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Hydraulic cement and composition employing the same

Assignee: Lone Star Industries Inc
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Filing: 1990-06-05
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Granted: 1991-03-05
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Expires: 2010-06-05
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Abstract

Abstract A hydraulic cement is formed from a Class C fly ash, an alkali metal activator, and citric acid. Mortar and concrete compositions can be prepared with this hydraulic cement. The cement is particularly useful in producing mortar and concrete compositions that achieve high strengths in a short time, in particular, a mortar having a strength of at least 2500 psi in 24 hours, when cured at room temperature.

Inventors

  • 👤 Billy B. Gravitt
  • 👤 Richard F. Heitzmann
  • 👤 James L. Sawyer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 02:13
CPC Classifications
C; C04; C04B; C04B28/00; C04B28/02; C04B28/021; C04B40/00; C04B40/0028; C04B40/0039; C04B7/00; C04B7/24; C04B7/243; Y; Y02; Y02P; Y02P40/00; Y02P40/10; Y10; Y10S; Y10S106/00; Y10S106/01

Claims Analysis

Total Claims: 35
Claim 1
Independent Claim 120 words
A hydraulic cement consisting essentially of, by weight the following cement forming constituents: from about 90.8 to 99 parts Class C fly ash from about 0.4 to 4.2 parts alkali metal activator from about 0.6 to 5 parts citric acid from about 0 to 3 parts set control materials, said alkali metal activator being selected from the class consisting of potassium hydroxide, potassium carbonate, sodium hydroxide, and sodium carbonate; and said admixture is at least one material selected from the class consisting of borax; a sodium salt of a copolymer of an unsaturated carboxylic acid and the hydroxyalkyl ester of such acid; a modified lignosulfonate, with catalyst; and a dispersion of sulfonated naphthalene formaldehyde condensate, a gluconate, and a lignosulfonate.
Claim 2
Dependent Claim 120 words
A hydraulic cement consisting essentially of, by weight the following cement forming constituents: from about 90.8 to 99 parts Class C fly ash from about 0.4 to 4.2 parts alkali metal activator from about 0.6 to 5 parts citric acid from about 0 to 3 parts set control materials, said alkali metal activator being selected from the class consisting of potassium hydroxide, potassium carbonate, sodium hydroxide, and sodium carbonate; and said admixture is at least one material selected from the class consisting of borax; a sodium salt of a copolymer of an unsaturated carboxylic acid and the hydroxyalkyl ester of such acid; a modified lignosulfonate, with catalyst; and a dispersion of sulfonated naphthalene formaldehyde condensate, a gluconate, and a lignosulfonate.
Claim 3
Dependent Claim 14 words
The hydraulic cement of claim 1 wherein the alkali metal activator is potassium hydroxide.
Claim 4
Dependent Claim 21 words
The hydraulic cement of claim 1 mixed with from 0.165 to 0.220 part water for each part of cement forming constituents.
Claim 5
Dependent Claim 17 words
The hydraulic cement of claim 3 wherein the amount of water is from 0.18 to 0.22 part.
Claim 6
Dependent Claim 21 words
A mortar formed from the hydraulic cement of claim 1 including sand in a ratio to cement forming constituents of 1.5-3.0:1.0.
Claim 7
Dependent Claim 10 words
The mortar of claim 5 wherein the ratio is 1.5-2.5:1.0.
Claim 8
Dependent Claim 22 words
The hydraulic cement of claim 1 having from 0.6 to 3.0 parts citric acid and from 1.0 to 2.9 parts potassium hydroxide.
Claim 9
Dependent Claim 22 words
The hydraulic cement of claim 1 having from 3.0 to 5.0 parts citric acid and from 0.4 to 3.8 parts potassium hydroxide.
Claim 10
Dependent Claim 144 words
A two part composition for hydraulic cement, wherein the two parts are blended prior to preparation of the cement, consisting essentially of by weight: a. a first part of from about 90.8 to 99 parts, Class C fly ash; and b. a second part containing: (1) from about 0.4 to 4.2 parts alkali metal activator (2) about 0.6 to 5 parts citric acid; and (3) about 0 to 3 parts admixture, wherein said alkali metal activator is selected from the class group consisting of potassium hydroxide, potassium carbonate, sodium hydroxide, and sodium carbonate; and said admixture is at least one material selected from the class consisting of borax; a sodium salt of a copolymer of an unsaturated carboxylic acid and the hydroxyalkyl ester of such acid; a modified lignosulfonate, with catalyst; and a dispersion of sulfonated naphthalene formaldehyde condensate, a gluconate, and a lignosulfonate.
Claim 11
Dependent Claim 144 words
