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US4980156A
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Antiperspirant compositions
Assignee: General Electric Co
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Filing: 1988-12-12
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Granted: 1990-12-25
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Expires: 2008-12-12
Abstract
Abstract An improved dry-feeling antiperspirant composition is provided which comprises an aqueous solution of an astringent emulsified in a volatile silicon fluid, the emulsion being stabilized by a combination of a long-chain alkyl modified polysiloxane-polyoxyalkylene copolymer and an organic surfactant having an HLB value from 8 to 18.
Inventors
- 👤 William J. Raleigh
- 👤 Raymond J. Thimineur
- 👤 Anthony A. Zotto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 17:06
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/84; A61K8/89; A61Q; A61Q15/00; A61K8/19; A61K8/28; A61K8/30; A61K8/58; A61K8/585; A61K8/891; A61K8/894
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
375 words
An improved water-in-oil antiperspirant emulsion composition having a reduced whitening effect on skin, and including: (a) from about 89.5 to about 50 parts by weight of an aqueous solution of an astringent as a discontinuous phase; (b) from about 10 to about 45 parts by weight of a volatile liquid having a normal boiling point of less than 250° C. as a continuous phase, said volatile liquid being selected from the group consisting of methylsiloxane fluids having the average unit formula (CH.sub.3).sub.a SiO.sub.(4-a)/2 wherein a has an average value of from 2 to 3, inclusive; (c) from about 0.1 to about 3 parts by weight of an organic oil-in-water surfactant having an HLB value of from 8 to 18 inclusive, wherein the improvement comprises (d) from about 0.4 to about 6 parts by weight of a polyorganosiloxane-polyoxyalkylene copolymer of the formula MD.sub.x D'.sub.y D".sub.z M wherein D is (CH 3 ) 2 SiO 2/2 , D' is (CH 3 )R 1 SiO 2/2 , where R 1 is an alkyl group having from 6 to 30 carbon atoms, D" is (CH 3 )R 2 SiO 2/2 , where R 2 is a polyoxyalkylene ether residue of the formula --(R.sup.4).sub.p --(OR.sup.3).sub.n --OR.sup.5 wherein each individual R 3 is an alkylene radical having 2 to 6 carbon atoms, R 4 is an alkylene radical having 2 to 20 carbon atoms, R 5 is hydrogen or an hydrocarbon radical of from 1 to about 12 carbon atoms, n has a value from about 5 to about 20, and p has a value of zero or 1, M is (CH 3 ) 2 R 6 SIO 2/2 , where R 6 may be an alkyl group having from 1 to 30 carbon atoms or R 2 , x has an average value of from about 10 to about 400, y has an average value of from 1 to about 200, and z has an average value of from 1 to about 100, and x+y+z has an average value of from about 12 to about 400, with the proviso that the weight ratio of R 2 to polysiloxane absent R 2 is from greater than 15/85 to less than 35/65; and the total of (a)+(b)+(c)+(d) being 100 parts by weight.
Claim 2
Dependent Claim
375 words
An improved water-in-oil antiperspirant emulsion composition having a reduced whitening effect on skin, and including: (a) from about 89.5 to about 50 parts by weight of an aqueous solution of an astringent as a discontinuous phase; (b) from about 10 to about 45 parts by weight of a volatile liquid having a normal boiling point of less than 250° C. as a continuous phase, said volatile liquid being selected from the group consisting of methylsiloxane fluids having the average unit formula (CH.sub.3).sub.a SiO.sub.(4-a)/2 wherein a has an average value of from 2 to 3, inclusive; (c) from about 0.1 to about 3 parts by weight of an organic oil-in-water surfactant having an HLB value of from 8 to 18 inclusive, wherein the improvement comprises (d) from about 0.4 to about 6 parts by weight of a polyorganosiloxane-polyoxyalkylene copolymer of the formula MD.sub.x D'.sub.y D".sub.z M wherein D is (CH 3 ) 2 SiO 2/2 , D' is (CH 3 )R 1 SiO 2/2 , where R 1 is an alkyl group having from 6 to 30 carbon atoms, D" is (CH 3 )R 2 SiO 2/2 , where R 2 is a polyoxyalkylene ether residue of the formula --(R.sup.4).sub.p --(OR.sup.3).sub.n --OR.sup.5 wherein each individual R 3 is an alkylene radical having 2 to 6 carbon atoms, R 4 is an alkylene radical having 2 to 20 carbon atoms, R 5 is hydrogen or an hydrocarbon radical of from 1 to about 12 carbon atoms, n has a value from about 5 to about 20, and p has a value of zero or 1, M is (CH 3 ) 2 R 6 SIO 2/2 , where R 6 may be an alkyl group having from 1 to 30 carbon atoms or R 2 , x has an average value of from about 10 to about 400, y has an average value of from 1 to about 200, and z has an average value of from 1 to about 100, and x+y+z has an average value of from about 12 to about 400, with the proviso that the weight ratio of R 2 to polysiloxane absent R 2 is from greater than 15/85 to less than 35/65; and the total of (a)+(b)+(c)+(d) being 100 parts by weight.
Claim 3
Dependent Claim
24 words
The antiperspirant emulsion composition of claim 1 wherein the volatile liquid is a mixture of cyclic dimethylsiloxanes consisting of octamethylcyclotetrasiloxane and larger cyclic dimethylsiloxanes.
Claim 4
Dependent Claim
26 words
The antiperspirant emulsion composition of claim 2 wherein the aqueous solution of an astringent antiperspirant agent consists of water and aluminum zirconium chloride tetrachlorohydrate glycine salt.
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