Sulfonated polyoxyalkylene ethers of 1,2 or 1,3-diols, their preparation and use
Abstract
Abstract Sulfonated polyoxyalkylene ethers of the formula R.sup.1 CH.sub.2 O--(C.sub.2 H.sub.4 O--).sub.n (C.sub.3 H.sub.6 O--).sub.m CH 2 CHR 3 CH 2 --SO 3 X in which R 1 is ##STR1## R2 is CH 3 --, C 2 H 5 --, or C 3 H 7 --, R 3 is H-- or CH 3 --, X is H--, alkali metal or ammonium ion, n is 0 to 100, m is 0 to 50, and n+m is not less than 1. The compounds are prepared by adding a compound of formula HSO 3 X in a known manner by a free radical reaction in the presence of catalysts and optionally at an elevated temperature to compounds of the formula R.sup.1 CH.sub.2 O--(C.sub.2 H.sub.4 O--).sub.n (C.sub.3 H.sub.6 O--).sub.m CH 2 CHR 3 ═CH 2 . The inventive compounds can be used as the only or a partial polyol component for the preparation of curable, polyurethane-based adhesives and increase the combined tensile and shear strength and the floating roller peel strength of the adhesive bonds.
Inventors
- 👤 Eberhard Esselborn
- 👤 Jurgen Fock
Bibliographic Details
Claims Analysis
Total Claims: 2References Cited (Backward Citations)
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