Patent US5006364A successfully refreshed from Google Patents.
US5006364A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Solid imaging method utilizing compositions comprising thermally coalescible materials
Assignee: DSM IP Assets BV
•
Filing: 1989-08-24
•
Granted: 1991-04-09
•
Expires: 2009-08-24
Abstract
Abstract A solid imaging method utilizing photoformable compositions comprising thermally coalescible materials for producing multilayer models and prototypes having improved structural properties and resolution.
Inventors
- 👤 Roxy N. Fan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 12:45
CPC Classifications
G; G03; G03C; G03C9/00; G03F; G03F7/00; G03F7/0037; B; B29; B29C; B29C64/00; B29C64/10; B29C64/106; B29C64/124; B29C64/129; B29C64/135; B29C35/00; B29C35/02; B29C35/08; B29C35/0805; Y; Y10; Y10S; Y10S430/00; Y10S430/148
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
209 words
A method for accurately fabricating an integral three dimensional object from a multiplicity of contiguous layers of a thermally coalescible photoformable liquid composition comprising the steps of: (a) forming a layer of a thermally coalescible photoformable liquid on a substrate; (b) imagewise exposing areas of at least a portion of the layer to actinic radiation; (c) introducing a new layer of liquid onto the layer previously exposed imagewise to actinic radiation according to step (b); (d) imagewise exposing areas of at least a portion of the new liquid layer to actinic radiation, with the requirement that the photoformable composition comprises a thermally coalescible polymeric cohesive material, a photohardenable monomer, and a photoinitiator, wherein after the exposure to the acthnic radiation, the photoformed areas of the composition remain thermally coalescible; (e) successively repeating steps (c) and (d) until all layers of the three dimensional object have been photoformed and connected through joining surfaces; and (f) in sequence (i) removing the unexposed portion of the photoformable composition from the exposed portion of the three dimensional object, and (ii) thermally coalescing the three dimensional object in order to promote cohesion both within the contiguous layers and at the joining surfaces between the contiguous layers, thus producing a single coalesced three dimensional object.
Claim 2
Independent Claim
209 words
A method for accurately fabricating an integral three dimensional object from a multiplicity of contiguous layers of a thermally coalescible photoformable liquid composition comprising the steps of: (a) forming a layer of a thermally coalescible photoformable liquid on a substrate; (b) imagewise exposing areas of at least a portion of the layer to actinic radiation; (c) introducing a new layer of liquid onto the layer previously exposed imagewise to actinic radiation according to step (b); (d) imagewise exposing areas of at least a portion of the new liquid layer to actinic radiation, with the requirement that the photoformable composition comprises a thermally coalescible polymeric cohesive material, a photohardenable monomer, and a photoinitiator, wherein after the exposure to the acthnic radiation, the photoformed areas of the composition remain thermally coalescible; (e) successively repeating steps (c) and (d) until all layers of the three dimensional object have been photoformed and connected through joining surfaces; and (f) in sequence (i) removing the unexposed portion of the photoformable composition from the exposed portion of the three dimensional object, and (ii) thermally coalescing the three dimensional object in order to promote cohesion both within the contiguous layers and at the joining surfaces between the contiguous layers, thus producing a single coalesced three dimensional object.
Claim 3
Dependent Claim
19 words
A method as defined in claim 1, wherein at least one of the layers has also an infraposed surface.
Claim 4
Dependent Claim
16 words
A method as defined in claim 2, wherein the photohardenable monomer comprises an ethylenically unsaturated monomer.
Claim 5
Dependent Claim
29 words
A method as defined in claim 3, wherein the ethylenically unsaturated monomer is selected from the group consisting of unsaturated bisphenol A oligomers, unsaturated urethane oligomers, and mixtures thereof.
Claim 6
Dependent Claim
19 words
A method as defined in claim 2, wherein the removing step (f)(i) is performed with a poor non-coalescing solvent.
Claim 7
Dependent Claim
15 words
A method as defined in claim 2, wherein the actinic radiation comprises a laser beam.
Claim 8
Dependent Claim
22 words
A method as defined in claim 2, wherein the thermally coalescible material comprises a plastisol containing a polymer and a thermal plasticizer.
Claim 9
Dependent Claim
34 words
A method as defined in claim 7, wherein the polymer is selected from the group consisting of polyvinyl halide, polyvinyl halide acetate, polyvinylidene halide, polyvinylidene halide acetate, polyphenylene oxide, polyvinyl acetal, and mixtures thereof.
Claim 10
Dependent Claim
22 words
A method as defined in claim 8, wherein the halide is selected from the group consisting of chloride, fluoride, and mixtures thereof.
Claim 11
Dependent Claim
29 words
A method as defined in claim 9, wherein the ethylenically unsaturated monomer is selected from the group consisting of unsaturated bisphenol A oligomers, unsaturated urethane oligomers, and mixtures thereof.
Claim 12
Dependent Claim
15 words
A method as defined in claim 9, wherein the actinic radiation comprises a laser beam.
Claim 13
Dependent Claim
13 words
A method as defined in claim 7, wherein the thermal plasticizer is non-polymerizable.
Claim 14
Dependent Claim
16 words
A method as defined in claim 7, wherein the photoformable liquid composition further comprises reinforcement fibers.
Claim 15
Dependent Claim
16 words
A method as defined in claim 7, wherein the unsaturated monomer constitutes part of the polymer.
Claim 16
Dependent Claim
15 words
A method as defined in claim 14, wherein the photoinitiator constitutes part of the polymer.
Claim 17
Dependent Claim
24 words
A method as defined in claim 7, wherein the polymer is selected from the group consisting of acrylic polymers, methacrylic polymers, and mixtures thereof.
Claim 18
Dependent Claim
135 words
A method as defined in claim 1, further comprising the steps of: repeating the steps used in the method of claim 1 in order to fabricate at least one additional single integral three-dimensional object, each single object thus fabricated having at least one first preselected matching surface intended to match a second matching surface, the second surface being part of at least one other single object; applying a coating of thermally coalescible composition on at least one of the first and second matching surfaces; bringing the first matching surfaces in contact with the second matching surfaces; and thermally coalescing the coating of the thermally coalescible composition within the first and second matching surfaces in order to form a strong bond between the first and second surfaces, thus completing the fabrication of an integral complex object.
Claim 19
Dependent Claim
112 words
A method as defined in claim 1, further comprising the steps of: repeating the steps used in the method of claim 1, except step (f)(ii) in order to fabricate at least one uncoalesced single integral three dimensional object, each uncoalesced single object thus fabricated having at least one third matching surface intended to match a fourth matching surface, the fourth matching surface being part of at least one other single object; bringing the third matching surfaces in contact with the fourth matching surfaces; and thermally coalescing the uncoalesced single object in order to form a strong bond between the first and second surfaces, thus completing the fabrication of an integral complex object.
References Cited (Backward Citations)
US3615448A
Cited
US4309331A
Cited
BE865180A
Cited
US4125700A
Cited
US4176028A
Cited
US4465572A
Cited
US4251618A
Cited
US4276366A
Cited
US4421619A
Cited
US4634562A
Cited
US4523983A
Cited
US4568405A
Cited
US4575330A
Cited
US4575330B1
Cited
US4623558A
Cited
EP0250121A2
Cited
US4752498A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-04-08 | 1994-10-08 | 1995-04-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-04-08 | 1998-10-08 | 1999-04-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-04-08 | 2002-10-08 | 2003-04-09 | $7700.00 | Window Closed / Lapsed |