US5061609A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process of preparing a tabular grain silver bromoiodide emulsion and emulsions produced thereby
Assignee: Eastman Kodak Co
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Filing: 1989-10-04
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Granted: 1991-10-29
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Expires: 2009-10-04
Abstract
Abstract A process is disclosed for the preparation of a tabular grain silver bromoiodide emulsion in which silver bromoiodide laminae are formed on the major faces of the tabular grains. The sensitivity of the emulsion as a function of pressure applied is rendered more nearly constant by forming the silver bromoiodide laminae on the major faces of the tabular grains. The silver bromoiodide laminae are formed on the major faces of the tabular grains with an iodide content higher than that of the host emulsion, and thereafter, within the pAg and temperature boundaries defined by Curve A in FIG. 1, bromide is deposited as a silver salt with the addition of iodide being limited or absent.
Inventors
- 👤 Roger H. Piggin
- 👤 Colin J. Bishop
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 11:16
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/0051; G03C1/035
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
183 words
A process for the preparation of a silver bromoiodide emulsion comprising providing a host emulsion comprised of a dispersing medium and silver bromide grains optionally including iodide in which greater than 50 percent of the total grain projected area is accounted for by tabular grains satisfying the relationship ECD/t.sup.2 >25 where ECD is the mean effective circular diaemter in μm of the tabular grains t is the mean thickness in μm of the tabular grains and forming silver bromoiodide laminae on the major faces of the tabular grains, characterized in that (a) the silver bromoiodide laminae are formed on the major faces of the tabular grains with an iodide content higher than that of the host emulsion and at least 5 mole percent, based on silver precipitated during this step, and (b) within the pAg and temperature boundaries defined by Curve A in FIG. 1 bromide is deposited on the silver bromoiodide laminae as a silver salt with any additional iodide supplied to the emulsion during this step being limited to less than 5 mole percent, based on silver introduced during this step.
Claim 2
Dependent Claim
183 words
A process for the preparation of a silver bromoiodide emulsion comprising providing a host emulsion comprised of a dispersing medium and silver bromide grains optionally including iodide in which greater than 50 percent of the total grain projected area is accounted for by tabular grains satisfying the relationship ECD/t.sup.2 >25 where ECD is the mean effective circular diaemter in μm of the tabular grains t is the mean thickness in μm of the tabular grains and forming silver bromoiodide laminae on the major faces of the tabular grains, characterized in that (a) the silver bromoiodide laminae are formed on the major faces of the tabular grains with an iodide content higher than that of the host emulsion and at least 5 mole percent, based on silver precipitated during this step, and (b) within the pAg and temperature boundaries defined by Curve A in FIG. 1 bromide is deposited on the silver bromoiodide laminae as a silver salt with any additional iodide supplied to the emulsion during this step being limited to less than 5 mole percent, based on silver introduced during this step.
Claim 3
Dependent Claim
31 words
A process according to claim 1 further characterized in that iodide accounts for at least 10 mole percent, based on silver, of the silver bromoiodide laminae as formed in step (a).
Claim 4
Dependent Claim
31 words
A process according to claim 2 further characterized in that iodide accounts for at least 15 mole percent, based on silver, of the silver bromoiodide laminae as formed in step (a).
Claim 5
Dependent Claim
24 words
A process according to claim 1 further characterized in that iodide constitutes less than 1 mole percent of total halide introduced during step (b).
Claim 6
Dependent Claim
19 words
A process according to claim 4 further characterized in that bromide is the sole halide introduced during step (b).
Claim 7
Dependent Claim
27 words
A process according to claim 1 further characterized in that step (a) is performed within the pAg and temperature boundaries defined by Curve A in FIG. 1.
Claim 8
Dependent Claim
27 words
A process according to claim 1 further characterized in that step (b) is performed within the pAg and temperature boundaries defined by Curve B in FIG. 1.
Claim 9
Dependent Claim
27 words
A process according to claim 7 further characterized in that step (a) is performed within the pAg and temperature boundaries defined by Curve B in FIG. 1.
Claim 10
Dependent Claim
30 words
A process according to claim 1 further characterized in that the silver introduced during step (a) constitutes from 1 to 40 mole percent of the total silver forming the emulsion.
Claim 11
Dependent Claim
30 words
A process according to claim 9 further characterized in that the silver introduced during step (a) constitutes from 5 to 25 mole percent of the total silver forming the emulsion.
Claim 12
Dependent Claim
30 words
A process according to claim 1 further characterized in that the silver introduced during step (b) constitutes from 10 to 40 mole percent of the total silver forming the emulsion.
Claim 13
Dependent Claim
30 words
A process according to claim 11 further characterized in that the silver introduced during step (b) constitutes from 25 to 35 mole percent of the total silver forming the emulsion.
Claim 14
Dependent Claim
21 words
A process according to claim 1 further characterized in that the host emulsion contains less than about 5 mole percent iodide.
Claim 15
Dependent Claim
21 words
A process according to claim 13 further characterized in that the host emulsion contains less than about 2 mole percent iodide.
Claim 16
Dependent Claim
18 words
A process according to claim 14 further characterized in that the host emulsion is a silver bromide emulsion.
Claim 17
Dependent Claim
19 words
A radiation sensitive silver bromoiodide emulsion prepared by the process of any one of claims 1 to 15 inclusive.
References Cited (Backward Citations)
US4414310A
Cited
US4425425A
Cited
US4433048A
Cited
US4434226A
Cited
US4439520A
Cited
US4414304A
Cited
US4425426B1
Cited
US4425426A
Cited
US4478929A
Cited
US4665012A
Cited
US4614711A
Cited
US4693964A
Cited
US4672027A
Cited
JPS62131247A
Cited
US4713320A
Cited
JPS63106746A
Cited
US4806461A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-10-28 | 1995-04-29 | 1995-10-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-10-28 | 1999-04-29 | 1999-10-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-10-28 | 2003-04-29 | 2003-10-29 | $7700.00 | Window Closed / Lapsed |