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US4981660A
Expired / Lapsed
US
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Selective hybrid NOx reduction process
Assignee: Individual
•
Filing: 1988-11-07
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Granted: 1991-01-01
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Expires: 2008-11-07
Abstract
Abstract The method of removing NO and NO 2 from a stream of hydrocarbon combustion products at elevated temperature includes the steps: (a) removing NO from the combustion products in a first zone, and removing NO and NO 2 from the combustion products in a second zone spaced downstream from the first zone, (b) the removal of NO at the first zone being effected by dispersing reagent ammonia or ammonia radical into the stream of combustion products to convert NO into N 2 and H 2 O, and (c) the removal of NO and NO 2 at the second zone being effected by providing a catalyst for contacting the stream, the catalyst effecting conversion of NO and NO 2 to N 2 and H 2 O. A natural draft heater tower is typically employed to contain the two zones.
Inventors
- 👤 James T. Leach
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 04:08
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; Y; Y02; Y02A; Y02A50/00; Y02A50/20
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
228 words
The method of removing NO and NO 2 from a stream of hydrocarbon combustion products at elevated temperature, the steps that include (a) providing an upright housing forming a first zone and removing NO from the combustion products flow in said first zone, and providing a stack on the housing to form a second zone and removing NO and NO 2 from the combustion products flowing in said second zone spaced downstream from said first zone, (b) the removal of NO at said first zone being effected by dispersing sufficient reagent ammonia or ammonia radical into the stream of combustion products at stream temperature between 1,300° F. and 2,000° F. to convert NO into N 2 and H 2 O, and to provide excess unreacted reagent dispersed in said stream and carried to the second zone, (c) the removal of NO and NO 2 at said second zone being effected by providing a catalyst for contacting the stream, the catalyst and excess reagent effecting conversion of NO and NO 2 to N 2 and H 2 O at stream temperatures between 400° F. and 850° F. (d) and providing first and second heat exchangers respectively in the housing and in the stack, in the flow paths of the hot combusting products, the heat exchangers operated to control said stream temperatures between 400° F. and 850° F. as aforesaid.
Claim 2
Independent Claim
228 words
The method of removing NO and NO 2 from a stream of hydrocarbon combustion products at elevated temperature, the steps that include (a) providing an upright housing forming a first zone and removing NO from the combustion products flow in said first zone, and providing a stack on the housing to form a second zone and removing NO and NO 2 from the combustion products flowing in said second zone spaced downstream from said first zone, (b) the removal of NO at said first zone being effected by dispersing sufficient reagent ammonia or ammonia radical into the stream of combustion products at stream temperature between 1,300° F. and 2,000° F. to convert NO into N 2 and H 2 O, and to provide excess unreacted reagent dispersed in said stream and carried to the second zone, (c) the removal of NO and NO 2 at said second zone being effected by providing a catalyst for contacting the stream, the catalyst and excess reagent effecting conversion of NO and NO 2 to N 2 and H 2 O at stream temperatures between 400° F. and 850° F. (d) and providing first and second heat exchangers respectively in the housing and in the stack, in the flow paths of the hot combusting products, the heat exchangers operated to control said stream temperatures between 400° F. and 850° F. as aforesaid.
Claim 3
Dependent Claim
33 words
The method of claim 1 including providing apparatus including a hydrocarbon fuel burner operating to produce said hot combustion products flowing to said zones, there also being O 2 supplied to said zones.
Claim 4
Dependent Claim
29 words
The method of claim 1 wherein said heat exchanger in the second zone comprises a boiler having tubes, and including locating said second zone immediately downstream of said tubes.
Claim 5
Dependent Claim
39 words
The method of claim 1 wherein said the level of NO and NO 2 in the steam is between 40% and 98% of initial level in the total stream, prior to dispersing ammonia or ammonia radical into the stream.
Claim 6
Dependent Claim
31 words
The method of claim 1 wherein the level of NO and NO 2 in the stream between said first and second zones is reduced by 30% to 90% of uncontrolled levels.
Claim 7
Dependent Claim
43 words
The method of claim 1 wherein the level of NO and NO 2 in the stream after it passes through the second zone is reduced by 40% to 95% from levels remaining in the gas stream after passage thereof through the first zone.
Claim 8
Dependent Claim
34 words
The method of claim 5 wherein the level of NO and NO 2 in the stream after it passes through the second zone is between about 70% to 98% reduced from the uncontrolled levels.
Claim 9
Dependent Claim
41 words
The method of claim 1 wherein the amount of ammonia or ammonia radical dispersed into the hot gas stream is such that the mole ratio of excess regeant to NO x leaving the first reaction zone is between 0.1 and 5.0.
Claim 10
Dependent Claim
13 words
The method of claim 1 wherein said ammonia radical is supplied by urea.
Claim 11
Dependent Claim
28 words
The method of claim 1 wherein the mole ratio of reagent to uncontrolled NO and NO 2 in the stream of combustion products is between 0.5 and 10.
Claim 12
Dependent Claim
42 words
The method of claim 1 including sensing the concentration of unreacted NO and NO 2 in the flow leaving the catalyst, and controlling the amount of said reagent dispersing to minimize NO and NO 2 in the stream leaving the second zone.
Claim 13
Dependent Claim
38 words
The method of claim 1 including sensing the concentration of unreacted reagent leaving the second zone, and particularly the amount of said reagent dispersing to prevent excessive release of the reagent in the stream leaving the second zone.
Claim 14
Dependent Claim
16 words
The method of claim 1 including flow of said stream through said zones by natural draft.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-12-31 | 1994-07-02 | 1995-01-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-12-31 | 1998-07-02 | 1999-01-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-12-31 | 2002-07-02 | 2003-01-01 | $7700.00 | Window Closed / Lapsed |