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US4752546A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrochemical cell

Assignee: US Philips Corp
•
Filing: 1987-08-20
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Granted: 1988-06-21
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Expires: 2007-08-20
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Abstract

Abstract The invention relates to an electrochemical cell having a negative electrode of a stable hydride-forming material, in which a high power density at a low temperature and a rapid activation (as a function of the number of charge and discharge cycles) are obtained by adding to the electrochemically active material one or more metals selected from the group formed by Ni, Pd, Pt, Ir and Rh. The activating metal may be added to the bulk of the hydride-forming material or may be provided by substituting it for less noble metals at the surface of the powdered material.

Inventors

  • 👤 Jacobus J. F. G. Heuts
  • 👤 Johannes J. G. S. A. Willems

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 09:53
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/34; H01M10/345; H01M4/00; H01M4/02; H01M4/36; H01M4/38; H01M4/383; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 243 words
An electrochemical cell comprising a negative electrode, the electrochemically active material of which consists of an intermetallic compound forming hydride with hydrogen, which compound has the CaCu 5 -structure and the compositional formula AB m C n , where m+n is between 4.8 and 5.4, where n is between 0.05 and 0.6, in which A consists of Mischmetall or of one or more elements selected from the group consisting of Y, Ti, Hf, Zr, Ca, Th, La and the remaining rare earth metals, in which the total atomic quantities of the elements Y, Ti, Hf and Zr may not be more than 40% of A, in which B consists of two or more elements selected from the group formed by Ni, Co, Cu, Fe and Mn, where the maximum atomic quantity per gram atom of A is for Ni: 3.5, for Co: 3.5, for Cu: 3.5, for Fe: 2.0 and for Mn: 1.0, and in which C consists of one or more elements selected from the group formed by Al, Cr and Si in the indicated atomic quantities: Al: 0.05-0.6, Cr: 0.05-0.5 and Si: 0.05-0.5, characterized in that the electrochemically active material additionally comprises a quantity Ni which quantity of Ni, is present as a separate, finely-dispersed phase, the maximum atomic quantity of Ni per gram atom of A is 3.5, and the total of m+n and the said atomic quantity of Ni per gram atom of A lies between 5.0 and 5.5.
Claim 2
Dependent Claim 243 words
An electrochemical cell comprising a negative electrode, the electrochemically active material of which consists of an intermetallic compound forming hydride with hydrogen, which compound has the CaCu 5 -structure and the compositional formula AB m C n , where m+n is between 4.8 and 5.4, where n is between 0.05 and 0.6, in which A consists of Mischmetall or of one or more elements selected from the group consisting of Y, Ti, Hf, Zr, Ca, Th, La and the remaining rare earth metals, in which the total atomic quantities of the elements Y, Ti, Hf and Zr may not be more than 40% of A, in which B consists of two or more elements selected from the group formed by Ni, Co, Cu, Fe and Mn, where the maximum atomic quantity per gram atom of A is for Ni: 3.5, for Co: 3.5, for Cu: 3.5, for Fe: 2.0 and for Mn: 1.0, and in which C consists of one or more elements selected from the group formed by Al, Cr and Si in the indicated atomic quantities: Al: 0.05-0.6, Cr: 0.05-0.5 and Si: 0.05-0.5, characterized in that the electrochemically active material additionally comprises a quantity Ni which quantity of Ni, is present as a separate, finely-dispersed phase, the maximum atomic quantity of Ni per gram atom of A is 3.5, and the total of m+n and the said atomic quantity of Ni per gram atom of A lies between 5.0 and 5.5.

References Cited (Backward Citations)

US3669745A Cited
US4107405A Cited
US4609599A Cited
US4554152A Cited
US4214043A Cited
US4312928A Cited
US4487817A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-06-21 1991-12-21 1992-06-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-06-21 1995-12-21 1996-06-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-06-21 1999-12-21 2000-06-21 $7700.00 Window Closed / Lapsed

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