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Alkaline storage battery using hydrogen absorbing alloy

Assignee: Panasonic Holdings Corp
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Filing: 1989-05-24
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Granted: 1990-05-15
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Expires: 2009-05-24
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Abstract

Abstract Disclosed is an improvement of a hydrogen absorbing alloy to be used as a negative electrode of an alkaline storage battery. The hydrogen absorbing alloy capable of electrochemically absorbing/desorbing hydrogen has a CaCu 5 type crystal structure and is represented by the general formula of A 1-x B x C y D z , in which formula: D is selected from the group consisting of V, In, Tl, Ga and mixtures thereof; the atomic ratio z has a value within the range made up as follows, 0.02≦z≦0.3 for V, 0.02≦z≦0.1 for In, 0.02≦z≦0.1 for Tl, and 0.02≦z≦0.1 for Ga; and the atomic ratio (y+z) has a value within the range of from 4.7 to 5.3.

Inventors

  • 👤 Munehisa Ikoma
  • 👤 Hiroshi Kawano
  • 👤 Osamu Takahashi
  • 👤 Isao Matsumoto
  • 👤 Masakazu Ikeyama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 23:17
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/34; H01M10/345; H01M4/00; H01M4/02; H01M4/36; H01M4/38; H01M4/383; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 237 words
An alkaline storage battery using a hydrogen absorbing alloy, said battery comprising: a positive electrode including a metal oxide as a main constituent material; a negative electrode including, as a main constituent material, a hydrogen absorbing alloy capable of electrochemically absorbing/desorbing hydrogen serving as an active material; an alkaline electrolytic solution; a separator; and said hydrogen absorbing alloy of said negative electrode having a CaCu 5 type crystal structure and being represented by the general formula of A 1-x B x C y D z , in which formula: A is selected from the group consisting of La, mixtures of rare-earth elements, and misch metal; B is selected from the group consisting of Ti, Zr, Ca, Y, Hf and mixtures thereof; x is an atomic ratio within the range 0≦x≦0.2; C is selected from the group consisting of Ni, Co, Mn, Al, Fe, Cu, Cr and mixtures thereof; y has an atomic ratio within the range made up as follows, y>3.5 for Ni, y ≦1.0 for Co, y≦0.6 for Mn, y≦0.5 for Al, y≦0.3 for Fe, y≦1.0 for Cu, and y≦0.3 for Cr; D is selected from the group consisting of V, In, Tl, Ga and mixtures thereof; z is an atomic ratio within the range made up as follows, 0.02≦z≦0.3 for V, 0.02≦z≦0.1 for In, 0.02≦z≦0.1 for Tl, and 0.02≦z≦0.1 for Ga; and (y+z) is an atomic ratio within the range of from 4.7 to 6.3.
Claim 2
Dependent Claim 237 words
An alkaline storage battery using a hydrogen absorbing alloy, said battery comprising: a positive electrode including a metal oxide as a main constituent material; a negative electrode including, as a main constituent material, a hydrogen absorbing alloy capable of electrochemically absorbing/desorbing hydrogen serving as an active material; an alkaline electrolytic solution; a separator; and said hydrogen absorbing alloy of said negative electrode having a CaCu 5 type crystal structure and being represented by the general formula of A 1-x B x C y D z , in which formula: A is selected from the group consisting of La, mixtures of rare-earth elements, and misch metal; B is selected from the group consisting of Ti, Zr, Ca, Y, Hf and mixtures thereof; x is an atomic ratio within the range 0≦x≦0.2; C is selected from the group consisting of Ni, Co, Mn, Al, Fe, Cu, Cr and mixtures thereof; y has an atomic ratio within the range made up as follows, y>3.5 for Ni, y ≦1.0 for Co, y≦0.6 for Mn, y≦0.5 for Al, y≦0.3 for Fe, y≦1.0 for Cu, and y≦0.3 for Cr; D is selected from the group consisting of V, In, Tl, Ga and mixtures thereof; z is an atomic ratio within the range made up as follows, 0.02≦z≦0.3 for V, 0.02≦z≦0.1 for In, 0.02≦z≦0.1 for Tl, and 0.02≦z≦0.1 for Ga; and (y+z) is an atomic ratio within the range of from 4.7 to 6.3.
Claim 3
Dependent Claim 23 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 1, in which said hydrogen absorbing alloy has a rough surface.
Claim 4
Dependent Claim 53 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 1, in which said hydrogen absorbing alloy has an Sf value {=In(P H/M =0.75/P H/M =0.25)} of not larger than 2.5, said Sf value representing flatness of plateau pressure in the case where hydrogen is desorbed from said hydrogen absorbing alloy.
Claim 5
Dependent Claim 32 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 1, in which said metal oxide included in said positive electrode as its main constituent material is a nickel oxide.
Claim 6
Dependent Claim 32 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 1, in which said metal oxide included in said positive electrode as its main constituent material is a manganese oxide.
Claim 7
Dependent Claim 26 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 1, in which at least a part of said negative electrode has hydrophobic property.
Claim 8
Dependent Claim 132 words
An alkaline storage battery using a hydrogen absorbing alloy, said battery comprising: a positive electrode including a metal oxide as a main constituent material; a negative electrode including, as a main constituent material, a hydrogen absorbing alloy capable of electrochemically absorbing/desorbing hydrogen serving as an active material; an alkaline electrolytic solution; a separator; and said hydrogen absorbing alloy of said negative electrode having a CaCu 5 type crystal structure and being represented by the general formula of MmNiaCobMncAldVe, in which formula; Mm represents a misch metal; a is an atomic ratio within the range a>3.5; b is an atomic ratio within the range 0.25<b<1.0; c is an atomic ratio within the range 0.2<c<0.6; d is an atomic ratio within the range 0.1<d<0.3; and e is an atomic ratio within the range 0.02<e<0.3.
