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US5013781A Expired / Lapsed US ⏱️ 0.0 years remaining

Gasket/packing material with excellent adhesiveness and resistance to coolants

Assignee: DuPont Toray Specialty Materials KK
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Filing: 1987-08-13
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Granted: 1991-05-07
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Expires: 2007-08-13
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Abstract

Abstract A gasket and packing material which exhibits excellent adhesiveness to substrates and resistances to degradation of properties when exposed to hot hydrocarbon oils and coolants such as used in an automobile radiator are made by curing a composition which contains polydimethylsiloxane, an organopolysiloxane having R'3SiO0.5 and SiO2 units or R'3SiO0.5, R'2SiO, and SiO2 units, an inorganic filler, an alkoxysilane adhesion promoter, and a ketoxime silicon compound crosslinker.

Inventors

  • 👤 Taro Koshii
  • 👤 Tetsuo Amemiya

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 20:59
CPC Classifications
C; C09; C09K; C09K3/00; C09K3/10; C09K3/1006; C09K3/1018; C08; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/16; C08G77/22; C08G77/24; C08G77/26; Y; Y10; Y10S; Y10S528/00; Y10S528/901

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 167 words
A room temperature-curing composition consisting essentially of a product obtained by mixing (i) 100 weight parts of an essentially linear polydimethylsiloxane having silicon-bonded hydroxyl group at the molecular terminals and having a viscosity of 0.005 to 0.05 m 2 /s at 25° C., (ii) 10 to 45 weight parts organopolysiloxane composed of R' 3 SiO 0 .5, R' 2 SiO, and SiO 2 units where each R' represents methyl, and in which the R' 3 SiO 0 .5 unit/R' 2 SiO/SiO 2 unit molar ratio is 0.7-1:0.01-0.5:1, (iii) 10 to 150 weight parts inorganic filler, (iv) 1 to 3 weight parts alkoxysilane selected from the group consisting of methyltrimethyoxysilane, vinyltrimethyoxysilane, gamma-glycidoxypropyltrimethyoxysilane, di(methyl ethyl ketoxime)diethoxysilane, and gamma-mercaptopropyltrimethoxysilane, and (v) 10 to 25 weight parts of a silicon compound selected from the group consisting of vinyltris(methyl ethyl ketoxime)silane, methyltris(methyl ethyl ketoxime)silane, tetrakis(methyl ethyl ketoxime)silane, and mixtures thereof to make compositions curable at room temperature to elastomeric solids which exhibit resistance to loss of properties upon exposure to radiator coolant.
Claim 2
Dependent Claim 167 words
A room temperature-curing composition consisting essentially of a product obtained by mixing (i) 100 weight parts of an essentially linear polydimethylsiloxane having silicon-bonded hydroxyl group at the molecular terminals and having a viscosity of 0.005 to 0.05 m 2 /s at 25° C., (ii) 10 to 45 weight parts organopolysiloxane composed of R' 3 SiO 0 .5, R' 2 SiO, and SiO 2 units where each R' represents methyl, and in which the R' 3 SiO 0 .5 unit/R' 2 SiO/SiO 2 unit molar ratio is 0.7-1:0.01-0.5:1, (iii) 10 to 150 weight parts inorganic filler, (iv) 1 to 3 weight parts alkoxysilane selected from the group consisting of methyltrimethyoxysilane, vinyltrimethyoxysilane, gamma-glycidoxypropyltrimethyoxysilane, di(methyl ethyl ketoxime)diethoxysilane, and gamma-mercaptopropyltrimethoxysilane, and (v) 10 to 25 weight parts of a silicon compound selected from the group consisting of vinyltris(methyl ethyl ketoxime)silane, methyltris(methyl ethyl ketoxime)silane, tetrakis(methyl ethyl ketoxime)silane, and mixtures thereof to make compositions curable at room temperature to elastomeric solids which exhibit resistance to loss of properties upon exposure to radiator coolant.
Claim 3
Dependent Claim 40 words
The composition in accordance with claim 1 in which the silicon compound is a mixture of methyltris(methyl ethyl ketoxime)silane and vinyltris(methyl ethy ketoxime)silane, the alkoxysilane is gamma- glycidoxypropyltrimethoxysilane, the inorganic filler is fumed silica, and there is also present dibutyltindilaurate.

References Cited (Backward Citations)

US3829529A Cited
US4191817A Cited
US4257932A Cited
US4399267A Cited
US4680363A Cited
US4485206A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-05-06 1994-11-05 1995-05-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-05-06 1998-11-05 1999-05-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-05-06 2002-11-05 2003-05-07 $7700.00 Window Closed / Lapsed

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