US4931487A — Chain extenders for polyurethanes

Claim 1

Independent Claim 405 words

A process for producing polyurethane or polyurethane-polyurea polymers by subjecting to a reaction injection molding process, a reaction mixture comprising (1) at least one polyisocyanate components: (2) at least one relatively high equivalent weight active hydrogen component; and (3) a diamine chain extender selected from the group consisting of: (a) heterocyclic diamines having a structure represented by Formula I: ##STR6## wherein each G is a divalent bridging group or a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (b) di(aromatic amine) disulfides; (c) alkyl ethers of halogen-substituted aromatic diamines having a structure represented by Formula III ##STR7## wherein m is an integer in the range of 0 to about 2 and n is an integer in the range of 1 to about 2, such that the sum of n and m is 3; J is nothing or --CH 2 --; each R 2 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an alkyl group, which alkyl or aryl groups are substituted or unsubstituted with groups that do not interfere undesirably with polyurethane formation; each R 3 is independently a halogen-substituted alkyl group or a halogen atom; and R 4 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (d) polysubstituted alkyl diamines having at least one highly electronegative group geminate to each amine group; (e) alkyl acid esters of halogen substituted diamino phenols having a structure represented by Formula V: ##STR8## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or a halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; and (f) mixtures thereof.

Claim 2

Dependent Claim 405 words

A process for producing polyurethane or polyurethane-polyurea polymers by subjecting to a reaction injection molding process, a reaction mixture comprising (1) at least one polyisocyanate components: (2) at least one relatively high equivalent weight active hydrogen component; and (3) a diamine chain extender selected from the group consisting of: (a) heterocyclic diamines having a structure represented by Formula I: ##STR6## wherein each G is a divalent bridging group or a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (b) di(aromatic amine) disulfides; (c) alkyl ethers of halogen-substituted aromatic diamines having a structure represented by Formula III ##STR7## wherein m is an integer in the range of 0 to about 2 and n is an integer in the range of 1 to about 2, such that the sum of n and m is 3; J is nothing or --CH 2 --; each R 2 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an alkyl group, which alkyl or aryl groups are substituted or unsubstituted with groups that do not interfere undesirably with polyurethane formation; each R 3 is independently a halogen-substituted alkyl group or a halogen atom; and R 4 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (d) polysubstituted alkyl diamines having at least one highly electronegative group geminate to each amine group; (e) alkyl acid esters of halogen substituted diamino phenols having a structure represented by Formula V: ##STR8## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or a halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; and (f) mixtures thereof.

Claim 3

Dependent Claim 18 words

The process of claim 1 wherein at least one relatively high equivalent weight compound is a polyether polyol.

Claim 4

Dependent Claim 21 words

The process of claim 1 wherein at least one relatively high equivalent weight compound is a polyester polyol produced from oxiranes.

Claim 5

Dependent Claim 19 words

The process of claim 1 wherein at least one relatively high equivalent weight compound is an aminated polyether polyol.

Claim 6

Dependent Claim 19 words

The process of claim 1 wherein at least one relatively high equivalent weight compound is an aminated polyester polyol.

Claim 7

Dependent Claim 14 words

The process of claim 1 wherein at least one polyisocyanate component is toluene diisocyanate.

Claim 8

Dependent Claim 17 words

The process of claim 1 wherein at least one polyisocyanate component is diphenylmethane-4,4'-diisocyanate, diphenylmethane-2,4'-diisocyanate, or polymethylene polyphenylisocyanate.

Claim 9

Dependent Claim 81 words

The process of claim 1 wherein the chain extender is a heterocyclic diamine and has a structure represented by Formula I: ##STR9## wherein each G is a divalent bridging group or a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation.

Claim 10

Dependent Claim 17 words

The process of claim 8 wherein the chain extender is 2,6-diaminopyridine, or 2,6-diaminopyrazine, or 2,6-diaminopyrimidine, or 2,6-diamino-4-phenyl-s-triazine.

Claim 11

Dependent Claim 66 words

The process of claim 1 wherein the di(aromatic amine) disulfide and has a structure represented by Formula II: ##STR10## wherein each R' is independently (a) hydrogen, (b) an alkyl group having from one to about three carbon atoms, or (c) an aryl group, which alkyl groups (b) or aryl groups (c) are unsubstituted or are substituted with groups which do not interfere undesirably with polyurethane formation.

Claim 12

Dependent Claim 15 words

The process of claim 10 wherein both amine groups are para to the disulfide group.

Claim 13

Dependent Claim 12 words

The process of claim 11 wherein the di(aromatic amine) disulfide is di(para-aminophenyl)disulfide.