Claim 9
Dependent Claim 132 words
An alkaline storage battery using a hydrogen absorbing alloy, said battery comprising: a positive electrode including a metal oxide as a main constituent material; a negative electrode including, as a main constituent material, a hydrogen absorbing alloy capable of electrochemically absorbing/desorbing hydrogen serving as an active material; an alkaline electrolytic solution; a separator; and said hydrogen absorbing alloy of said negative electrode having a CaCu 5 type crystal structure and being represented by the general formula of MmNiaCobMncAldVe, in which formula; Mm represents a misch metal; a is an atomic ratio within the range a>3.5; b is an atomic ratio within the range 0.25<b<1.0; c is an atomic ratio within the range 0.2<c<0.6; d is an atomic ratio within the range 0.1<d<0.3; and e is an atomic ratio within the range 0.02<e<0.3.
Claim 10
Dependent Claim 23 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 7, in which said hydrogen absorbing alloy has a rough surface.
Claim 11
Dependent Claim 53 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 7, in which said hydrogen absorbing alloy has an Sf value {=In(P H/M =0.75/P H/M =0.25)} of not larger than 2.5, said Sf value representing flatness of plateau pressure in the case where hydrogen is desorbed from said hydrogen absorbing alloy.
Claim 12
Dependent Claim 32 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 7, in which said metal oxide included in said positive electrode as its main constituent material is a nickel oxide.
Claim 13
Dependent Claim 32 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 7, in which said metal oxide included in said positive electrode as its main constituent material is a manganese oxide.
Claim 14
Dependent Claim 26 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 7, in which at least a part of said negative electrode has hydrophobic property.
Claim 15
Dependent Claim 132 words
An alkaline storage battery using a hydrogen absorbing alloy, said battery comprising; a positive electrode including a metal oxide as a main constituent material; a negative electrode including, as a main constituent material, a hydrogen absorbing alloy capable of electrochemically absorbing/desorbing hydrogen serving as an active material; an alkaline electrolytic solution; a separator; and said hydrogen absorbing alloy of said negative electrode having a CaCu 5 type crystal structure and being represented by the general formula of MmNiaCobMncAldIne, in which formula; Mm represents a misch metal; a is an atomic ratio within the range a>3.5; b is an atomic ratio within the range 0.25<b<1.0; c is an atomic ratio within the range 0.2<c<0.6; d is an atomic ratio within the range 0.1<d<0.3; and e is an atomic ratio within the range 0.02<e<0.1.
Claim 16
Dependent Claim 132 words
An alkaline storage battery using a hydrogen absorbing alloy, said battery comprising; a positive electrode including a metal oxide as a main constituent material; a negative electrode including, as a main constituent material, a hydrogen absorbing alloy capable of electrochemically absorbing/desorbing hydrogen serving as an active material; an alkaline electrolytic solution; a separator; and said hydrogen absorbing alloy of said negative electrode having a CaCu 5 type crystal structure and being represented by the general formula of MmNiaCobMncAldIne, in which formula; Mm represents a misch metal; a is an atomic ratio within the range a>3.5; b is an atomic ratio within the range 0.25<b<1.0; c is an atomic ratio within the range 0.2<c<0.6; d is an atomic ratio within the range 0.1<d<0.3; and e is an atomic ratio within the range 0.02<e<0.1.
Claim 17
Dependent Claim 23 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 13, in which said hydrogen absorbing alloy has a rough surface.
Claim 18
Dependent Claim 54 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 13, in which said hydrogen absorbing alloy has an Sf value {=In(P H/M = 0.75/P H/M =0.25)} of not larger than 2.5, said Sf value representing flatness of plateau pressure in the case where hydrogen in desorbed from said hydrogen absorbing alloy.
Claim 19
Dependent Claim 32 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 13, in which said metal oxide included in said positive electrode as its main constituent material is a nickel oxide.
Claim 20
Dependent Claim 32 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 13, in which said metal oxide included in said positive electrode as its main constituent material is a manganese oxide.
Claim 21
Dependent Claim 26 words
An alkaline storage battery using a hydrogen absorbing alloy according to claim 13, in which at least a part of said negative electrode has hydrophobic property.

References Cited (Backward Citations)

US3850694A Cited
US4214043A Cited
US4312928A Cited
US4487817A Cited
US4636445A Cited
US4702978A Cited
US4752546A Cited
US4837119A Cited
US4826744A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-05-14 1993-11-13 1994-05-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-05-14 1997-11-13 1998-05-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-05-14 2001-11-13 2002-05-15 $7700.00 Window Closed / Lapsed

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