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US4964133A
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Lasers in alkali halides using N and R color-centers
Assignee: Cornell Research Foundation Inc
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Filing: 1989-04-14
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Granted: 1990-10-16
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Expires: 2009-04-14
Abstract
Abstract The laser material of the invention comprises an alkali-halide crystal, with a rocksalt crystallographic structure, containing point defects selected from the group consisting of F 3 or R, F 4 and N 2 color centers. The preferred laser material is based on the neutral "N 2 " color center defect. The alkali halide can be any alkali halide, for example, lithium, sodium, potassium and rubidium chloride, bromide and fluoride. The preferred alkali halide is potassium chloride. The lasers of the invention comprise a stable near-infrared laser which can be tuned in the case of KCl for example from 1.23 to 1.35 μm, and can be optically pumped at 1.06 μm, for example from a Q-switched Nd:YAG laser. The laser of the invention represent the first reported laser based on N 2 -center transitions, and appear to be the first stable laser using a charge-neutral color center in pure alkali halide hosts.
Inventors
- 👤 Clifford R. Pollock
- 👤 Efstratios T. Georgiou
- 👤 Timothy J. Carrig
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 15:56
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/14; H01S3/16; H01S3/1681
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
19 words
A laser material which comprises an alkali-halide crystal having a rocksalt crystallographic structure with N 2 color-center point defects.
Claim 2
Dependent Claim
19 words
A laser material which comprises an alkali-halide crystal having a rocksalt crystallographic structure with N 2 color-center point defects.
Claim 3
Dependent Claim
26 words
The laser material of claim 1 wherein said alkali halide is selected from the class consisting of lithium, sodium, potassium, and rubidium chloride, bromide and fluoride.
Claim 4
Dependent Claim
20 words
The laser material of claim 1 wherein said alkali halide is selected from sodium chloride, potassium chloride, and potassium bromide.
Claim 5
Dependent Claim
12 words
The laser material of claim 1 wherein alkali halide is potassium chloride.
Claim 6
Independent Claim
58 words
A method of generating laser-active N 2 centers in an alkali halide which comprises the steps: a. coloring said crystal to provide F color centers; b. illuminating said crystal with light in approximately the spectral region of an F center absorption band at a temperature above about 250° K. until the N 2 center concentration is significantly increased.
Claim 7
Independent Claim
58 words
A method of generating laser-active N 2 centers in an alkali halide which comprises the steps: a. coloring said crystal to provide F color centers; b. illuminating said crystal with light in approximately the spectral region of an F center absorption band at a temperature above about 250° K. until the N 2 center concentration is significantly increased.
Claim 8
Dependent Claim
71 words
The method as in claim 5 of generating laser-active N 2 centers in an alkali halide which comprises the steps: a. additively coloring said crystal to provide F color centers; b. quenching said crystal to retard colloid formation; c. illuminating said crystal with light in approximately the spectral region of the F center absorption band at a temperature above about 250° K. until the N 2 center concentration is significantly increased.
Claim 9
Dependent Claim
21 words
The method of claim 6 wherein the illuminating is with light at slightly longer wavelengths than the F center absorption band.
Claim 10
Dependent Claim
11 words
The method of claim 5 wherein alkali halide is potassium chloride.
Claim 11
Independent Claim
56 words
A method of generating laser-active R centers in an alkali halide which comprises the steps: a. coloring said crystal to provide F color centers; b. illuminating said crystal with light in approximately the spectral region of an F center absorption band at a temperature above about 250° K. until the R center concentration is significantly increased.
Claim 12
Independent Claim
56 words
A method of generating laser-active R centers in an alkali halide which comprises the steps: a. coloring said crystal to provide F color centers; b. illuminating said crystal with light in approximately the spectral region of an F center absorption band at a temperature above about 250° K. until the R center concentration is significantly increased.
Claim 13
Dependent Claim
69 words
The method as in claim 9 of generating laser-active R centers in an alkali halide which comprises the steps: a. additively coloring said crystal to provide F color centers; b. quenching said crystal to retard colloid formation; c. illuminating said crystal with light in approximately the spectral region of the F center absorption band at a temperature above about 250° K. until the R center concentration is significantly increased.
Claim 14
Dependent Claim
21 words
The method of claim 9 wherein the illuminating is with light at wavelengths slighly longer than the F center absoption band.
Claim 15
Independent Claim
57 words
A method of generating laser-active N 2 and R centers in an alkali halide which comprises the steps: a. coloring said crystal; b. illuminating said crystal with light in approximately the spectral region of an R 1 center absorption band at a temperature above about 250° K. until the N and R center concentration is significantly increased.
Claim 16
Independent Claim
57 words
A method of generating laser-active N 2 and R centers in an alkali halide which comprises the steps: a. coloring said crystal; b. illuminating said crystal with light in approximately the spectral region of an R 1 center absorption band at a temperature above about 250° K. until the N and R center concentration is significantly increased.
Claim 17
Dependent Claim
71 words
The method as in claim 12 of generating laser-active N 2 and R centers in an alkali halide which comprises the steps: a. additively coloring said crystal; b. quenching said crystal to retard colloid formation; c. illuminating said crystal with light in approximately the spectral region of the an R 1 center absorption band at a temperature above about 250° K. until the N and R center concentration is significantly increased.
Claim 18
Dependent Claim
11 words
The method of claim 13 wherein alkali halide is potassium chloride.
Claim 19
Dependent Claim
12 words
The method of claim 13 wherein light is provided by red light.
Claim 20
Dependent Claim
16 words
The method of claim 12 wherein the coloring is achieved by electrolytic coloration or radiation damage.
Claim 21
Dependent Claim
107 words
In an apparatus for amplifying light by stimulated emission of radiation, the improvement which comprises: a. laser medium which is the alkali halide crystal having a rocksalt crystallographic structure with N 2 color-center point defects b. means for exposing said crystal with light in the absorption bands of the N 2 center of said crystal to produce a population invention in the energy configuration of said crystal; c. an optical cavity, in which said crystal is located, said cavity being capable of resonating at the fluorescence bands of N 2 and R centers and thus capable of stimulating the emission of coherent radiation from said color centers;
Claim 22
Dependent Claim
107 words
In an apparatus for amplifying light by stimulated emission of radiation, the improvement which comprises: a. laser medium which is the alkali halide crystal having a rocksalt crystallographic structure with N 2 color-center point defects b. means for exposing said crystal with light in the absorption bands of the N 2 center of said crystal to produce a population invention in the energy configuration of said crystal; c. an optical cavity, in which said crystal is located, said cavity being capable of resonating at the fluorescence bands of N 2 and R centers and thus capable of stimulating the emission of coherent radiation from said color centers;
Claim 23
Dependent Claim
18 words
The apparatus of claim 17 further comprising means for maintaining the crystal at about 100° K. or lower.
Claim 24
Dependent Claim
29 words
The apparatus of claim 18 wherein said cavity has a two mirror and two lens configuration and said laser medium is located at the beam waist of said cavity.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-10-15 | 1994-04-16 | 1994-10-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-10-15 | 1998-04-16 | 1998-10-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-10-15 | 2002-04-16 | 2002-10-16 | $7700.00 | Window Closed / Lapsed |