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US5030548A
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Photo-polymerizable composition
Assignee: Fujifilm Holdings Corp
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Filing: 1989-08-10
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Granted: 1991-07-09
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Expires: 2009-08-10
Abstract
Abstract A photo-polymerizable composition is disclosed, which comprises a thermoplastic polymeric binder; a non-gaseous ethylenically unsaturated compound; a photo-polymerization initiator system composed of 4,4'-bis(dialkylamino)benzophenone, aromatic ketone and lophine dimer; an organic halogen compound; and a leuco dye.
Inventors
- 👤 Sadao Fujikura
- 👤 Masayuki Iwasaki
- 👤 Minoru Maeda
- 👤 Minoru Wada
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 16:39
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/09; G03F7/105; G03F7/027; G03F7/028; G03F7/029; G03F7/0295; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106; Y10S430/108; Y10S430/111; Y10S430/114; Y10S430/117; Y10S430/12; Y10S430/121; Y10S430/126
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
249 words
A photo-polymerizable composition which comprises: a thermoplastic polymeric binder; a non-gaseous ethylenically unsaturated compound; a photo-polymerization initiator system comprised of 4,4'-bis(dialkylamino)benzophenone, aromatic ketone and lophine dimer; an organic halogen compound; and a leuco dye, wherein said organic halogen compound is selected from the compounds represented by the following formulae IIIa to IIIe: ##STR7## wherein A 1 r represents a substituted or unsubstituted phenyl or a substituted or unsubstituted naphthyl group, and Z represents a chlorine atom or a bromine atom; ##STR8## wherein A 2 r represents a substituted or unsubstituted aryl group, W represents a hydrogen atom or a C 1 to C 20 alkyl or a C 6 to C 20 aryl group, and Z represents a chlorine atom or a bromine atom; A.sup.3 r--SO.sub.2 CZ.sub.3 IIIc wherein A 3 r represents a substituted or unsubstituted phenyl or a substituted or unsubstituted naphthyl group, and Z represents a chlorine atom or a bromine atom; ##STR9## wherein Z represents a chlorine atom or a bromine atom; and ##STR10## wherein R 2 represents CZ 3 or a substituted or unsubstituted phenyl or a substituted or unsubstituted naphthyl group, R 3 represents CA 3 , NH 2 , NHR 4 , N(R 4 ) 2 , SR 4 , OR 4 or R 4 , R 4 represents a C 1 to C 20 alkyl, a C 6 to C 20 aryl or a C 2 to C 20 alkenyl group, and Z represents a chlorine atom or a bromine atom.
Claim 2
Dependent Claim
249 words
A photo-polymerizable composition which comprises: a thermoplastic polymeric binder; a non-gaseous ethylenically unsaturated compound; a photo-polymerization initiator system comprised of 4,4'-bis(dialkylamino)benzophenone, aromatic ketone and lophine dimer; an organic halogen compound; and a leuco dye, wherein said organic halogen compound is selected from the compounds represented by the following formulae IIIa to IIIe: ##STR7## wherein A 1 r represents a substituted or unsubstituted phenyl or a substituted or unsubstituted naphthyl group, and Z represents a chlorine atom or a bromine atom; ##STR8## wherein A 2 r represents a substituted or unsubstituted aryl group, W represents a hydrogen atom or a C 1 to C 20 alkyl or a C 6 to C 20 aryl group, and Z represents a chlorine atom or a bromine atom; A.sup.3 r--SO.sub.2 CZ.sub.3 IIIc wherein A 3 r represents a substituted or unsubstituted phenyl or a substituted or unsubstituted naphthyl group, and Z represents a chlorine atom or a bromine atom; ##STR9## wherein Z represents a chlorine atom or a bromine atom; and ##STR10## wherein R 2 represents CZ 3 or a substituted or unsubstituted phenyl or a substituted or unsubstituted naphthyl group, R 3 represents CA 3 , NH 2 , NHR 4 , N(R 4 ) 2 , SR 4 , OR 4 or R 4 , R 4 represents a C 1 to C 20 alkyl, a C 6 to C 20 aryl or a C 2 to C 20 alkenyl group, and Z represents a chlorine atom or a bromine atom.
