US5034356A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Ceramic matrix composite
Assignee: General Electric Co
•
Filing: 1989-08-07
•
Granted: 1991-07-23
•
Expires: 2009-08-07
Abstract
Abstract A ceramic composite is produced wherein the matrix is comprised of silicon nitride and cordierite and the reinforcing phase is comprised of Si-C-containing fibers.
Inventors
- 👤 Milivoj K. Brun
- 👤 Brady A. Jones
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 19:06
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/515; C04B35/58; C04B35/584; C04B35/593; C04B35/71; C04B35/78; C04B35/80
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
276 words
A process for producing a solid composite comprised of a ceramic matrix and at least a layer of a plurality of continuous Si-C-containing fibers which comprises forming a slurry of a matrix-forming material comprised of a particulate mixture of silicon nitride and a member selected from the group consisting of cordierite, a cordierite-forming composition, and combinations thereof wherein said member ranges from 1% to 50% by weight of said particulate mixture, providing at least a layer of a plurality of continuous fibers comprised of a Si-C containing material containing at least 50% by weight of silicon and at least 25% by weight of carbon based on the weight of said Si-C containing material, producing a wet preform comprised of said fibers coated with the wet solids of said slurry wherein the coated fibers in each layer are substantially parallel to each other and wherein the coatings prevent significant direct contact between the fibers, drying said wet preform to produce a dry preform comprised of said matrix-forming material and said fibers, and hot compressing the resulting preform or a sample thereof under a sufficient pressure at a temperature sufficient to generate sufficient liquid phase to sinter said silicon nitride and produce a sintered product, said compression temperature ranging from 1200° C. to 1750° C., and cooling said sintered product producing said solid composite, said composite having a porosity of less than 5% by volume, said composite containing no significant amount of reaction product of said fibers and said matrix, said matrix having a thermal expansion coefficient which is lower than that of said fibers, at least 10% by volume of said composite being comprised of said fibers.
Claim 2
Dependent Claim
276 words
A process for producing a solid composite comprised of a ceramic matrix and at least a layer of a plurality of continuous Si-C-containing fibers which comprises forming a slurry of a matrix-forming material comprised of a particulate mixture of silicon nitride and a member selected from the group consisting of cordierite, a cordierite-forming composition, and combinations thereof wherein said member ranges from 1% to 50% by weight of said particulate mixture, providing at least a layer of a plurality of continuous fibers comprised of a Si-C containing material containing at least 50% by weight of silicon and at least 25% by weight of carbon based on the weight of said Si-C containing material, producing a wet preform comprised of said fibers coated with the wet solids of said slurry wherein the coated fibers in each layer are substantially parallel to each other and wherein the coatings prevent significant direct contact between the fibers, drying said wet preform to produce a dry preform comprised of said matrix-forming material and said fibers, and hot compressing the resulting preform or a sample thereof under a sufficient pressure at a temperature sufficient to generate sufficient liquid phase to sinter said silicon nitride and produce a sintered product, said compression temperature ranging from 1200° C. to 1750° C., and cooling said sintered product producing said solid composite, said composite having a porosity of less than 5% by volume, said composite containing no significant amount of reaction product of said fibers and said matrix, said matrix having a thermal expansion coefficient which is lower than that of said fibers, at least 10% by volume of said composite being comprised of said fibers.
Claim 3
Dependent Claim
20 words
The process according to claim 1, wherein said cordierite ranges from 5% to 25% by weight of said particulate mixture.
Claim 4
Dependent Claim
48 words
The process according to claim 1, wherein said Si-C-containing material is selected from the group consisting of silicon carbide, Si-C-O, Si-C-O-N, Si-C-O-Metal, Si-C-O-N-Metal, and mixtures thereof, wherein said O, N and metal are each present at least in an amount of 1% by weight of said Si-C-containing material.
Claim 5
Dependent Claim
13 words
The process according to claim 1, wherein said Si-C-containing material surrounds a core.
Claim 6
Dependent Claim
17 words
The process according to claim 1, wherein said fibers have a diameter greater than about 5 microns.
Claim 7
Dependent Claim
27 words
The process according to claim 1, wherein said matrix-forming material includes silicon carbide whiskers in an amount ranging to about 30% by weight of said matrix-forming material.
Claim 8
Dependent Claim
16 words
The process according to claim 1, wherein said Si-C containing material is comprised of silicon carbide.
Claim 9
Dependent Claim
16 words
The process according to claim 1, wherein said hot compressing is carried out by hot pressing.
Claim 10
Dependent Claim
52 words
The process according to claim 1, wherein said resulting preform or a sample thereof is encapsulated within a material which is pressure- and heat-transmitting at said compression temperature, wherein said hot compression is carried out by hot isostatic pressing, and wherein said encapsulating material has no significant deleterious effect on said composite.
