Process for the production of polyisocyanate compositions containing urea and/or biuret groups, the polyisocyanate compositions obtained by this process, and their use for the production of plastics by the isocyanate polyaddition process

Claim 2

A polyisocyanate containing urea and/or biuret groups and having an isocyanate content of about 0.7 to 45% by weight which is prepared by reacting (A) at least one organic polyisocyanate having an NCO content of about 10 to 50% by weight with (B) at least one organic compound containing isocyanate reactive groups comprising (i) a polyether or polyester having a molecular weight of 500 to about 20,000 and containing at least two isocyanate reactive groups comprising a member selected from the group consisting of alcoholic hydroxyl groups attached to primary carbon atoms, alcoholic hydroxyl groups attached to secondary carbon atoms, aromatically bound primary amino groups, aromatically bound secondary amino groups, cycloaliphatically bound primary amino groups, cycloaliphatically bound secondary amino groups, aliphatically bound primary amino groups, aliphatically bound secondary amino groups and mixtures thereof and, optionally, (ii) a low molecular weight organic compound comprising (a) an aromatic diamine or triamine having a molecular weight of 108 to 499 and containing primary and/or secondary amino groups, (b) an aliphatic or cycloaliphatic diamine or triamine having a molecular weight of 60 to 499 and containing primary and/or secondary amino groups, (c) an organic compound having a molecular weight of 61 to 499 and containing at least one alcoholic hydroxyl group attached to a primary or secondary carbon atom and at least one aliphatically, cycloaliphatically or aromatically bound primary or secondary amino group, (d) a compound containing at least two alcoholic hydroxyl groups and optionally at least one ether or ester group, (e) hydrazine or a derivative of hydrazine containing at least two reactive NH groups and (f) mixtures of (a)-(e), and (C) water wherein the equivalent ratio of isocyanate groups in component A to isocyanate reactive groups in components B and C is about 2:1 to 100:1; the equivalent ratio of isocyanate reactive groups in components B and C is about 1:0.1 to 1:10; the equivalent ratio of isocyanate reactive groups in components B1 and C to component B2 is about 1:0 to 1:10; and the equivalent ratio of isocyanate reactive groups in component B1 to component B2 is about 1:0 to 1:5.

Claim 3

The polyisocyanate of claim 1 wherein not more than about 75% of the isocyanate-reactive groups of component B are hydroxyl groups and the remainder are aminic or hydrazinic amino groups.

Claim 4

The polyisocyanate of claim 1 wherein component A comprises a modified polyisocyanate of the diphenyl methane series which is liquid at room temperature, has an NCO content of about 20 to 32% and comprises a member selected from the group consisting of urethane groups, carbodiimide groups, uretone amine groups and mixtures thereof.

Claim 5

The polyisocyanate of claim 1 wherein component B1 comprises a polyether having a molecular weight of about 1,000 to 7,000 and wherein at least about 50% of the isocyanate-reactive groups of said polyether are selected from the group consisting of aromatically bound primary amino groups, aliphatically bound primary amino groups and cycloaliphatically bound primary amino groups.

Claim 6

The polyisocyanate of claim 3 wherein component B1 comprises a polyether having a molecular weight of about 1,000 to 7,000 and wherein at least about 50% of the isocyanate-reactive groups of said polyether are selected from the group consisting of aromatically bound primary amino groups, aliphatically bound primary amino groups and cycloaliphatically bound primary amino groups.

Claim 7

The polyisocyanate of claim 1 wherein component B2 consists of an aromatic diamine containing a C 1 -C 4 alkyl substituent in at least one ortho position to each amino group.

Claim 8

The polyisocyanate of claim 1 wherein the equivalent ratio of isocyanate groups in component A to isocyanate reactive groups in component B is about 4:1 to 50:1.

Claim 9

The polyisocyanate of claim 1 which comprises reacting components A and B at a temperature of about 20° to 140° C.