Claim 14

Dependent Claim 144 words

The process of claim 1 wherein the chain extender is an alkyl ether of halogen-substituted aromatic diamine and has a structure represented by Formula III ##STR11## wherein m is an integer in the range of 0 to about 2 and n is an integer in the range of 1 to about 2, such that the sum of n and m is 3; J is nothing or --CH 2 --; each R 2 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 3 is independently a halogen-substituted alkyl group or a halogen atom; and R 4 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation.

Claim 15

Dependent Claim 12 words

The process of claim 13 wherein each R 2 group is H.

Claim 16

Dependent Claim 14 words

The process of claim 13 wherein each R 3 group is a perfluoroalkyl group.

Claim 17

Dependent Claim 30 words

The process of claim 13 wherein the chain extender is an alkyl ether of a halogen-substituted aromatic diamine of Formula III and each amine group is adjacent the ether group.

Claim 18

Dependent Claim 16 words

The process of claim 16 wherein the alkyl ether of a halogen-substituted aromatic diamine is 1-chloro-4-trifluoromethoxy-2,6-diaminobenzene.

Claim 19

Dependent Claim 134 words

The process of claim 1 wherein the chain extender is a polysubstituted alkyl diamine represented by Formula IV: ##STR12## wherein Q is (CX 2 )q--, --(CX 2 ) r --Ar--(CX 2 )s--; q, s and r are integers in the range of 0 to about 4 and each X group is independently Z or is a branched or straight chain alkyl group represented by the formula --C t Z.sub.(2t+1) --, where each Z is independently hydrogen, a halogen, a perhalogenated methyl group, or a cyano group, and t is an integer in the range of 1 to about 2; wherein at least one X group geminate to each amino group is not hydrogen: and Ar is divalent aromatic radical which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation.

Claim 20

Dependent Claim 140 words

The process of claim 1 wherein the chain extender is an alkyl acid ester of a halogen-substituted diamino phenol and has a structure represented by Formula V ##STR13## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or a halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation.

Claim 21

Dependent Claim 26 words

The process of claim 19 wherein each R 6 is hydrogen, each R 7 is chlorine, and each amino group is ortho to the ester group.

Claim 22

Dependent Claim 10 words

The process of claim 19 wherein R 8 is trifluoromethyl.

Claim 23

Dependent Claim 17 words

The process of claim 19 wherein the alkyl acid ester of a diamino phenol is 2,6 diamino-4-chloro-1-perfluoroacetate.

Claim 24

Dependent Claim 15 words

The process of claim 1 wherein the reaction mixture additionally comprises a second chain extender.

Claim 25

Dependent Claim 12 words

The process of claim 1 wherein the process is a one-shot process.

Claim 26

Dependent Claim 12 words

The process of claim 10 wherein the process is a one-shot process.

Claim 27

Dependent Claim 26 words

The process of claim 8 wherein G is selected from the group consisting of unsubstituted or inertly substituted alkyl, aryl, alkylaryl groups and a covalent bond.

Claim 28

Dependent Claim 304 words

A process for producing a polyurethane or polyurethane-polyurea by polymerizing a reaction mixture comprising (1) at least one polyisocyanate component; (2) at least one relatively high equivalent eight active hydrogen component; and (3) at least one chain extender selected from the group consisting of: (a) heterocyclic diamines having a structure represented by Formula I: ##STR14## wherein each G is a divalent bridging group selected from the group consisting of unsubstituted or inertly substituted alkyl, aryl, alkylaryl groups and a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group and at least one Y is a nitrogen atom, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (b) polysubstituted alkyl diamines having at least one highly electronegative group geminate to each amino group; and (c) alkyl acid esters of halogen substituted diamino phenols having a structure represented by Formula V: ##STR15## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or a halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; and (d) mixtures thereof wherein component (2) and chain extender (3) are mixed together and subsequently mixed with polyisocyanate component (1).

Claim 29

Dependent Claim 304 words

A process for producing a polyurethane or polyurethane-polyurea by polymerizing a reaction mixture comprising (1) at least one polyisocyanate component; (2) at least one relatively high equivalent eight active hydrogen component; and (3) at least one chain extender selected from the group consisting of: (a) heterocyclic diamines having a structure represented by Formula I: ##STR14## wherein each G is a divalent bridging group selected from the group consisting of unsubstituted or inertly substituted alkyl, aryl, alkylaryl groups and a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group and at least one Y is a nitrogen atom, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (b) polysubstituted alkyl diamines having at least one highly electronegative group geminate to each amino group; and (c) alkyl acid esters of halogen substituted diamino phenols having a structure represented by Formula V: ##STR15## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or a halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; and (d) mixtures thereof wherein component (2) and chain extender (3) are mixed together and subsequently mixed with polyisocyanate component (1).

