Patent US4917809A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4917809A Expired / Lapsed US ⏱️ 0.0 years remaining

High-temperature lubricants

Assignee: BASF Corp
•
Filing: 1987-11-02
•
Granted: 1990-04-17
•
Expires: 2007-11-02
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A composition comprising (a) one or more lubricants or hydraulic based on mineral oil or synthetic oils and (b) 0.05 to 5% by weight, relative to the total weight of the lubricant composition or hydraulic oil composition, of a mixture of (1) at least one compound of the formula I or II ##STR1## in which Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 as well as a are as defined in patent claim 1 and (2) at least one compound of the formulae III or IV ##STR2## in which X, X 1 , X 2 , R 11 , R 12 , m, n, n*, k, b and M are as defined in patent claim 1.

Inventors

  • 👤 Horst Zinke
  • 👤 Rolf Schumacher

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 01:16
CPC Classifications
C; C10; C10M; C10M141/00; C10M141/10; C10M135/00; C10M135/32; C10M135/36; C10M137/00; C10M137/02; C10M137/04; C10M137/06; C10M137/08; C10M137/10; C10M2219/00; C10M2219/09; C10M2219/10; C10M2219/102; C10M2219/104; C10M2219/106; C10M2219/108; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/041; C10M2223/042; C10M2223/043; C10M2223/045; C10M2223/047; C10M2223/049; C10M2223/10; C10N; C10N2010/00; C10N2010/04; C10N2040/00; C10N2040/08

