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US4946895A Expired / Lapsed US ⏱️ 0.0 years remaining

Resinous composition for powder coating

Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1989-09-29
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Granted: 1990-08-07
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Expires: 2009-09-29
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Abstract

Abstract A resinous composition suitable for powder coating on metals on which a heat resistant coating layer is formed contains (A) modified polypropylene in which unsaturated carboxylic acid or anhydride is grafted on crystalline propylene/ alpha -olefin copolymer, (B) ethylene polymer, (C) metal oxide or hydroxide and (D) polymers of C6 or more vinyl cycloalkane and the composition contains 0.001-1.0% by weight of the vinyl cycloalkane unit.

Inventors

  • 👤 Tadayuki Ohmae
  • 👤 Kentaro Mashita
  • 👤 Kizuku Wakatsuki
  • 👤 Toshio Kawakita

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 08:45
CPC Classifications
C; C09; C09D; C09D151/00; C09D151/06

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 184 words
A resinous composition for powder coating which comprises (A) 80-95 parts by weight of a modified polypropylene in which an unsaturated carboxylic acid or anhydride thereof is grafted onto at least a part of a crystalline random copolymer of (a) 90-99% by weight of propylene and (b) 10-1% by weight of a α-olefin having 2-10 carbon atoms excluding propylene, said modified polypropylene having a melt index of 10-60 g/10 min. and containing 0.01-5% by weight of said unsaturated carboxylic acid or anhydride thereof, (B) 20-5 parts by weight of at least one ethylene polymer selected from a low density polyethylene, a linear low density polyethylene and a copolymer of ethylene with 10% by weight or less of an ester of an unsaturated carboxylic acid or a vinyl ester of a fatty acid, (C) 0.1-10 parts by weight of an oxide or hydroxide of a metal of IIa, IIIa or IVb of the Mendelleev's Periodic Table, and (D) a vinyl cycloalkane polymer having at least six carbon atoms in such an amount that the units of vinyl cycloalkane are 0.001-1.0% by weight of the composition.
Claim 2
Dependent Claim 184 words
A resinous composition for powder coating which comprises (A) 80-95 parts by weight of a modified polypropylene in which an unsaturated carboxylic acid or anhydride thereof is grafted onto at least a part of a crystalline random copolymer of (a) 90-99% by weight of propylene and (b) 10-1% by weight of a α-olefin having 2-10 carbon atoms excluding propylene, said modified polypropylene having a melt index of 10-60 g/10 min. and containing 0.01-5% by weight of said unsaturated carboxylic acid or anhydride thereof, (B) 20-5 parts by weight of at least one ethylene polymer selected from a low density polyethylene, a linear low density polyethylene and a copolymer of ethylene with 10% by weight or less of an ester of an unsaturated carboxylic acid or a vinyl ester of a fatty acid, (C) 0.1-10 parts by weight of an oxide or hydroxide of a metal of IIa, IIIa or IVb of the Mendelleev's Periodic Table, and (D) a vinyl cycloalkane polymer having at least six carbon atoms in such an amount that the units of vinyl cycloalkane are 0.001-1.0% by weight of the composition.
Claim 3
Dependent Claim 15 words
A composition according to claim 1, wherein the crystalline random copolymer is a propylene/ethylene copolymer.
Claim 4
Dependent Claim 19 words
A composition according to claim 1, wherein the crystalline random copolymer has a melt index of 1-20 g/10 min.
Claim 5
Dependent Claim 29 words
A composition according to claim 1, wherein graft-copolymerization for production of the modified polypropylene (A) is conducted at a temperature of 100°-250° C. in the presence of a peroxide.
Claim 6
Dependent Claim 21 words
A composition according to claim 1, wherein the ethylene polymer (B) is a low density polyethylene or linear low density polyethylene.
Claim 7
Dependent Claim 21 words
A composition according to claim 1, wherein the metal oxide or hydroxide (C) is magnesium oxide, calcium hydroxide or magnesium hydroxide.
Claim 8
Dependent Claim 23 words
A composition according to claim 1, wherein said vinyl cycloalkane is vinyl cyclobutane, vinyl cyclopentane, vinyl-3-methylcyclopentane, vinyl cyclohexane, vinyl-2-methylcyclohexane, vinyl-3-methylcyclohexane or vinyl norbornane.
Claim 9
Dependent Claim 13 words
A composition according to claim 7, wherein said vinyl cycloalkane is vinyl cyclohexane.

References Cited (Backward Citations)

US4301062A Cited
JPS5852338A Cited
US4562230A Cited
JPS5930841A Cited
US4551501A Cited
US4762882A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-08-06 1994-02-05 1994-08-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-08-06 1998-02-05 1998-08-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-08-06 2002-02-05 2002-08-07 $7700.00 Window Closed / Lapsed

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