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US4985523A Expired / Lapsed US ⏱️ 0.0 years remaining

Anaerobically curing adhesive sealing composition

Assignee: ThreeBond Co Ltd
•
Filing: 1989-08-28
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Granted: 1991-01-15
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Expires: 2009-08-28
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Abstract

Abstract An anaerobically curing adhesive sealing composition comprising (A) a mono(meth)acrylate monomer represented by formula (I) ##STR1## wherein R 1 represents a hydrogen atom or a methyl group; and R 2 represents ##STR2## and (B) a (meth)acrylate prepolymer having a urethane structure in the main chain thereof and having an average molecular weight of 10,000 or more and further containing (C) a (meth)acrylate prepolymer having a urethane structure in the main chain thereof and an average molecular weight of at most 5,000. The sealing composition exhibits, upon curing, excellent elasticity and properties to follow an adherend while retaining excellent resistance to oil and heat as possessed by acrylate type reactive sealing compositions.

Inventors

  • 👤 Shuji Mochizuki
  • 👤 Atsushi Okuma
  • 👤 Katsunori Haruna

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 13:18
CPC Classifications
C; C08; C08F; C08F290/00; C08F290/08; C08F290/14; C08F290/147; C09; C09K; C09K3/00; C09K3/10; C09K2003/1034; C09K2003/1065; C09K2200/00; C09K2200/06; C09K2200/0615; C09K2200/0625; Y; Y10; Y10S; Y10S525/00; Y10S525/92

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 198 words
An anaerobically curing adhesive sealing composition comprising (A) a mono(meth)acrylate monomer represented by formula (I) ##STR14## wherein R 1 represents a hydrogen atom or a methyl group; and R 2 represents ##STR15## (B) a (meth)acrylate prepolymer having a urethane structure in the main chain thereof and having an average molecular weight of at least 10,000 and (C) a (meth)acrylate prepolymer having a urethane structure in the main chain thereof and an average molecular weight of from 500 to 5,000, said methacrylate prepolymer (B) being the reaction product of an isocyanate terminated polyurethane prepolymer, prepared from a polyether polyol and an organic diisocyanate, with a (meth)acrylate of a polyhydric alcohol having active hydrogen which is a mono(meth)acrylate of a dihydric alcohol or a (mono)methacrylate or di(meth)acrylate of a trihydric alcohol and said (meth)acrylate prepolymer (C) being a polyester diol or a polyester polyol-diisocyanate reaction product having isocyanate terminal groups reacted with a (meth)acrylate of a polyhydric alcohol as defined above, and wherein the polyether polyol employed to prepare component (B) is at least one compound of the formula (II), (III), (IV) or (V); ##STR16## wherein n 1 and n 2 each represents an integer of from 1 to 5.
Claim 2
Dependent Claim 198 words
An anaerobically curing adhesive sealing composition comprising (A) a mono(meth)acrylate monomer represented by formula (I) ##STR14## wherein R 1 represents a hydrogen atom or a methyl group; and R 2 represents ##STR15## (B) a (meth)acrylate prepolymer having a urethane structure in the main chain thereof and having an average molecular weight of at least 10,000 and (C) a (meth)acrylate prepolymer having a urethane structure in the main chain thereof and an average molecular weight of from 500 to 5,000, said methacrylate prepolymer (B) being the reaction product of an isocyanate terminated polyurethane prepolymer, prepared from a polyether polyol and an organic diisocyanate, with a (meth)acrylate of a polyhydric alcohol having active hydrogen which is a mono(meth)acrylate of a dihydric alcohol or a (mono)methacrylate or di(meth)acrylate of a trihydric alcohol and said (meth)acrylate prepolymer (C) being a polyester diol or a polyester polyol-diisocyanate reaction product having isocyanate terminal groups reacted with a (meth)acrylate of a polyhydric alcohol as defined above, and wherein the polyether polyol employed to prepare component (B) is at least one compound of the formula (II), (III), (IV) or (V); ##STR16## wherein n 1 and n 2 each represents an integer of from 1 to 5.
Claim 3
Dependent Claim 18 words
An anaerobically curing adhesive sealing composition as claimed in claim 1 wherein the component (A) is dicyclopentenyloxyethyl methacrylate.

References Cited (Backward Citations)

DE2200021A1 Cited
US4295909A Cited
EP0008202A1 Cited
US4446286A Cited
US4608409A Cited
US4690501A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-01-14 1994-07-16 1995-01-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-01-14 1998-07-16 1999-01-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-01-14 2002-07-16 2003-01-15 $7700.00 Window Closed / Lapsed

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