Claim 10

A process for the production of a polyisocyanate containing urea and/or biuret groups and having an isocyanate content of about 0.7 to 45% by weight which is prepared by reacting (A) at least one organic polyisocyanate having an NCO content of about 10 to 50% by weight with (B) at least one organic compound containing isocyanate reactive groups comprising (i) a polyether or polyester having a molecular weight of 500 to about 20,000 and containing at least two isocyanate reactive groups comprising a member selected from the group consisting of alcoholic hydroxyl groups attached to primary carbon atoms, alcoholic hydroxyl groups attached to secondary carbon atoms, aromatically bound primary amino groups, aromatically bound secondary amino groups, cycloaliphatically bound primary amino groups, cycloaliphatically bound secondary amino groups, aliphatically bound primary amino groups, aliphatically bound secondary amino groups and mixtures thereof and, optionally, (ii) a low molecular weight organic compound comprising (a) an aromatic diamine or triamine having a molecular weight of 108 to 499 and containing primary and/or secondary amino groups, (b) an aliphatic or cycloaliphatic diamine or triamine having a molecular weight of 60 to 499 and containing primary and/or secondary amino groups, (c) an organic compound having a molecular weight of 61 to 499 and containing at least one alcoholic hydroxyl group attached to a primary or secondary carbon atom and at least one aliphatically, cycloaliphatically or aromatically bound primary or secondary amino group, (d) a compound containing at least two alcoholic hydroxyl groups and optionally at least one ether or ester group, (e) hydrazine or a derivative of hydrazine containing at least two reactive NH groups and (f) mixtures of (a)-(e), and (C) water wherein the equivalent ratio of isocyanate groups in component A to isocyanate reactive groups in components B and C is about 2:1 to 100:1; the equivalent ratio of isocyanate reactive groups in components B and C is about 1:0.1.to 1:10; the equivalent ratio of isocyanate reactive groups in components B1 and C to component B2 is about 1:0 to 1:10; and the equivalent ratio of isocyanate reactive groups in component B1 to component B2 is about 1:0 to 1:5.

Claim 11

A process for the production of a polyisocyanate containing urea and/or biuret groups and having an isocyanate content of about 0.7 to 45% by weight which is prepared by reacting (A) at least one organic polyisocyanate having an NCO content of about 10 to 50% by weight with (B) at least one organic compound containing isocyanate reactive groups comprising (i) a polyether or polyester having a molecular weight of 500 to about 20,000 and containing at least two isocyanate reactive groups comprising a member selected from the group consisting of alcoholic hydroxyl groups attached to primary carbon atoms, alcoholic hydroxyl groups attached to secondary carbon atoms, aromatically bound primary amino groups, aromatically bound secondary amino groups, cycloaliphatically bound primary amino groups, cycloaliphatically bound secondary amino groups, aliphatically bound primary amino groups, aliphatically bound secondary amino groups and mixtures thereof and, optionally, (ii) a low molecular weight organic compound comprising (a) an aromatic diamine or triamine having a molecular weight of 108 to 499 and containing primary and/or secondary amino groups, (b) an aliphatic or cycloaliphatic diamine or triamine having a molecular weight of 60 to 499 and containing primary and/or secondary amino groups, (c) an organic compound having a molecular weight of 61 to 499 and containing at least one alcoholic hydroxyl group attached to a primary or secondary carbon atom and at least one aliphatically, cycloaliphatically or aromatically bound primary or secondary amino group, (d) a compound containing at least two alcoholic hydroxyl groups and optionally at least one ether or ester group, (e) hydrazine or a derivative of hydrazine containing at least two reactive NH groups and (f) mixtures of (a)-(e), and (C) water wherein the equivalent ratio of isocyanate groups in component A to isocyanate reactive groups in components B and C is about 2:1 to 100:1; the equivalent ratio of isocyanate reactive groups in components B and C is about 1:0.1.to 1:10; the equivalent ratio of isocyanate reactive groups in components B1 and C to component B2 is about 1:0 to 1:10; and the equivalent ratio of isocyanate reactive groups in component B1 to component B2 is about 1:0 to 1:5.

Claim 12

A process for the production of a polyisocyanate polyaddition product which comprises reacting the polyisocyanate of claim 1 with at least one compound containing isocyanate reactive hydrogens.

Claim 13

The process, of claim 10 wherein said polyisocyanate addition product is a molded plastic having a density of about 0.8 to 1.4 g/cm 2 and said process is a reaction injection molding process.