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Compositions for dental restoration

Assignee: GC Corp
•
Filing: 1990-06-07
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Granted: 1991-08-27
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Expires: 2010-06-07
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Abstract

Abstract A combined chemical-/light-polymerization type composition for dental restoration consists of a formulation A composed main of a. an ethylenically polymerizable unsaturated compound, b. a photo-polymerization initiator and c. a reducing agent, and a formulation B composed mainly of d. a filler and e. an organic peroxide. The formulations A and B are separately packaged and designed to be mixed for use.

Inventors

  • 👤 Takao Kubota
  • 👤 Tetsuro Sakuma
  • 👤 Ryoji Nakazato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 21:11
CPC Classifications
A; A61; A61K; A61K6/00; A61K6/80; A61K6/884; A61K6/887; Y; Y10; Y10S; Y10S522/00; Y10S522/908

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 252 words
A combined chemical-/light-polymerization type composition for dental restoration consisting of a formula A consisting essentially of (a) an ethylenically polymerizable unsaturated compound, (b) a photo-polymerization initiator and (c) a reducing agent, and a formulation B consisting essentially of (d) a filler and (e) an organic peroxide, said formulations A and B being separately packaged and designed to be mixed for use, wherein said photo-polymerization initiator consists of one or two or more ketal base compounds expressed in terms of the following formula 1: ##STR9## wherein X is H, Cl, an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, A is a six-membered aromatic group, and R is an alkyl group having 1 to 10 carbon atoms, an aralkyl group having 7 to 9 carbon atoms or C n H 2n O m R' in which n is an integer of 2 to 5, m is an integer of 1 to 5 and R' is an alkyl group having 1 to 5 carbon atoms, and one or two or more benzoin alkyl ether base compound of the following formula (4) ##STR10## wherein R is an alkyl group, R' is selected from the group consisting of a hydrogen atom, an alkyl group, and a halogen atom, and one or more R" may be present on the phenyl rings in that formula, or R" may be selected from the group consisting of an alkyl group, an alkoxy group, a halogen atom and an alkylamine group.
Claim 2
Dependent Claim 252 words
A combined chemical-/light-polymerization type composition for dental restoration consisting of a formula A consisting essentially of (a) an ethylenically polymerizable unsaturated compound, (b) a photo-polymerization initiator and (c) a reducing agent, and a formulation B consisting essentially of (d) a filler and (e) an organic peroxide, said formulations A and B being separately packaged and designed to be mixed for use, wherein said photo-polymerization initiator consists of one or two or more ketal base compounds expressed in terms of the following formula 1: ##STR9## wherein X is H, Cl, an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, A is a six-membered aromatic group, and R is an alkyl group having 1 to 10 carbon atoms, an aralkyl group having 7 to 9 carbon atoms or C n H 2n O m R' in which n is an integer of 2 to 5, m is an integer of 1 to 5 and R' is an alkyl group having 1 to 5 carbon atoms, and one or two or more benzoin alkyl ether base compound of the following formula (4) ##STR10## wherein R is an alkyl group, R' is selected from the group consisting of a hydrogen atom, an alkyl group, and a halogen atom, and one or more R" may be present on the phenyl rings in that formula, or R" may be selected from the group consisting of an alkyl group, an alkoxy group, a halogen atom and an alkylamine group.
Claim 3
Dependent Claim 25 words
The composition as defined in claim 1, wherein said ethylenically polymerizable unsaturated compound is one or two or more compounds having one ethylenically unsaturated double-bond.
Claim 4
Dependent Claim 27 words
The composition as defined in claim 1, wherein said ethylenically polymerizable unsaturated compound is one or two or more compounds having at least two ethylenically unsaturated double-bonds.
Claim 5
Dependent Claim 33 words
The composition as defined in claim 1, wherein said ethylenically polymerizable unsaturated compound comprises a mixture of the compound having one ethylenically unsaturated double-bond with that having at least two ethylenically unsaturated double-bonds.
Claim 6
Dependent Claim 32 words
The composition as defined in any one of claims 1, wherein said ethylenically polymerizable unsaturated compound is one or two or more compounds selected from the group consisting of methacrylates and acrylates.
Claim 7
Dependent Claim 33 words
The composition as defined in any one of claims 1, wherein the ketal base compound having the general formula 1 are any one benzil dimethyl ketal, benzil diethyl ketal, benzil-di(2-methoxyethyl)ketal and 4,4-dimethylbenzil-dimethyl ketal.
Claim 8
Dependent Claim 37 words
The composition as defined in any one of claims 1, wherein the concentration of the ketal base compound having the general formula 1 is 0.01 to 5 weight % with respect to the ethylenically polymerizable unsaturated compound.
Claim 9
Dependent Claim 23 words
The composition as defined in claim 1, wherein the benzoin alkyl ether base compound having the general formula 4 is benzoin isobutyl ether.
Claim 10
Dependent Claim 36 words
The composition as defined in any one of claims 1, wherein the reducing agent is any one or combinations of p-tolyl diethanolamine, m-tolyldiethanolamine, N,N'-dimethyl-p-toluidine, dimethylaminoethyl methacrylate, triethanolamine, 4-dimethylaminobenzoic acid methyl ester and 4-dimethylaminobenozic acid ethyl ester.
Claim 11
Dependent Claim 31 words
The composition as defined in any one of claims 1, wherein the concentration of the reducing agent is 0.01 to 5 wight % with respect to the ethylenically polymerizable unsaturated compound.
Claim 12
Dependent Claim 19 words
The composition as defined in any one of claims 1, wherein the filler is inorganic, organic, and/or composite thereof.
Claim 13
Dependent Claim 17 words
The composition as defined in any one of claims 1, wherein the organic peroxide is benzoyl peroxide.
Claim 14
Dependent Claim 28 words
The composition as defined in any one of claims 1, wherein the concentration of the organic peroxide is 0.01 to 5 weight % with respect to the filler.
Claim 15
Dependent Claim 33 words
The composition as defined in any one of claims 1, wherein the amount of the ethylenically polymerizable unsaturated compound is between 90 weight % and 10 weight % with respect to the filler.

References Cited (Backward Citations)

US4131529A Cited
US4269931A Cited
US4674980A Cited
JPS58204013A Cited
US4649062A Cited
US4771084A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-08-26 1995-02-25 1995-08-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-08-26 1999-02-25 1999-08-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-08-26 2003-02-25 2003-08-27 $7700.00 Window Closed / Lapsed

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