Abstract Polyoxylalkylene ether with an average molecular weight of 400 to 10,000 with at least one terminal hydroxyl group and at least one lateral --SO 3 X group (X=hydrogen, alkali metal or ammonium ion) is disclosed. The polyoxyalkylene ether is obtainable by the statistical or blockwise addition reaction of (a) α-alkylene oxides with 2 to 14 carbon atoms or mixtures thereof and (b) allyl and/or methallyl glycidyl ethers to monohydric to quadrihydric aliphatic alcohols with up to 8 carbon atoms, the ratio of component (a) to component (b) being selected so that at least one allyl ether group is linked to the average molecule, reacting the polymer by a known reaction with, based on the allyl ether groups, at least equimolar amounts of a compound of the formula HSO 3 Y (Y=alkali or ammonium ion) and if necessary, exchanging the cation Y against a hydrogen ion also by a known procedure. The compounds are suitable as polyol components for the preparation of stable, ionic, aqueous polyurethane dispersions with a high solids content.
In an aqueous polyurethane dispersion, wherein the polyurethane is prepared by the reaction of a polyol component and an isocyanate component, the improvement which comprises that the polyurethane contains the reaction product of the isocyanate component and a polyol component which is a polyoxyalkylene ether with an average molecular weight to 400 to 10,000 and having at least two terminal hydroxyl groups and at least one --SO 3 X group wherein X is hydrogen, alkali metal or ammonium ion, said polyoxyalkylene ether being the reaction product obtained by (i) the statistical or blockwise addition of (a) α-alkylene oxides with 2 to 14 carbon atoms or mixtures hereof, and (b) allyl and/or methallyl glycidyl ethers, to dihydric to quadrihydric aliphatic alcohols with up to 8 carbon atoms, the ratio of component (a) to component (b) being selected so that at least one allyl ether group is linked to the average molecule, and (ii) reacting the polymer thus obtained with, based on the allyl ether groups, at least equimolar amounts of a compound of the formula HSO 3 Y, wherein Y is alkali metal or ammonium ion.
Claim 2
Dependent Claim
185 words
In an aqueous polyurethane dispersion, wherein the polyurethane is prepared by the reaction of a polyol component and an isocyanate component, the improvement which comprises that the polyurethane contains the reaction product of the isocyanate component and a polyol component which is a polyoxyalkylene ether with an average molecular weight to 400 to 10,000 and having at least two terminal hydroxyl groups and at least one --SO 3 X group wherein X is hydrogen, alkali metal or ammonium ion, said polyoxyalkylene ether being the reaction product obtained by (i) the statistical or blockwise addition of (a) α-alkylene oxides with 2 to 14 carbon atoms or mixtures hereof, and (b) allyl and/or methallyl glycidyl ethers, to dihydric to quadrihydric aliphatic alcohols with up to 8 carbon atoms, the ratio of component (a) to component (b) being selected so that at least one allyl ether group is linked to the average molecule, and (ii) reacting the polymer thus obtained with, based on the allyl ether groups, at least equimolar amounts of a compound of the formula HSO 3 Y, wherein Y is alkali metal or ammonium ion.
Claim 3
Dependent Claim
24 words
The aqueous polyurethane dispersion of claim 1 wherein in the polyol component the cation Y is exchanged against a hydrogen ion by ion exchange.