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US5042288A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of sensing contamination in the atmosphere

Assignee: United States Department of the Army
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Filing: 1990-05-25
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Granted: 1991-08-27
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Expires: 2010-05-25
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Abstract

Abstract Contamination in the atmosphere is sensed and identified using unsealed d mode resonators and a means to clean the resonators in an ongoing method to measure contamination induced frequency change with time, while compensating for temperatures induced frequency shifts.

Inventors

  • 👤 John R. Vig

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 19:02
CPC Classifications
G; G01; G01N; G01N29/00; G01N29/02; G01N29/036

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 101 words
A continuous method of sensing contamination in the atmosphere in which the rate of change of frequency of an unsealed dual mode quartz crystal resonator is used to measure the rate of change of contamination induced by the adsorption of contaminant molecules, said method including the steps of: (A) cleaning the electrodes of the resonator, (B) allowing contamination from the atmosphere to be adsorbed onto the resonator and simultaneously measuring the rate of change of frequency to measure the rate of change of contamination until nearly a monolayer compensating for temperature induced frequency shifts, and (C) repeating steps (A) and (B).
Claim 2
Dependent Claim 101 words
A continuous method of sensing contamination in the atmosphere in which the rate of change of frequency of an unsealed dual mode quartz crystal resonator is used to measure the rate of change of contamination induced by the adsorption of contaminant molecules, said method including the steps of: (A) cleaning the electrodes of the resonator, (B) allowing contamination from the atmosphere to be adsorbed onto the resonator and simultaneously measuring the rate of change of frequency to measure the rate of change of contamination until nearly a monolayer compensating for temperature induced frequency shifts, and (C) repeating steps (A) and (B).
Claim 3
Dependent Claim 26 words
Method according to claim 1 where steps (A) and (B) are continuously repeated until it is no longer desired to sense the contamination in the atmosphere.
Claim 4
Dependent Claim 24 words
Method according to claim 1 wherein step (B) is carried out until 75 percent of a monolayer of contamination is adsorbed onto the resonator.
Claim 5
Dependent Claim 15 words
Method according to claim 1 wherein the electrodes are cleaned by the use of UV-ozone.
Claim 6
Dependent Claim 17 words
Method according to claim 1 wherein the method is used to sense toxic gas in the atmosphere.
Claim 7
Dependent Claim 19 words
Method according to claim 1 wherein the unsealed dual mode resonator is a 10 megahertz third overtone SC-cut resonator.
Claim 8
Dependent Claim 10 words
Method according to claim 1 wherein the electrodes are gold.
Claim 9
Dependent Claim 10 words
Method according to claim 1 wherein the electrodes are carbon.
Claim 10
Dependent Claim 14 words
Method according to claim 1 wherein the electrodes are selective for a particular contaminant.
Claim 11
Dependent Claim 118 words
A continuous method of sensing contamination in the atmosphere in which the rate of changes of frequency of multiple unsealed dual mode quartz crystal resonators, each with a different set of electrode surfaces, are used to measure the rate of change of contamination induced by the adsorption of contaminant molecules, said method including the steps of: (A) cleaning the electrodes of the resonators, (B) allowing contamination from the atmosphere to be adsorbed onto the resonators and simultaneously measuring the rate of change of frequency to measure the rate of change of contamination until nearly a monolayer of contamination has been adsorbed onto the resonators while compensating for temperature induced frequency shifts, and (C) repeating steps (A) and (B).
Claim 12
Dependent Claim 118 words
A continuous method of sensing contamination in the atmosphere in which the rate of changes of frequency of multiple unsealed dual mode quartz crystal resonators, each with a different set of electrode surfaces, are used to measure the rate of change of contamination induced by the adsorption of contaminant molecules, said method including the steps of: (A) cleaning the electrodes of the resonators, (B) allowing contamination from the atmosphere to be adsorbed onto the resonators and simultaneously measuring the rate of change of frequency to measure the rate of change of contamination until nearly a monolayer of contamination has been adsorbed onto the resonators while compensating for temperature induced frequency shifts, and (C) repeating steps (A) and (B).
Claim 13
Dependent Claim 16 words
Method according to claim 10 wherein the multiple unsealed resonators are a set of discrete resonators.
Claim 14
Dependent Claim 22 words
Method according to claim 10 wherein the multiple unsealed resonators are a single quartz substrate with multiple sets of electrodes on it.
Claim 15
Dependent Claim 24 words
Method according to claim 10 wherein the variations in frequency changes due to the desorbing-actions of UV-ozone are used to identify the contaminant gases.
Claim 16
Dependent Claim 17 words
Method according to claim 10 wherein a particle filter is included to filter out UV-ozone resistant contaminants.

References Cited (Backward Citations)

US3897992A Cited
US3981687A Cited
US4760351A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-08-26 1995-02-25 1995-08-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-08-26 1999-02-25 1999-08-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-08-26 2003-02-25 2003-08-27 $7700.00 Window Closed / Lapsed

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