Claim 30

Dependent Claim 291 words

A composition of matter comprising (1) a relatively high equivalent weight polyfunctional active hydrogen component; (2) a chain extender selected from the group consisting of: (a) heterocyclic diamines having a structure represented by Formula I: ##STR16## wherein each G is a divalent bridging group selected from the group consisting of unsubstituted or inertly substituted alkyl, aryl, alkylaryl groups and a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group and at least one Y is a nitrogen atom, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (b) polysubstituted alkyl diamines having at least one highly electronegative group geminate to each amino group; (c) alkyl acid esters of halogen substituted diamino phenols having a structure represented by Formula V: ##STR17## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or a halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation and (d) mixtures thereof; and (3) at least one polyisocyanate component wherein component (1) and chain extender (2) are mixed together and subsequently mixed with polyisocyanate component (3).

Claim 31

Dependent Claim 291 words

A composition of matter comprising (1) a relatively high equivalent weight polyfunctional active hydrogen component; (2) a chain extender selected from the group consisting of: (a) heterocyclic diamines having a structure represented by Formula I: ##STR16## wherein each G is a divalent bridging group selected from the group consisting of unsubstituted or inertly substituted alkyl, aryl, alkylaryl groups and a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group and at least one Y is a nitrogen atom, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (b) polysubstituted alkyl diamines having at least one highly electronegative group geminate to each amino group; (c) alkyl acid esters of halogen substituted diamino phenols having a structure represented by Formula V: ##STR17## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or a halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation and (d) mixtures thereof; and (3) at least one polyisocyanate component wherein component (1) and chain extender (2) are mixed together and subsequently mixed with polyisocyanate component (3).

Claim 32

Dependent Claim 401 words

A polyurethane or polyurethane-polyurea polymer produced by subjecting to a reaction injection molding process, a reaction mixture comprising (1) at least one polyisocynate component; (2) at least one relatively high equivalent weight active hydrogen component; and (3) a chain extender selected from the group consisting of: (a) heterocyclic diamines having a structure represented by Formula I: ##STR18## wherein each G is a divalent bridging group or a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted ith groups which do not interfere undesirably with polyurethane formation; (b) di(aromatic amine) disulfides; (c) alkyl ethers of halogen-substituted aromatic diamines having a structure represented by Formula III: ##STR19## wherein m is an integer in the range of 0 to about 2 and n is an integer in the range of 1 to about 2, such that the sum of n and m is 3; J is nothing or --CH 2 --; each R 2 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 3 is independently a halogen-substituted alkyl group or a halogen atom; and R 4 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (d) polysubstituted alkyl diamines having at least one highly electronegative group geminate to each amine group; (e) alkyl acid esters of halogen substituted diamino phenols having a structure represented by Formula V: ##STR20## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation and (f) mixtures thereof.

Claim 33

Dependent Claim 401 words

A polyurethane or polyurethane-polyurea polymer produced by subjecting to a reaction injection molding process, a reaction mixture comprising (1) at least one polyisocynate component; (2) at least one relatively high equivalent weight active hydrogen component; and (3) a chain extender selected from the group consisting of: (a) heterocyclic diamines having a structure represented by Formula I: ##STR18## wherein each G is a divalent bridging group or a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted ith groups which do not interfere undesirably with polyurethane formation; (b) di(aromatic amine) disulfides; (c) alkyl ethers of halogen-substituted aromatic diamines having a structure represented by Formula III: ##STR19## wherein m is an integer in the range of 0 to about 2 and n is an integer in the range of 1 to about 2, such that the sum of n and m is 3; J is nothing or --CH 2 --; each R 2 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 3 is independently a halogen-substituted alkyl group or a halogen atom; and R 4 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (d) polysubstituted alkyl diamines having at least one highly electronegative group geminate to each amine group; (e) alkyl acid esters of halogen substituted diamino phenols having a structure represented by Formula V: ##STR20## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation and (f) mixtures thereof.

Claim 34

Dependent Claim 284 words

A polyurethane or polyurethane-polyurea produced by polymerizing a reaction mixture comprising (1) at least one polyisocyanate component; (2) at least one relatively high equivalent weight active hydrogen component; and (3) at least one chain extender selected from the group consisting of: (a) heterocyclic diamines having a structure represented by Formula I: ##STR21## wherein each G is a divalent bridging group selected from the group consisting of unsubstituted or inertly substituted alkyl, aryl, alkylaryl groups and a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group and at least one Y is a nitrogen atom, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (b) polysubstituted alkyl diamines having at least one highly electronegative group geminate to each amino group; and (c) alkyl acid esters of halogen substituted diamino phenols having a structure represented by Formula V: ##STR22## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or a halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation and (d) mixtures thereof.

