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US5013781A
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US
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Gasket/packing material with excellent adhesiveness and resistance to coolants
Assignee: DuPont Toray Specialty Materials KK
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Filing: 1987-08-13
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Granted: 1991-05-07
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Expires: 2007-08-13
Abstract
Abstract A gasket and packing material which exhibits excellent adhesiveness to substrates and resistances to degradation of properties when exposed to hot hydrocarbon oils and coolants such as used in an automobile radiator are made by curing a composition which contains polydimethylsiloxane, an organopolysiloxane having R'3SiO0.5 and SiO2 units or R'3SiO0.5, R'2SiO, and SiO2 units, an inorganic filler, an alkoxysilane adhesion promoter, and a ketoxime silicon compound crosslinker.
Inventors
- 👤 Taro Koshii
- 👤 Tetsuo Amemiya
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 21:29
CPC Classifications
C; C09; C09K; C09K3/00; C09K3/10; C09K3/1006; C09K3/1018; C08; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/16; C08G77/22; C08G77/24; C08G77/26; Y; Y10; Y10S; Y10S528/00; Y10S528/901
Claims Analysis
Total Claims: 3
Claim 1
Independent Claim
167 words
A room temperature-curing composition consisting essentially of a product obtained by mixing (i) 100 weight parts of an essentially linear polydimethylsiloxane having silicon-bonded hydroxyl group at the molecular terminals and having a viscosity of 0.005 to 0.05 m 2 /s at 25° C., (ii) 10 to 45 weight parts organopolysiloxane composed of R' 3 SiO 0 .5, R' 2 SiO, and SiO 2 units where each R' represents methyl, and in which the R' 3 SiO 0 .5 unit/R' 2 SiO/SiO 2 unit molar ratio is 0.7-1:0.01-0.5:1, (iii) 10 to 150 weight parts inorganic filler, (iv) 1 to 3 weight parts alkoxysilane selected from the group consisting of methyltrimethyoxysilane, vinyltrimethyoxysilane, gamma-glycidoxypropyltrimethyoxysilane, di(methyl ethyl ketoxime)diethoxysilane, and gamma-mercaptopropyltrimethoxysilane, and (v) 10 to 25 weight parts of a silicon compound selected from the group consisting of vinyltris(methyl ethyl ketoxime)silane, methyltris(methyl ethyl ketoxime)silane, tetrakis(methyl ethyl ketoxime)silane, and mixtures thereof to make compositions curable at room temperature to elastomeric solids which exhibit resistance to loss of properties upon exposure to radiator coolant.
Claim 2
Dependent Claim
167 words
A room temperature-curing composition consisting essentially of a product obtained by mixing (i) 100 weight parts of an essentially linear polydimethylsiloxane having silicon-bonded hydroxyl group at the molecular terminals and having a viscosity of 0.005 to 0.05 m 2 /s at 25° C., (ii) 10 to 45 weight parts organopolysiloxane composed of R' 3 SiO 0 .5, R' 2 SiO, and SiO 2 units where each R' represents methyl, and in which the R' 3 SiO 0 .5 unit/R' 2 SiO/SiO 2 unit molar ratio is 0.7-1:0.01-0.5:1, (iii) 10 to 150 weight parts inorganic filler, (iv) 1 to 3 weight parts alkoxysilane selected from the group consisting of methyltrimethyoxysilane, vinyltrimethyoxysilane, gamma-glycidoxypropyltrimethyoxysilane, di(methyl ethyl ketoxime)diethoxysilane, and gamma-mercaptopropyltrimethoxysilane, and (v) 10 to 25 weight parts of a silicon compound selected from the group consisting of vinyltris(methyl ethyl ketoxime)silane, methyltris(methyl ethyl ketoxime)silane, tetrakis(methyl ethyl ketoxime)silane, and mixtures thereof to make compositions curable at room temperature to elastomeric solids which exhibit resistance to loss of properties upon exposure to radiator coolant.
Claim 3
Dependent Claim
40 words
The composition in accordance with claim 1 in which the silicon compound is a mixture of methyltris(methyl ethyl ketoxime)silane and vinyltris(methyl ethy ketoxime)silane, the alkoxysilane is gamma- glycidoxypropyltrimethoxysilane, the inorganic filler is fumed silica, and there is also present dibutyltindilaurate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-05-06 | 1994-11-05 | 1995-05-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-05-06 | 1998-11-05 | 1999-05-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-05-06 | 2002-11-05 | 2003-05-07 | $7700.00 | Window Closed / Lapsed |