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US4970015A Expired / Lapsed US ⏱️ 0.0 years remaining

Radiator cleaning composition and method of manufacture thereof

Assignee: CHEM-SHIELD Inc A CORP OF NEVADA
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Filing: 1989-12-22
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Granted: 1990-11-13
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Expires: 2009-12-22
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Abstract

Abstract An acidic solution for use as a radiator cleaning composition includes an aqueous solution of from about 1-8 weight percent an ethylene glycol base, and about 2-45 weight percent hydrochloric acid. In addition, approximately 2-45 weight percent of an aqueous hydrochloric acid-based composition is included, which composition has a pH of less than about 1.0 yet is substantially non-reactive with compounds having low oxidative states, including human skin tissue.

Inventors

  • 👤 Silverio M. Garcia

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 05:07
CPC Classifications
C; C11; C11D; C11D7/00; C11D7/50; C11D7/5004; C11D7/5022; C11D7/02; C11D7/04; C11D7/08; C23; C23G; C23G1/00; C23G1/02

Claims Analysis

Total Claims: 45
Claim 1
Independent Claim 64 words
An acidic solution for use as a radiator cleaning composition comprising an aqueous solution of from about 1-8 weight percent of an ethylene glycol base, about 2-45 weight percent hydrochloric acid, and about 2-45 weight percent of an aqueous hydrochloric acid based composition having a pH of less than about 1.0, yet substantially non-reactive with compounds having low oxidative states including human skin tissue.
Claim 2
Dependent Claim 64 words
An acidic solution for use as a radiator cleaning composition comprising an aqueous solution of from about 1-8 weight percent of an ethylene glycol base, about 2-45 weight percent hydrochloric acid, and about 2-45 weight percent of an aqueous hydrochloric acid based composition having a pH of less than about 1.0, yet substantially non-reactive with compounds having low oxidative states including human skin tissue.
Claim 3
Dependent Claim 42 words
The acidic solution of claim 1, wherein said hydrochloric acid-based composition comprises a dilute, aqueous hydrochloric acid-based solution admixed with an effective amount of at least one weak acid to produce strong conjugate bases to control the disassociation production of hydronium ions.
Claim 4
Dependent Claim 51 words
The acidic solution as claimed in claim 2, wherein said hydrochloric acid-based composition comprises a dilute aqueous solution of hydrochloric acid and phosphoric acid admixed with an effective amount of at least one weak organic acid to produce strong conjugate bases to further control hydrochloric acid disassociation production of hydronium ions.
Claim 5
Dependent Claim 50 words
The acidic solution as claimed in claim 3, wherein said hydrochloric acid-based composition comprises an aqueous mixture of about 5-20 weight percent hydrochloric and about 5-20 weight percent phosphoric acid admixed with approximately 1-5 weight percent of an hydroxy carboxylic acid and approximately 1-5 weight percent of a dicarboxylic acid.
Claim 6
Dependent Claim 25 words
The acidic solution as claimed in claim 4, wherein said hydrochloric acid based composition further comprises about 1-3 weight percent of a poly methyl amine.
Claim 7
Dependent Claim 27 words
The acidic solution as claimed in claim 4, wherein said hydroxy carboxylic acid is selected from the group consisting of citric acid, tartaric acid, and malic acid.
Claim 8
Dependent Claim 18 words
The acidic solution as claimed in claim 6, wherein said hydroxy carboxylic acid is comprised of citric acid.
Claim 9
Dependent Claim 30 words
The acidic solution as claimed in claim 4, wherein said dicarboxylic acid is selected from the group consisting of oxalic acid, malonic acid, succinic acid, glutaric acid and adipic acid.
Claim 10
Dependent Claim 15 words
The acidic solution as claimed in claim 8, wherein said dicarboxylic acid comprises oxalic acid.
Claim 11
Dependent Claim 24 words
The acidic solution as claimed in claim 5, wherein said poly methyl amine is selected from the group consisting of hexamethylenetetramine, hexamethylenediamine and hexamethyleneamine.
Claim 12
Dependent Claim 15 words
The acidic solution as claimed in claim 10, wherein said poly methyl amine comprises hexamethylenetetramine.
Claim 13
Dependent Claim 22 words
The acidic solution as claimed in claim 4, wherein said solution further comprises approximately 2-3 weight percent of an acid thickening agent.
Claim 14
Dependent Claim 17 words
The acidic solution as claimed in claim 1, wherein said ethylene glycol base comprises butyl ethylene glycol.
Claim 15
Dependent Claim 19 words
The acidic solution as claimed in claim 13, wherein said aqueous solution includes approximately 2-75 weight percent distilled water.