Claim 11
Dependent Claim
267 words
A composite comprised of a ceramic matrix and a plurality of layers of continuous Si-C-containing fibers embedded in said matrix with no significant contact between said layers of fibers, said matrix leaving no significant portion of said Si-C-containing fibers embedded therein exposed, each said layer being comprised of a plurality of said continuous fibers, said Si-C-containing fibers comprising at least 10% by volume of said composite, said fibers being comprised of an Si-C-containing material containing at least 50% by weight of silicon and at least 25% weight of carbon based on the weight of said Si-C-containing material, each said Si-C-containing fiber having a diameter greater than 5 microns and a length at least ten times its diameter, said continuous fibers having a length greater than 1000 microns, more than 90% by volume of said fibers in each layer being spaced from each other and being at least substantially parallel to each other, said matrix being comprised of a mixture of silicon nitride, cordierite, and silicon carbide whiskers, said cordierite ranging from 1% to 50% by weight of the total amount of said silicon nitride and said cordierite, said whiskers ranging to 30% by weight of said matrix, said matrix being continuous and in direct contact with said fibers, said composite having a porosity of less than 5% by volume, said composite containing no significant amount of reaction product of said fibers and said matrix, said matrix having a thermal expansion coefficient which is lower than that of said fibers, said fibers preventing brittle fracture of said composite at a temperature ranging from 15° C. to 30° C.
Claim 12
Dependent Claim
267 words
A composite comprised of a ceramic matrix and a plurality of layers of continuous Si-C-containing fibers embedded in said matrix with no significant contact between said layers of fibers, said matrix leaving no significant portion of said Si-C-containing fibers embedded therein exposed, each said layer being comprised of a plurality of said continuous fibers, said Si-C-containing fibers comprising at least 10% by volume of said composite, said fibers being comprised of an Si-C-containing material containing at least 50% by weight of silicon and at least 25% weight of carbon based on the weight of said Si-C-containing material, each said Si-C-containing fiber having a diameter greater than 5 microns and a length at least ten times its diameter, said continuous fibers having a length greater than 1000 microns, more than 90% by volume of said fibers in each layer being spaced from each other and being at least substantially parallel to each other, said matrix being comprised of a mixture of silicon nitride, cordierite, and silicon carbide whiskers, said cordierite ranging from 1% to 50% by weight of the total amount of said silicon nitride and said cordierite, said whiskers ranging to 30% by weight of said matrix, said matrix being continuous and in direct contact with said fibers, said composite having a porosity of less than 5% by volume, said composite containing no significant amount of reaction product of said fibers and said matrix, said matrix having a thermal expansion coefficient which is lower than that of said fibers, said fibers preventing brittle fracture of said composite at a temperature ranging from 15° C. to 30° C.
Claim 13
Dependent Claim
25 words
The composite according to claim 10, wherein said cordierite ranges from 5% to 25% by weight of the amount of said silicon nitride and cordierite.
Claim 14
Dependent Claim
52 words
The composite according to claim 10, wherein said Si-C-containing material is comprised of a material selected from the group consisting of silicon carbide, Si-C-O, Si-C-O-N, Si-C-O-Metal, Si-C-O-Metal and mixtures thereof, wherein said O, N and Metal are each present at least in an amount of 1% by weight of said Si-C-containing material.
Claim 15
Dependent Claim
13 words
The composite according to claim 10, wherein said Si-C-containing material surrounds a core.
Claim 16
Dependent Claim
15 words
The composite according to claim 10, wherein said Si-C-containing material is comprised of silicon carbide.
Claim 17
Dependent Claim
33 words
The composite according to claim 10, which contains a plurality of layers and said fibers in a layer extend in a direction different from that of the fibers in another of said layers.
Claim 18
Dependent Claim
21 words
The composite according to claim 10, wherein said silicon carbide whiskers range from 10% to 25% by weight of said matrix.
Claim 19
Dependent Claim
13 words
The process according to claim 1, wherein said Si-C-containing material envelops a core.
Claim 20
Dependent Claim
13 words
The composite according to claim 10, wherein said Si-C-containing material envelops a core.
References Cited (Backward Citations)
US4540674A
Cited
US4542109A
Cited
US4585500A
Cited
US4528275A
Cited
US4689188A
Cited
US4781993A
Cited
US4855262A
Cited
US4886682A
Cited
US4915760A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-07-22 | 1995-01-21 | 1995-07-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-07-22 | 1999-01-21 | 1999-07-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-07-22 | 2003-01-21 | 2003-07-23 | $7700.00 | Window Closed / Lapsed |