Trialkylammonium alkyl carboxylate primer for cyanoacrylate bonding of polymeric substrates

Claim 2

A non-aqueous primer composition for bonding surfaces with cyanoacrylate adhesives, consisting essentially of: (a) at least one tertiary ammonium carboxylate compound of the formula: ##STR6## wherein: R 1 , R 2 , R 3 , and R 4 may each vary independently of the others and are each selected from the group consisting of alkyl, alkenyl, alkynyl, alkylaryl and aralkyl; R 4 is a long chain moiety having 6-20 carbon atoms in the chain; and at least one of the R 1 , R 2 , and R 3 groups is a long chain moiety having 6-20 carbon atoms in the chain; and (b) a non-aqueous, low surface tension organic solvent for the tertiary ammonium carboxylate compound.

Claim 3

A primer composition according to claim 1, wherein R 4 is selected from the group consisting of alkyl and alkenyl.

Claim 4

A primer composition according to claim 1, wherein each of the R 1 , R 2 and R 3 groups comprising long chain moieties has at least 16 carbon atoms in the chain and each of the other R 1 , R 2 and R 3 groups is a short chain alkyl group having less than 5 carbon atoms.

Claim 5

A primer composition according to claim 1, wherein each of R 1 , R 2 , R 3 , and R 4 is independently selected from the group consisting of alkyl groups having 6 to 20 carbon atoms.

Claim 6

A primer composition according to claim 1, wherein R 4 COO.sup.⊖ is selected from the group consisting of oleate and stearate.

Claim 7

A primer composition according to claim 1, wherein R 4 is a long chain moiety having 10 to 15 carbon atoms in the chain.

Claim 8

A primer composition according to claim 1, wherein the tertiary ammonium carboxylate compound comprises distearylmethylammonium stearate.

Claim 9

A primer composition according to claim 1, wherein the tertiary ammonium carboxylate compound comprises distearylmethylammonium oleate.

Claim 10

A primer composition according to claim 1, wherein the tertiary ammonium carboxylate compound comprises tridodecylammonium stearate.

Claim 11

A primer composition according to claim 1, wherein the tertiary ammonium carboxylate compound has a concentration of from about 0.05% to about 1.0% by weight, based on the volume of the solvent.

Claim 12

A primer composition according to claim 1, wherein the solvent comprises isopropanol.

Claim 13

A primer composition according to claim 1, wherein the solvent comprises trichlorofluoroethane.

Claim 14

A non-aqueous primer composition for bonding surfaces with cyanoacrylate adhesives, consisting essentially of: (a) at least one tertiary ammonium carboxylate compound selected from the group consisting of: distearylmethylammonium stearate, tridodecylammonium stearate, disterylmethylammonium oleate, tridodecylammonium oleate, tridodecylammonium palmitate, methyltrioctylammonium stearate, and tristearylammonium stearate; and (b) a non-aqueous, low surface tension organic solvent for the tertiary ammonium carboxylate compound; wherein the non-aqueous, low surface tension organic solvent and the relative proportions of the tertiary ammonium carboxylate compound and the non-aqueous, low surface tension organic solvent are selected such that initial lap shear strength determined by the method of ASTM D-4502 STM-650 on polypropylene substrates bonded with cyanoacrylate adhesive is at least 1,000 psi, and that lap strength determined by said method on polypropylene substrates after 20 hours of open time prior to cyanoacrylate bonding is at least 80 percent of the initial lap shear strength value.

Claim 15

A non-aqueous primer composition for bonding surfaces with cyanoacrylate adhesives, consisting essentially of: (a) at least one tertiary ammonium carboxylate compound selected from the group consisting of: distearylmethylammonium stearate, tridodecylammonium stearate, disterylmethylammonium oleate, tridodecylammonium oleate, tridodecylammonium palmitate, methyltrioctylammonium stearate, and tristearylammonium stearate; and (b) a non-aqueous, low surface tension organic solvent for the tertiary ammonium carboxylate compound; wherein the non-aqueous, low surface tension organic solvent and the relative proportions of the tertiary ammonium carboxylate compound and the non-aqueous, low surface tension organic solvent are selected such that initial lap shear strength determined by the method of ASTM D-4502 STM-650 on polypropylene substrates bonded with cyanoacrylate adhesive is at least 1,000 psi, and that lap strength determined by said method on polypropylene substrates after 20 hours of open time prior to cyanoacrylate bonding is at least 80 percent of the initial lap shear strength value.

Claim 16

A non-aqueous primer composition composition according to claim 13, wherein the tertiary ammonium carboxylate compound is selected from the group consisting of distearylmethylammonium stearate, distearylammonium oleate, tridodecylammonium stearate, and tridodecylammonium oleate.

Claim 17

A non-aqueous primer composition according to claim 13, wherein the solvent is selected from the group consisting of alcohols, halogenated hydrocarbon solvents, and mixtures thereof.