A two part composition for hydraulic cement, wherein the two parts are blended prior to preparation of the cement, consisting essentially of by weight: a. a first part of from about 90.8 to 99 parts, Class C fly ash; and b. a second part containing: (1) from about 0.4 to 4.2 parts alkali metal activator (2) about 0.6 to 5 parts citric acid; and (3) about 0 to 3 parts admixture, wherein said alkali metal activator is selected from the class group consisting of potassium hydroxide, potassium carbonate, sodium hydroxide, and sodium carbonate; and said admixture is at least one material selected from the class consisting of borax; a sodium salt of a copolymer of an unsaturated carboxylic acid and the hydroxyalkyl ester of such acid; a modified lignosulfonate, with catalyst; and a dispersion of sulfonated naphthalene formaldehyde condensate, a gluconate, and a lignosulfonate.
Claim 12
Dependent Claim 13 words
The composition of claim 9 wherein the alkali metal activator is potassium hydroxide.
Claim 13
Dependent Claim 20 words
The composition of claim 9 mixed with from 0.165 to 0.220 part water for each part the hydraulic cement composition.
Claim 14
Dependent Claim 16 words
The composition of claim 11 wherein the amount of water is from 0.18 to 0.22 part.
Claim 15
Dependent Claim 19 words
A mortar formed from the composition of claim 9 including sand in a ratio to hydraulic composition of 1.5-3.0:1.0.
Claim 16
Dependent Claim 10 words
The mortar of claim 13 wherein the ratio is 1.5-2.5:1.0.
Claim 17
Dependent Claim 20 words
The composition of claim 9 having from 0.6 to 3.0 parts citric acid and from 1.0 to 2.9parts potassium hydroxide.
Claim 18
Dependent Claim 20 words
The composition of claim 9 having from 3.0 to 5.0 parts citric acid and from 0.4 to 3.8parts potassium hydroxide.
Claim 19
Dependent Claim 13 words
The composition of claim 9 wherein the alkali metal activator is potassium hydroxide.
Claim 20
Dependent Claim 24 words
A hydraulic cement comprising, by weight, approximately: 96.29 parts Class C fly ash 1.41 parts potassium hydroxide 1.28 parts citric acid 1.02 parts borax
Claim 21
Dependent Claim 24 words
A hydraulic cement comprising, by weight, approximately: 96.29 parts Class C fly ash 1.41 parts potassium hydroxide 1.28 parts citric acid 1.02 parts borax
Claim 22
Dependent Claim 43 words
A hydraulic cement comprising, by weight, approximately: 95.98 parts Class C fly ash 1.40 parts potassium hydroxide 1.28 parts citric acid 1.02 parts borax 0.05 part sodium salt of a copolymer of an unsaturated carboxylic acid and the hydroxyalkyl ester of said acid
Claim 23
Dependent Claim 43 words
A hydraulic cement comprising, by weight, approximately: 95.98 parts Class C fly ash 1.40 parts potassium hydroxide 1.28 parts citric acid 1.02 parts borax 0.05 part sodium salt of a copolymer of an unsaturated carboxylic acid and the hydroxyalkyl ester of said acid
Claim 24
Dependent Claim 24 words
A hydraulic cement comprising, by weight, approximately: 96.41 parts Class C fly ash 1.28 parts potassium hydroxide 1.28 parts citric acid 1.03 parts borax
Claim 25
Dependent Claim 24 words
A hydraulic cement comprising, by weight, approximately: 96.41 parts Class C fly ash 1.28 parts potassium hydroxide 1.28 parts citric acid 1.03 parts borax
Claim 26
Dependent Claim 24 words
A hydraulic cement comprising, by weight, approximately: 96.53 parts Class C fly ash 1.16 parts potassium hydroxide 1.28 parts citric acid 1.03 parts borax
Claim 27
Dependent Claim 24 words
A hydraulic cement comprising, by weight, approximately: 96.53 parts Class C fly ash 1.16 parts potassium hydroxide 1.28 parts citric acid 1.03 parts borax
Claim 28
Dependent Claim 24 words
A hydraulic cement comprising, by weight, approximately: 96.66 parts Class C fly ash 1.03 parts potassium hydroxide 1.28 parts citric acid 1.03 parts borax
Claim 29
Dependent Claim 24 words
A hydraulic cement comprising, by weight, approximately: 96.66 parts Class C fly ash 1.03 parts potassium hydroxide 1.28 parts citric acid 1.03 parts borax
Claim 30
Dependent Claim 21 words
A hydraulic cement comprising, by weight, approximately: 96.79 parts Class C fly ash 0.90 part potassium hydroxide 1.28 parts citric acid
Claim 31
Dependent Claim 21 words
A hydraulic cement comprising, by weight, approximately: 96.79 parts Class C fly ash 0.90 part potassium hydroxide 1.28 parts citric acid
Claim 32
Dependent Claim 3 words
03 parts borax
Claim 33
Dependent Claim 3 words
03 parts borax
Claim 34
Dependent Claim 21 words
A hydraulic cement comprising, by weight, approximately: 94.95 parts Class C fly ash 3.79 parts potassium carbonate 1.26 parts citric acid
Claim 35
Dependent Claim 21 words
A hydraulic cement comprising, by weight, approximately: 94.95 parts Class C fly ash 3.79 parts potassium carbonate 1.26 parts citric acid

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-03-04 1994-09-03 1995-03-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-03-04 1998-09-03 1999-03-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-03-04 2002-09-03 2003-03-05 $7700.00 Window Closed / Lapsed

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