Bonding method using photocurable acrylate adhesive containing perester/tautomeric acid adhesion promoter

Claim 2

In a method for bonding surfaces to one another, the steps comprising: (a) providing a liquid composition capable of reaction to an adhesive solid when exposed to actinic radiation, comprising a major proportion of at least one polymerizable acrylate monomer and an elastomeric domain-providing filler, an effective amount of an actinic radiation-responsive photoinitiator and, based upon the weight of said composition, about 1.0 to 5.0 percent of a perester compound having free radical-initiating capability and about 0.5 to 5.0 percent of an organic acid capable of cyclic tautomerism, said composition being free from stabilizers containing sulfur or the amine functionality; (b) applying said composition to at least one of the surfaces to be bonded, and effecting contact of another surface therewith; and (c) exposing said composition between said surfaces to actinic radiation for a period of time sufficient to effect curing of said composition to an adhesive solid.

Claim 3

The method of claim 1 wherein, in said composition said perester compound is selected from the group consisting of tert-butyl perbenzoate and tert-butyl peroctoate, and wherein said organic acid is maleic.

Claim 4

The method of claim 1 wherein, in said composition said filler is an acrylated polyurethane oligomer.

Claim 5

The method of claim 3 wherein, in said composition said oligomer has a molecular weight of about 400 to 6000 and is a diisocyanate-capped polyether acrylated by reaction with hydroxyethyl acrylate or hydroxyethyl methacrylate.

Claim 6

The method of claim 1 wherein, in said composition said acrylate monomer is a compound selected from the group consisting of isobornyl acrylate, hydroxyethyl methacrylate, polyethyleneglycol dimethacrylate, trimethylcyclohexyl acrylate, and mixtures thereof.

Claim 7

The method of claim 1 wherein, in said composition said photoinitiator is a compound selected from the group consisting of diethoxy acetophenone, 1-hydroxycyclohexylphenyl ketone, 2-methyl-1-(methylthiophenyl)-2-(4-morpholinyl)-1propanone, and 2,2-dimethoxy-2-phenyl acetophenone, and wherein said actinic radiation is in the ultaviolate range.

Claim 8

The method of claim 1 wherein said composition additionally includes about 2.0 to 6.0 percent by weight thereof of acrylic acid.

Claim 9

The method of claim 1 wherein at least one of said surfaces is glass.

Claim 10

The method of claim 8 wherein a silane adhesion promoter is additionally included in said composition.

Claim 11

In a method for bonding surfaces to one another, the steps comprising: (a) providing a liquid composition capable of reaction to an adhesive solid when exposed to actinic radiation, comprising a major proportion of at least one polymerizable acrylate monomer and an elastomeric domain-providing filler, an effective amount of an actinic radiation-responsive photoinitiator and, based upon the weight of said composition, about 1.0 to 5.0 percent of a compound selected from the class consisting of perester compounds having free radical-initiating capability and cumene hydroperoxide, and about 0.5 to 5.0 percent of an organic acid capable of cyclic tautomerism, said composition being free from stabilizers containing sulfur or the amine functionality; (b) applying said composition to at least one of the surfaces to be bonded, and effecting contact of another surface therewith; and (c) exposing said composition between said surfaces to actinic radiation for a period of time sufficient to effect curing of said composition to an adhesive solid.

Claim 12

In a method for bonding surfaces to one another, the steps comprising: (a) providing a liquid composition capable of reaction to an adhesive solid when exposed to actinic radiation, comprising a major proportion of at least one polymerizable acrylate monomer and an elastomeric domain-providing filler, an effective amount of an actinic radiation-responsive photoinitiator and, based upon the weight of said composition, about 1.0 to 5.0 percent of a compound selected from the class consisting of perester compounds having free radical-initiating capability and cumene hydroperoxide, and about 0.5 to 5.0 percent of an organic acid capable of cyclic tautomerism, said composition being free from stabilizers containing sulfur or the amine functionality; (b) applying said composition to at least one of the surfaces to be bonded, and effecting contact of another surface therewith; and (c) exposing said composition between said surfaces to actinic radiation for a period of time sufficient to effect curing of said composition to an adhesive solid.

Claim 13

In a method for bonding surfaces to one another, the steps comprising: (a) providing a liquid composition capable of reaction to an adhesive solid when exposed to actinic radiation, comprising a major proportion of at least one polymerizable acrylate monomer and a elastomeric domain-providing filler, an effective amount of an actinic radiation-responsive photoinitiator and, based upon the weight of said composition, about 1.0 to 5.0 percent of tert-butyl peroctoate and about 0.5 to 5.0 percent of an organic acid capable of cyclic tautomerism, said composition being free from stabilizers containing sulfur or the amine functionality; (b) applying said composition to at least one of the surfaces to be bonded, and effecting contact of another surface therewith; and (c) exposing said composition between said surfaces to actinic radiation for a period of time sufficient to effect curing of said composition to an adhesive solid.

Claim 14

In a method for bonding surfaces to one another, the steps comprising: (a) providing a liquid composition capable of reaction to an adhesive solid when exposed to actinic radiation, comprising a major proportion of at least one polymerizable acrylate monomer and a elastomeric domain-providing filler, an effective amount of an actinic radiation-responsive photoinitiator and, based upon the weight of said composition, about 1.0 to 5.0 percent of tert-butyl peroctoate and about 0.5 to 5.0 percent of an organic acid capable of cyclic tautomerism, said composition being free from stabilizers containing sulfur or the amine functionality; (b) applying said composition to at least one of the surfaces to be bonded, and effecting contact of another surface therewith; and (c) exposing said composition between said surfaces to actinic radiation for a period of time sufficient to effect curing of said composition to an adhesive solid.

Claim 15

The method of claim 11 wherein said organic acid is maleic.