dioxide as a main active material and nickel hydroxide, and a negative electrode including metallic cadmium as a main active matter and cadmium hydroxide, in which the weight of cadmium hydroxide contained in said negative electrode is not more than the sum of 0.84 times as much as the weight of manganese dioxide and 0.95 times as much as the weight of nickel hydroxide in said positive electrode when said battery is discharged, and in which γ-Cd(OH) 2 exists in said negative electrode, in which an initial charging current is established so as to be not more than 1 CA on the basis of the theoretical capacity of cadmium hydroxide contained in the negative electrode.
Claim 20
Independent Claim 131 words
A method for charging a manganese dioxide-cadmium alkaline secondary battery having a positive electrode including manganese dioxide as a main active material and nickel hydroxide, and a negative electrode including metallic cadmium as a main active matter and cadmium hydroxide, in which the weight of cadmium hydroxide contained in said negative electrode is not more than the sum of 0.84 times as much as the weight of manganese dioxide and 0.95 times as much as the weight of nickel hydroxide in said positive electrode when said battery is discharged, and in which γ-Cd(OH) 2 exists in said negative electrode, in which an initial charging current is established so as to be not more than 1 CA on the basis of the theoretical capacity of cadmium hydroxide contained in the negative electrode.
Claim 21
Independent Claim 92 words
A method for charging a silver oxide-cadmium alkaline secondary battery having a silver oxide positive electrode and a cadmium negative electrode, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 1.36 times as much as the weight of silver contained in said positive electrode, and which γ-Cd(OH) 2 exists in said negative electrode, in which an initial charging current is established so as to be not more than 1 CA on the basis of the theoretical capacity of cadmium hydroxide contained in the negative electrode.
Claim 22
Independent Claim 92 words
A method for charging a silver oxide-cadmium alkaline secondary battery having a silver oxide positive electrode and a cadmium negative electrode, in which the weight of cadmium hydroxide contained in said negative electrode is not more than 1.36 times as much as the weight of silver contained in said positive electrode, and which γ-Cd(OH) 2 exists in said negative electrode, in which an initial charging current is established so as to be not more than 1 CA on the basis of the theoretical capacity of cadmium hydroxide contained in the negative electrode.

References Cited (Backward Citations)

US4172184A Cited
US4275127A Cited
US4614696A Cited
JPS61240577A Cited
JPS61240579A Cited
US4713126A Cited
JPS63250068A Cited
JPS63252056A Cited
US4906539A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-12-09 1995-06-10 1995-12-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-12-09 1999-06-10 1999-12-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-12-09 2003-06-10 2003-12-10 $7700.00 Window Closed / Lapsed

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