Claim 35

Dependent Claim 284 words

A polyurethane or polyurethane-polyurea produced by polymerizing a reaction mixture comprising (1) at least one polyisocyanate component; (2) at least one relatively high equivalent weight active hydrogen component; and (3) at least one chain extender selected from the group consisting of: (a) heterocyclic diamines having a structure represented by Formula I: ##STR21## wherein each G is a divalent bridging group selected from the group consisting of unsubstituted or inertly substituted alkyl, aryl, alkylaryl groups and a covalent bond; each Y is independently nitrogen or a ═CR-- group, but at least one Y is a ═CR-- group and at least one Y is a nitrogen atom, wherein each R is independently hydrogen, an alkyl group or an aryl group which groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; (b) polysubstituted alkyl diamines having at least one highly electronegative group geminate to each amino group; and (c) alkyl acid esters of halogen substituted diamino phenols having a structure represented by Formula V: ##STR22## wherein w is an integer in the range of about 0 to about 2 and x is an integer in the range of 1 to about 3, such that the sum of w and x is 3; each R 6 is independently hydrogen, an alkyl group having from one to about three carbon atoms, or an aryl group, which alkyl or aryl groups are unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation; each R 7 is independently a halogen-substituted alkyl group or a halogen atom; and R 8 is an alkyl group which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation and (d) mixtures thereof.

Claim 36

Dependent Claim 30 words

The composition of claim 28 wherein the chain extender is a heterocyclic diamine having a structure represented by Formula I wherein at least one Y is nitrogen or mixtures thereof.

Claim 37

Dependent Claim 26 words

The composition of claim 28 wherein the chain extender is an alkyl acid ester of a halogen-substituted diamino phenol having a structure represented by Formula V.

Claim 38

Dependent Claim 43 words

The polyurethane or polyurethane-polyurea of claim 29 wherein the chain extender is a heterocyclic diamine having a structure represented by Formula I wherein G is selected from the group consisting of unsubstituted or inertly substituted alkyl, aryl, alkylaryl groups and a covalent bond.

Claim 39

Dependent Claim 28 words

The polyurethane or polyurethane-polyurea of claim 29 wherein the chain extender is an alkyl acid ester of a halogen-substituted diamino phenol having a structure represented by Formula V.

Claim 40

Dependent Claim 27 words

The polyurethane or polyurethane-polyurea of claim 29 wherein the chain extender is an alkyl ether of a halogen-substituted aromatic diamine having a structure represented by Formula III.

Claim 41

Dependent Claim 157 words

The polyurethane or polyurethane-polyurea of claim 29 wherein the chain extender is a polysubstituted alkyl diamine having at least one highly electronegative group geminate to each amine group and having a structure represented by Formula IV: ##STR23## wherein Q is (CX 2 ) q --, --(CX 2 ) r --Ar--(CX 2 ) s --; q, s and r are integers in the range of 0 to about 4 and each X group is independently Z or is a branched or straight chain alkyl group represented by the formula --C t Z.sub.(2t+1) --, where each Z is independently hydrogen, a halogen, a perhalogenated methyl group, or a cyano group, and t is an integer in the range of 1 to about 2; wherein at least one X group germinate to each amino group is not hydrogen; and Ar is a divalent aromatic radical which is unsubstituted or substituted with groups which do not interfere undesirably with polyurethane formation.

Claim 42

Dependent Claim 71 words

The polyurethane or polyurethane-polyurea of claim 29 wherein the chain extender is a di(aromatic amine) disulfide having a structure represented by Formula IV: ##STR24## wherein each R' is independently (a) hydrogen, (b) an alkyl group having from one to about three carbon atoms, or (c) an aryl group, which alkyl groups (b) or aryl groups (c) are unsubstituted or are substituted with groups which do not interfere undesirably with polyurethane formation.

Claim 43

Dependent Claim 36 words

The process of claim 30 herein the highly electronegative groups geminate to each amino group in chain extender (b) are independently selected from the group consisting of halogen atoms, perhaloalkyl groups, nitro groups, and cyano groups.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1993-06-04	1993-12-04	1994-06-05	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1997-06-04	1997-12-04	1998-06-05	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	2001-06-04	2001-12-04	2002-06-05	$7700.00	Window Closed / Lapsed

Chain extenders for polyurethanes

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