Claim 16
Dependent Claim 36 words
The acidic solution as claimed in claim 1, wherein said solution comprises an aqueous solution of approximately 50 weight percent of said aqueous hydrochloric acid-based composition, and approximately 50 weight percent glycol and hydrochloric acid solution.
Claim 17
Dependent Claim 51 words
The acidic solution as claimed in claim 15, wherein said hydrochloric acid-based composition comprises an aqueous mixture of about 5-20 weight percent hydrochloric acid and about 5-20 weight percent phosphoric acid admixed with approximately 1-5 weight percent of an hydroxy carboxylic acid and approximately 1-5 weight percent of a dicarboxylic acid.
Claim 18
Dependent Claim 50 words
The acidic solution as claimed in claim 16, wherein said hydroxy carboxylic acid is selected from the group consisting of citric acid, tartaric acid, and malic acid, and wherein said dicarboxylic acid is selected from the group consisting of oxalic acid, malonic acid, succinic acid, glutaric acid and adipic acid.
Claim 19
Dependent Claim 24 words
The acidic solution as claimed in claim 17, wherein said hydroxy carboxylic acid comprises citric acid, and wherein said dicarboxylic acid comprises oxalic acid.
Claim 20
Dependent Claim 24 words
The acidic solution as claimed in claim 18, wherein said hydrochloric acid-based composition further comprises about 1-3 weight percent of a poly methyl amine.
Claim 21
Dependent Claim 22 words
The acidic solution as claimed in claim 19, wherein said solution further comprises approximately 2-3 weight percent of an acid thickening agent.
Claim 22
Dependent Claim 124 words
A process for preparing an acidic solution for use as a radiator cleaning composition having a pH of less than about 1.0 while being non-reactive with human skin tissue, comprising admixing approximately 2-75 weight percent water and approximately 1-8 weight percent of an ethylene glycol base with approximately 2-45 weight percent of a hydrochloric acid, and further admixing this glycol-acid solution with about 2-45 weight percent of an aqueous acid-based composition, said aqueous acid-based composition being prepared by the steps of: admixing from about 5-20 weight percent hydrochloric acid with about 5-20 weight percent phosphoric acid to produce an acidic mixture; and admixing said acidic mixture with an effective amount of water to produce an aqueous acid-based composition having approximately 47-87 weight percent water.
Claim 23
Dependent Claim 124 words
A process for preparing an acidic solution for use as a radiator cleaning composition having a pH of less than about 1.0 while being non-reactive with human skin tissue, comprising admixing approximately 2-75 weight percent water and approximately 1-8 weight percent of an ethylene glycol base with approximately 2-45 weight percent of a hydrochloric acid, and further admixing this glycol-acid solution with about 2-45 weight percent of an aqueous acid-based composition, said aqueous acid-based composition being prepared by the steps of: admixing from about 5-20 weight percent hydrochloric acid with about 5-20 weight percent phosphoric acid to produce an acidic mixture; and admixing said acidic mixture with an effective amount of water to produce an aqueous acid-based composition having approximately 47-87 weight percent water.
Claim 24
Dependent Claim 40 words
The process as claimed in claim 21, wherein said aqueous acid-based composition is admixed with an effective amount of at least one weak organic acid to produce strong conjugate bases to control hydrochloric acid dissociation production of hydronium ions therein.
Claim 25
Dependent Claim 34 words
The process of claim 22, wherein said aqueous acid-based composition is further admixed with approximately 1-5 weight percent of a hydroxy carboxylic acid and with from about 1-5 weight percent of a dicarboxylic acid.
Claim 26
Dependent Claim 26 words
The process as claimed in claim 23, wherein said hydroxy carboxylic acid is selected from the group consisting of citric acid, tartaric acid, and malic acid.
Claim 27
Dependent Claim 29 words
The process as claimed in claim 23, wherein said dicarboxylic acid is selected from the group consisting of oxalic acid, malonic acid, succinic acid, glutaric acid and adipic acid.
Claim 28
Dependent Claim 22 words
The process as claimed in claim 23, wherein said hydroxy carboxylic acid comprises citric acid and said dicarboxylic acid comprises oxalic acid.
Claim 29
Dependent Claim 19 words
The process as claimed in claim 23, wherein said acid-based composition is further admixed with a poly methyl amine.
Claim 30
Dependent Claim 49 words
The process as claimed in claim 21, wherein said 5-20 weight percent phosphoric acid functions as a controller for hydronium ion production by the disassociation of hydrochloric acid in water, and wherein said hydronium ion production is further controlled by adding an effective amount of yet another weak acid.
