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US4771084A Expired / Lapsed US ⏱️ 0.0 years remaining

Light curing compositions for dental restoration

Assignee: GC Corp
•
Filing: 1986-09-11
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Granted: 1988-09-13
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Expires: 2006-09-11
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Abstract

Abstract A novel light curing composition for dental restoration comprises (a) a polymerizable compound containing at least one ethylenically unsaturated double-bond, (b) at least one photo-polymerization initiator selected from ketal base compounds defined hereinafter, (c) at least one photo-polymerization initiator selected from benzoin alkyl ether base compounds defined hereinafter, (d) a reducing agent and (e) a filler.

Inventors

  • 👤 Takao Kubota
  • 👤 Tetsuro Sakuma
  • 👤 Ryoji Nakazato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 10:35
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; A; A61; A61K; A61K6/00; A61K6/30; A61K6/80; A61K6/884; A61K6/887; A61K6/891; A61K6/893; A61K6/90; Y; Y10; Y10S; Y10S522/00; Y10S522/908

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 284 words
A light curing paste composition for dental restoration comprising the following five constitutional components: (a) a polymerizable compound containing at least one ethylenically unsaturated double-bond; a photo-polymerization initiator system consisting essentially of: (b) at least one photo-polymerization initiator selected from ketal base compounds expressed in terms of the following general formula (1): ##STR7## wherein X is H, Cl, an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, A is a six-membered aromatic group, and R is an alkyl group having 1 to 10 carbon atoms, an aralkyl group having 7 to 9 carbon atoms or a --C n H 2n O) m R' in which n is an integer of 2 to 5, m is an integer of 1 to 5, and R' is an alkyl group having 1 to 5 carbon atoms, in an amount of 0.01 to 5 weight % relative to polymerizable compound (a), and (c) at least one photo-polymerization initiator selected from benzoin alkyl ether base compounds expressed in terms of the following general formula (2): ##STR8## wherein R is an alkyl group, R' is selected from the group consisting of a hydrogen atom, and alkyl group, and a halogen atom, and R" is one or more groups which may optionally be present on the respective rings of that formula, and are selected from the group consisting of an alkyl group, an alkoxy group, a halogen atom and an alkylamino group, in an amount of 0.01 to 5 weight % relative to polymerizable compound (a); (d) a reducing agent other than (c) in an amount of 0.01 to 5 weight % relative to polymerizable compound (a); and (e) a filler.
Claim 2
Dependent Claim 284 words
A light curing paste composition for dental restoration comprising the following five constitutional components: (a) a polymerizable compound containing at least one ethylenically unsaturated double-bond; a photo-polymerization initiator system consisting essentially of: (b) at least one photo-polymerization initiator selected from ketal base compounds expressed in terms of the following general formula (1): ##STR7## wherein X is H, Cl, an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, A is a six-membered aromatic group, and R is an alkyl group having 1 to 10 carbon atoms, an aralkyl group having 7 to 9 carbon atoms or a --C n H 2n O) m R' in which n is an integer of 2 to 5, m is an integer of 1 to 5, and R' is an alkyl group having 1 to 5 carbon atoms, in an amount of 0.01 to 5 weight % relative to polymerizable compound (a), and (c) at least one photo-polymerization initiator selected from benzoin alkyl ether base compounds expressed in terms of the following general formula (2): ##STR8## wherein R is an alkyl group, R' is selected from the group consisting of a hydrogen atom, and alkyl group, and a halogen atom, and R" is one or more groups which may optionally be present on the respective rings of that formula, and are selected from the group consisting of an alkyl group, an alkoxy group, a halogen atom and an alkylamino group, in an amount of 0.01 to 5 weight % relative to polymerizable compound (a); (d) a reducing agent other than (c) in an amount of 0.01 to 5 weight % relative to polymerizable compound (a); and (e) a filler.
Claim 3
Dependent Claim 24 words
The composition as defined in claim 1, wherein said polymerizable compound containing at least one ethylenically unsaturated double-bond is a diacrylate and/or a dimethacrylate.
Claim 4
Dependent Claim 29 words
The composition as defined in claim 1 or 2, wherein said ketal base compound is any one of benzil dimethyl ketal, benzil diethyl ketal, benzil di(2-methoxyethyl)ketal and 4,4'-dimethylbenzil-dimethyl ketal.
Claim 5
Dependent Claim 18 words
The composition as defined in claim 1, wherein said benzoin alkyl ether base compound is benzoin isobutyl ether.
Claim 6
Dependent Claim 27 words
The composition as defined in claim 1, wherein said reducing agent is any one of dimethylaminoethyl methacrylate, triethanolamine, 4-dimethylaminobenzoic acid methyl ester and 4-dimethylaminobenzoic acid ethyl ester.

References Cited (Backward Citations)

US3801329A Cited
US4040925A Cited
US3992275A Cited
US4269931A Cited
GB1575873A Cited
US4271258A Cited
US4411625A Cited
CA1177301A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-13 1992-03-14 1992-09-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-13 1996-03-14 1996-09-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-13 2000-03-14 2000-09-13 $7700.00 Window Closed / Lapsed

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