Claim 3
Dependent Claim
21 words
A photo-polymerizable composition as in claim 1, wherein said thermoplastic polymeric binder has a molecular weight of from 5,000 to 2,000,000.
Claim 4
Dependent Claim
32 words
A photo-polymerizable composition as in claim 1, wherein said thermoplastic polymeric binder is present in an amount of 5 to 95 weight percent based on the solid components of the photo-polymerizable composition.
Claim 5
Dependent Claim
34 words
A photo-polymerizable composition as in claim 1, wherein said non-gaseous ethylenically unsaturated compound is a compound which has at least two terminal unsaturated groups and which can be photo-polymerized by irradiation with actinic radiation.
Claim 6
Dependent Claim
25 words
A photo-polymerizable composition as in claim 1, wherein said non-gaseous ethylenically unsaturated compound is present in an amount of from 5 to 90 weight percent.
Claim 7
Dependent Claim
86 words
A photo-polymerizable composition as in claim 1, wherein said 4,4'-bis(dialkylamino)benzophenone is present in an amount of from 0.01 weight percent to 1 weight percent based on the solid components of the photo-polymerizable composition, said aromatic ketone is present in an amount of from 0.1 weight percent to 10 weight percent based on the solid components of the photo-polymerizable composition, and said lophine dimer is present in an amount of from 0.1 weight percent to 10 weight percent based on the solid components of the photo-polymerizable composition.
Claim 8
Dependent Claim
86 words
A photo-polymerizable composition as in claim 1, wherein said 4,4'-bis(dialkylamino)benzophenone is present in an amount of from 0.05 weight percent to 0.5 weight percent based on the solid components of the photo-polymerizable composition, said aromatic ketone is present in an amount of from 0.5 weight percent to 5.0 weight percent based on the solid components of the photo-polymerizable composition, and said lophine dimer is present in an amount of from 0.5 weight percent to 5.0 weight percent based on the solid components of the photo-polymerizable composition.
Claim 9
Dependent Claim
35 words
A photo-polymerizable composition as in claim 1, wherein said organic halogen compound is present in an amount of from 0.001 weight percent to 5 weight percent based on the solid components of the photo-polymerizable composition.
Claim 10
Dependent Claim
35 words
A photo-polymerizable composition as in claim 1, wherein said organic halogen compound is present in an amount of from 0.005 weight percent to 1 weight percent based on the solid components of the photo-polymerizable composition.
Claim 11
Dependent Claim
25 words
A photo-polymerizable composition as in claim 1, wherein said organic halogen compound is a compound having 3 halogen atoms bound to the same carbon atom.
Claim 12
Dependent Claim
20 words
A photo-polymerizable composition as in claim 1, wherein said organic halogen compound is selected from tribromomethyl phenyl sulphone and 2,4-bis(trichloromethyl)-6-phenyltriazole.
Claim 13
Dependent Claim
32 words
A photo-polymerizable composition as in claim 1, wherein the leuco dyes are present in an amount of from 0.01 to 10 weight percent based on the solid components of the photo-polymerizable composition.
Claim 14
Dependent Claim
44 words
A photo-polymerizable composition which comprises: a thermoplastic polymeric binder; a non-gaseous ethylenically unsaturated compound; a photo-polymerizable initiator system comprised of 4,4'-bis(dialklamino)benzophenone, aromatic ketone and lophine dimer; an organic halogen compound having three halogen atoms bound to the same carbon atom; and a leuco dye.
Claim 15
Dependent Claim
44 words
A photo-polymerizable composition which comprises: a thermoplastic polymeric binder; a non-gaseous ethylenically unsaturated compound; a photo-polymerizable initiator system comprised of 4,4'-bis(dialklamino)benzophenone, aromatic ketone and lophine dimer; an organic halogen compound having three halogen atoms bound to the same carbon atom; and a leuco dye.
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