Photocurable acrylate adhesive containing perester/tautomeric acid adhesion promoter

Claim 2

A liquid composition capable of reaction to an adhesive solid, when exposed to actinic radiation, comprising a major proportion of at least one polymerizable acrylate monomer and an elastomeric domain-providing filler, an effective amount of an actinic radiation-responsive photoinitiator and, based upon the weight of said composition about 1.0 to 5.0 percent of a perester compound having free radical-initiating capability and about 0.5 to 5.0 percent of an organic acid capable of cyclic tautomerism, said composition being free from stabilizers containing sulfur or the amine functionality.

Claim 3

A liquid composition capable of reaction to an adhesive solid, when exposed to actinic radiation, comprising a major proportion of at least one polymerizable acrylate monomer and an elastomeric domain-providing filler, an effective amount of an actinic radiation-responsive photoinitiator and, based upon the weight of said composition, about 1.0 to 5.0 percent of cumene hydroperoxide, and about 0.5 to 5.0 percent of an organic acid capable of cyclic tautomerism, said composition being free from stabilizers containing sulfur or the amine functionality.

Claim 4

A liquid composition capable of reaction to an adhesive solid, when exposed to actinic radiation, comprising a major proportion of at least one polymerizable acrylate monomer and an elastomeric domain-providing filler, an effective amount of an actinic radiation-responsive photoinitiator and, based upon the weight of said composition, about 1.0 to 5.0 percent of cumene hydroperoxide, and about 0.5 to 5.0 percent of an organic acid capable of cyclic tautomerism, said composition being free from stabilizers containing sulfur or the amine functionality.

Claim 5

A liquid composition capable of reaction to an adhesive solid when exposed to actinic radiation, comprising about 30 to 60 percent of at least one polymerizable acrylate monomer, about 5 to 60 percent of an acrylated polyurethane oligomer having a molecular weight of about 400 to 6000, about 1.0 to 5.0 percent of an ultraviolet radiation-responsive photoinitiator, about 2.0 to 6.0 percent of acrylic acid, about 2.0 to 4.0 percent of a compound selected from the class consisting of a perester compound having free radical-initiating capability and cumene hydroperoxide, and about 1.0 to 2.0 percent of an organic acid capable of cyclic tautomerism, all based upon the weight of said compound, said composition being free from stabilizers containing sulfur or the amine functionality.

Claim 6

A liquid composition capable of reaction to an adhesive solid when exposed to actinic radiation, comprising about 30 to 60 percent of at least one polymerizable acrylate monomer, about 5 to 60 percent of an acrylated polyurethane oligomer having a molecular weight of about 400 to 6000, about 1.0 to 5.0 percent of an ultraviolet radiation-responsive photoinitiator, about 2.0 to 6.0 percent of acrylic acid, about 2.0 to 4.0 percent of a compound selected from the class consisting of a perester compound having free radical-initiating capability and cumene hydroperoxide, and about 1.0 to 2.0 percent of an organic acid capable of cyclic tautomerism, all based upon the weight of said compound, said composition being free from stabilizers containing sulfur or the amine functionality.

Claim 7

A liquid composition capable of reaction to an adhesive solid, when exposed to actinic radiation, comprising a major proportion of at least one polymerizable acrylate monomer and an elastomeric domain-providing filler, an effective amount of an actinic radiation-responsive photoinitiator and, based upon the weight of said composition, about 1.0 to 5.0 percent of tert-butyl peroctoate and about 0.5 to 5.0 percent of an organic acid capable of cyclic tautomerism, said composition being free from stabilizers containing sulfur or the amine functionality.

Claim 8

A liquid composition capable of reaction to an adhesive solid, when exposed to actinic radiation, comprising a major proportion of at least one polymerizable acrylate monomer and an elastomeric domain-providing filler, an effective amount of an actinic radiation-responsive photoinitiator and, based upon the weight of said composition, about 1.0 to 5.0 percent of tert-butyl peroctoate and about 0.5 to 5.0 percent of an organic acid capable of cyclic tautomerism, said composition being free from stabilizers containing sulfur or the amine functionality.

Claim 9

The composition of claims 1 or 3 wherein said perester compound is selected from the group consisting of tert-butyl perbenzoate and tert-butyl peroctoate, and wherein said organic acid is maleic.

Claim 10

The composition of claims 1 or 2 or 4 wherein said filler is an acrylated polyurethane oligomer.

Claim 11

The composition of claim 6 wherein said oligomer has a molecular weight of about 400 to 6000, and is a diisocyanate-capped polyether acrylated by reaction with hydroxyethyl acrylate or hydroxyethyl methacrylate.

Claim 12

The composition of claims 1 or 2 or 3 or 4 wherein said acrylate monomer is a compound selected from the group consisting of isobornyl acrylate, hydroxyethyl methacrylate, polyethyleneglycol dimethacrylate, trimethylcyclohexyl acrylate, and mixtures thereof.

Claim 13

The composition of claims 1 or 2 or 3 or 4 wherein said photoinitiator is a compound selected from the group consisting of diethoxy acetophenone, 1-hydroxy-cyclohexylphenyl ketone, 2-methyl-1-(methylthiophenyl)-2-(4-morpholinyl)-1-propanone, and 2,2-dimethoxy-2-phenyl acetophenone.

Claim 14

The composition of claims 1 or 2 or 4 additionally including about 2.0 to 6.0 percent by weight thereof of acrylic acid.