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Bisacrylate monomers and polymers exhibiting nonlinear optical response

Assignee: CNA Holdings LLC
•
Filing: 1989-11-13
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Granted: 1990-10-16
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Expires: 2009-11-13
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Abstract

Abstract This invention provides novel bisacrylate monomers and thermoset polymers which exhibit nonlinear optical response. The polymers have utility as a transparent nonlinear optical component in optical light switch and light modulator devices. An invention bisacrylate monomer is illustrated by the following structure: ##STR1##

Inventors

  • 👤 Ronald N. DeMartino
  • 👤 Anthony J. East
  • 👤 Gordon W. Calundann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:20
CPC Classifications
C; C07; C07C; C07C255/00; C07C255/49; C07C255/58; C07C219/00; C07C219/02; C07C219/04; C07C219/08; C08; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/34; G; G02; G02F; G02F1/00; G02F1/35; G02F1/355; G02F1/361; G02F1/3611

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 115 words
A process for producing a nonlinear optical medium which comprises heating and forming a melt phase medium of a bisacrylate composition corresponding to the formula: ##STR7## where R is a C 1 -C 4 alkyl substituent, R 1 is a divalent C 2 -C 12 alkylene radical, m is an integer with a value of 0-2, n is an integer with a value of 0-1, and X is an electron-withdrawing substituent; subjecting the melt phase to an external field to induce an orientation of aligned molecules in the medium, and forming a solid phase of the molecularly oriented medium while maintaining the external field effect to freeze the molecular orientation in the formed solid phase.
Claim 2
Dependent Claim 115 words
A process for producing a nonlinear optical medium which comprises heating and forming a melt phase medium of a bisacrylate composition corresponding to the formula: ##STR7## where R is a C 1 -C 4 alkyl substituent, R 1 is a divalent C 2 -C 12 alkylene radical, m is an integer with a value of 0-2, n is an integer with a value of 0-1, and X is an electron-withdrawing substituent; subjecting the melt phase to an external field to induce an orientation of aligned molecules in the medium, and forming a solid phase of the molecularly oriented medium while maintaining the external field effect to freeze the molecular orientation in the formed solid phase.
Claim 3
Dependent Claim 19 words
A process in accordance with claim 1, wherein the solid phase is formed by cooling of the melt phase.
Claim 4
Dependent Claim 22 words
A process in accordance with claim 1 wherein polymerization of the bisacrylate occurs in the melt phase after molecular orientation is induced.
Claim 5
Dependent Claim 19 words
A process in accordance with claim 1 wherein polymerization of the bisacrylate occurs in the molecularly oriented solid phase.
Claim 6
Dependent Claim 13 words
A nonlinear optical medium produced in accordance with the process of claim 1.

References Cited (Backward Citations)

JPH08170737A Cited
US4613619A Cited
EP0321891A2 Cited
JPH03290857A Cited
JPH0740448A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-10-15 1994-04-16 1994-10-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-10-15 1998-04-16 1998-10-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-10-15 2002-04-16 2002-10-16 $7700.00 Window Closed / Lapsed

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