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US4612142A Expired / Lapsed US ⏱️ 0.0 years remaining

Ether sulfonates as low-foam wetting agents

Assignee: Henkel AG and Co KGaA
•
Filing: 1985-09-05
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Granted: 1986-09-16
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Expires: 2005-09-05
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Abstract

Abstract Ether sulfonates corresponding to the following general formula R.sup.1 -- O(C.sub.n H.sub.2n O).sub.x --R.sup.2 --SO.sub.3 M (I) wherein R 1 is a C 1-6 alkyl, n is an integer of 2-4, x is an integer from 0-30, R 2 is a C 6-22 linear alkenylene, hydroxyalkylene or hydroxyalkenylene group, and M is hydrogen or an alkali metal cation, which can be obtained by sulfonation of olefinically unsaturated fatty alkyl lower alkyl ethers or fatty alkyl (polyoxyalkyl) lower alkyl ethers with sulfur trioxide and hydrolysis of the sultones formed, are particularly suitable for use as low-foam wetting agents in aqueous acidic or alkaline commercial-grade treatment preparations.

Inventors

  • 👤 Robert Piorr
  • 👤 Hildegard van Delden
  • 👤 Sabine Luttge
  • 👤 Bernd Bahr
  • 👤 Ingo Wegener

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 17:22
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/0005; C11D3/0026; C11D1/00; C11D1/02; C11D1/12; C23; C23G; C23G1/00; C23G1/14; D; D06; D06L; D06L4/00; D06L4/10; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/03

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 107 words
In an aqueous composition for the treatment of a solid surface wherein such composition has a pH below 3 or above 10 and wherein such composition contains a wetting agent, the improvement wherein said wetting agent is an effective amount of an ether sulfonate of the formula R.sup.1 --O(C.sub.n H.sub.2n O)x--R.sup.2 --SO.sub.3 M (I) in which R 1 is a C 1 -C 6 alkyl group, n is an integer of from 2 to 4, x is an integer of from 0 to 30, R 2 is a C 6 -C 22 linear alkenylene, hydroxyalkylene, or hydroxyalkenylene group, and M is hydrogen or an alkali metal cation.
Claim 2
Dependent Claim 107 words
In an aqueous composition for the treatment of a solid surface wherein such composition has a pH below 3 or above 10 and wherein such composition contains a wetting agent, the improvement wherein said wetting agent is an effective amount of an ether sulfonate of the formula R.sup.1 --O(C.sub.n H.sub.2n O)x--R.sup.2 --SO.sub.3 M (I) in which R 1 is a C 1 -C 6 alkyl group, n is an integer of from 2 to 4, x is an integer of from 0 to 30, R 2 is a C 6 -C 22 linear alkenylene, hydroxyalkylene, or hydroxyalkenylene group, and M is hydrogen or an alkali metal cation.
Claim 3
Dependent Claim 35 words
A composition in accordance with claim 1 wherein from about 0.05 to about 1% by weight, based on the weight of the composition, of the ether sulfonate of formula I is present in the composition.
Claim 4
Dependent Claim 33 words
A composition in accordance with claim 1 wherein in the ether sulfonate of formula I, n is 2, x is 3-10, and the R 2 group contains from 16 to 22 carbon atoms.
Claim 5
Dependent Claim 56 words
A composition in accordance with claim 1 wherein the composition is an alkaline peroxide bleaching bath comprising (a) from about 0.3 to about 3% by weight of hydrogen peroxide, (b) from 0.05 to 1 mole/liter of a strong base, and (c) from about 0.05 to about 1% by weight of the ether sulfonate of formula I.
Claim 6
Dependent Claim 41 words
A composition in accordance with claim 4 wherein in (b) the strong base is one or more of NaOH, KOH, Na 2 CO 3 , K 2 CO 3 , Na 2 SiO 3 , and K 2 SiO 3 .

References Cited (Backward Citations)

US2062957A Cited
US3592796A Cited
US3856738A Cited
DE2724442A1 Cited
GB1566770A Cited
US4468335A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-09-15 1990-03-17 1990-09-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-09-15 1994-03-17 1994-09-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-09-15 1998-03-17 1998-09-16 $7700.00 Window Closed / Lapsed

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