Claim 31
Dependent Claim 53 words
The process as claimed in claim 28, wherein said weak acid comprises hydroxy carboxylic acid, and further comprises the step of adding yet a third weak acid to control hydronium ion production created by the disassociation of hydrochloric acid in water as well as created by the addition of said hydroxy carboxylic acid.
Claim 32
Dependent Claim 16 words
The process as claimed in claim 29, wherein said additional weak acid comprises a dicarboxylic acid.
Claim 33
Dependent Claim 15 words
The process as claimed in claim 21, wherein said glycol base comprises butyl ethylene glycol.
Claim 34
Dependent Claim 95 words
An acidic radiator cleaning composition comprising approximately 2-75 weight percent distilled water, about 1-8 weight percent of an ethylene glycol base, approximately 2-45 weight percent hydrochloric acid, and approximately 2-45 weight percent of an aqueous hydrochloric acid-based composition having a pH of approximately less than 1.0 and prepared by the steps of: admixing from about 5-20 weight percent hydrochloric acid with about 5-20 weight percent phosphoric acid to produce an acidic mixture; and admixing said acidic mixture with an effective amount of water to produce an aqueous acid-based composition having approximately 47-87 weight percent water.
Claim 35
Dependent Claim 95 words
An acidic radiator cleaning composition comprising approximately 2-75 weight percent distilled water, about 1-8 weight percent of an ethylene glycol base, approximately 2-45 weight percent hydrochloric acid, and approximately 2-45 weight percent of an aqueous hydrochloric acid-based composition having a pH of approximately less than 1.0 and prepared by the steps of: admixing from about 5-20 weight percent hydrochloric acid with about 5-20 weight percent phosphoric acid to produce an acidic mixture; and admixing said acidic mixture with an effective amount of water to produce an aqueous acid-based composition having approximately 47-87 weight percent water.
Claim 36
Dependent Claim 42 words
A radiator cleaning composition as claimed in claim 32, wherein said aqueous acid-based composition is admixed with an effective amount of at least one weak organic acid to produce strong conjugate bases to control hydrochloric acid dissociation production of hydronium ions therein.
Claim 37
Dependent Claim 36 words
The radiator cleaning composition of claim 33, wherein said aqueous acid-based composition is further admixed with approximately 1-5 weight percent of a hydroxy carboxylic acid and with from about 1-5 weight percent of a dicarboxylic acid.
Claim 38
Dependent Claim 28 words
The radiator cleaning composition as claimed in claim 34, wherein said hydroxy carboxylic acid is selected from the group consisting of citric acid, tartaric acid, and malic acid.
Claim 39
Dependent Claim 31 words
The radiator cleaning composition as claimed in claim 34, wherein said dicarboxylic acid is selected from the group consisting of oxalic acid, malonic acid, succinic acid, glutaric acid and adipic acid.
Claim 40
Dependent Claim 24 words
The radiator cleaning composition as claimed in claim 34, wherein said hydroxy carboxylic acid comprises citric acid and said dicarboxylic acid comprises oxalic acid.
Claim 41
Dependent Claim 21 words
The radiator cleaning composition as claimed in claim 34, wherein said acid-based composition is further admixed with a poly methyl amine.
Claim 42
Dependent Claim 51 words
The radiator cleaning composition as claimed in claim 32, wherein said 5-20 weight percent phosphoric acid functions as a controller for hydronium ion production by the disassociation of hydrochloric acid in water, and wherein said hydronium ion production is further controlled by adding an effective amount of yet another weak acid.
Claim 43
Dependent Claim 55 words
The radiator cleaning composition as claimed in claim 39, wherein said weak acid comprises hydroxy carboxylic acid, and further comprises the step of adding yet a third weak acid to control hydronium ion production created by the disassociation of hydrochloric acid in water as well as created by the addition of said hydroxy carboxylic acid.
Claim 44
Dependent Claim 18 words
The radiator cleaning composition as claimed in claim 40, wherein said additional weak acid comprises a dicarboxylic acid.
Claim 45
Dependent Claim 17 words
The radiator cleaning composition as claimed in claim 32, wherein said glycol base comprises butyl ethylene glycol.

References Cited (Backward Citations)

US4181622A Cited
US4199469A Cited
US4250048A Cited
US4477364A Cited
US4569779A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-11-12 1994-05-14 1994-11-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-11-12 1998-05-14 1998-11-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-11-12 2002-05-14 2002-11-13 $7700.00 Window Closed / Lapsed

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