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 525 words
A composition consisting essentially of (a) one or more lubricants or hydraulic oils based on mineral oil or synthetic oils and (b) 0.05 to 5% by weight, relative to the total weight of the lubricant composition or hydraulic oil composition, of a mixture of (1) at least one compound of the formula I or II ##STR16## in which Y is --O--, --S--, --NH-- or --NR 9 --, with R 9 being C 1 -C 12 -alkyl, Z is --CR 8 -- or --N-- and R 1 is hydrogen, C 1 -C 12 -alkyl, C 1 -C 4 -alkoxy, C 2 -C 24 -alkoxycarbonyl or nitro, R 2 is hydrogen or unsubstituted or OH-substituted C 1 -C 24 -alkyl, R 3 is hydrogen, C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl, R 4 is C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl, or R 3 and R 4 together are a --C(R 10 )═N--CH 2 -CH 2 - radical, with R 10 being hydrogen, C 1 -C 17 -alkyl or C 2 -C 17 -alkenyl, and R 5 is hydrogen, --SH or C 1 -C 22 -alkyl, R 6 is hydrogen, R 7 is hydrogen or R 6 and R 7 together are a direct bond, R 8 is hydrogen or C 1 -C 22 -alkyl or phenyl, or R 7 and R 8 together are carbonyl and a has the value 0 or 1 to 2, and (2) at least one compound of the formulae III or IV ##STR17## in which X, X 1 and X 2 independently of one another are oxygen or sulfur, R 11 and R 12 are identical or different and are each C 1 -C 12 -alkyl which may be interrupted by --O--, --S-- or --C(O)O --, unsubstituted or C 1 -C 12 -alkyl-substituted phenyl or naphthyl, unsubstituted or C 1 -C 4 -alkyl-substituted C 5 -C 12 -cycloalkyl or C 7 -C 13 -aralkyl, and n is the number 1, 2 or 3, n* is the number 1 or 2, m is the number 1 or 2, k is the number 1 or 2 and b is the number 0 or 1, and, in the case of n or n* being 2 or also n being 3, the radicals R 11 are identical or different or two radicals R 11 can, together with the two heteroatoms X 1 and the P atom to which they are linked, form a 5-membered or 6-membered ring, and in which M is a k-valent metal cation, a proton or a compound HN + R 13 R 14 R 15 , R 13 being hydrogen or unsubstituted or OH-substituted C 1 -C 30 -alkyl, R 14 being hydrogen or C 1 -C 30 -alkyl and R 15 being C 1 -C 30 -alkyl or C 18 -alkenyl, or R 14 and R 15 together forming a -C(R 16 )═N--CH 2 -CH 2 -- radical and R 16 being hydrogen, C 1 -C 17 -alkyl or C 2 -C 17 -alkenyl, with the proviso that, if m is 2 and k is 1, two different radicals M are possible.
Claim 2
Dependent Claim 525 words
A composition consisting essentially of (a) one or more lubricants or hydraulic oils based on mineral oil or synthetic oils and (b) 0.05 to 5% by weight, relative to the total weight of the lubricant composition or hydraulic oil composition, of a mixture of (1) at least one compound of the formula I or II ##STR16## in which Y is --O--, --S--, --NH-- or --NR 9 --, with R 9 being C 1 -C 12 -alkyl, Z is --CR 8 -- or --N-- and R 1 is hydrogen, C 1 -C 12 -alkyl, C 1 -C 4 -alkoxy, C 2 -C 24 -alkoxycarbonyl or nitro, R 2 is hydrogen or unsubstituted or OH-substituted C 1 -C 24 -alkyl, R 3 is hydrogen, C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl, R 4 is C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl, or R 3 and R 4 together are a --C(R 10 )═N--CH 2 -CH 2 - radical, with R 10 being hydrogen, C 1 -C 17 -alkyl or C 2 -C 17 -alkenyl, and R 5 is hydrogen, --SH or C 1 -C 22 -alkyl, R 6 is hydrogen, R 7 is hydrogen or R 6 and R 7 together are a direct bond, R 8 is hydrogen or C 1 -C 22 -alkyl or phenyl, or R 7 and R 8 together are carbonyl and a has the value 0 or 1 to 2, and (2) at least one compound of the formulae III or IV ##STR17## in which X, X 1 and X 2 independently of one another are oxygen or sulfur, R 11 and R 12 are identical or different and are each C 1 -C 12 -alkyl which may be interrupted by --O--, --S-- or --C(O)O --, unsubstituted or C 1 -C 12 -alkyl-substituted phenyl or naphthyl, unsubstituted or C 1 -C 4 -alkyl-substituted C 5 -C 12 -cycloalkyl or C 7 -C 13 -aralkyl, and n is the number 1, 2 or 3, n* is the number 1 or 2, m is the number 1 or 2, k is the number 1 or 2 and b is the number 0 or 1, and, in the case of n or n* being 2 or also n being 3, the radicals R 11 are identical or different or two radicals R 11 can, together with the two heteroatoms X 1 and the P atom to which they are linked, form a 5-membered or 6-membered ring, and in which M is a k-valent metal cation, a proton or a compound HN + R 13 R 14 R 15 , R 13 being hydrogen or unsubstituted or OH-substituted C 1 -C 30 -alkyl, R 14 being hydrogen or C 1 -C 30 -alkyl and R 15 being C 1 -C 30 -alkyl or C 18 -alkenyl, or R 14 and R 15 together forming a -C(R 16 )═N--CH 2 -CH 2 -- radical and R 16 being hydrogen, C 1 -C 17 -alkyl or C 2 -C 17 -alkenyl, with the proviso that, if m is 2 and k is 1, two different radicals M are possible.
Claim 3
Dependent Claim 19 words
A composition according to claim 1, wherein, in the formula I, R 1 is hydrogen and Y is --S--.
Claim 4
Dependent Claim 21 words
A composition according to claim 1, wherein, in the formula II, R 6 together with R 7 is a direct bond.
Claim 5
Dependent Claim 26 words
A composition according to claim 1, wherein, in the formulae I or II, R 2 is hydrogen or unsubstituted or OH-substituted C 1 -C 4 -alkyl.
Claim 6
Dependent Claim 40 words
A composition according to claim 1, wherein, in the formulae I or II, R 2 is hydrogen and R 3 and R 4 independently of one another are each C 8 -C 24 -alkyl or C 8 -C 24 -alkenyl.
Claim 7
Dependent Claim 35 words
A composition according to claim 1, wherein, in the formulae I or II, R 2 and R 3 are hydrogen and R 4 is C 8 -C 24 -alkyl or C 8 -C 24 -alkenyl.
Claim 8
Dependent Claim 34 words
A composition according to claim 1, wherein, in the formulae I or II, R 2 is 2-hydroxyethyl and R 3 together with R 4 is a -C(R 10 )═N--CH 2 -CH 2 -- radical.
Claim 9
Dependent Claim 45 words
A composition according to claim 1, wherein, in the formulae III or IV, R 11 is C 1 -C 12 -alkyl which may be interrupted by --O--, --S-- or --C(O)O, or unsubstituted or C 1 -C 12 -alkyl-substituted phenyl or naphthyl, or cyclohexyl or benzyl.
Claim 10
Dependent Claim 45 words
A composition according to claim 1, wherein, in the formulae III or IV, R 12 is C 1 -C 12 -alkyl which may be interrupted by --O--, --S-- or --C(O)O--, or unsubstituted or C 1 -C 12 -alkyl-substituted phenyl or naphthyl, or cyclohexyl or benzyl.
Claim 11
Dependent Claim 25 words
A composition according to claim 1, wherein, in the formula III, M is a proton, Zn 2+ or HN.sup.⊕(R 13 )(R 14 )(R 15 )
Claim 12
Dependent Claim 40 words
A composition according to claim 1, wherein, in the formula III, X and X 2 are sulfur, X 1 is oxygen, R 11 is C 3 -C 8 -alkyl, n* is 2, m is 1 and M is Zn 2+
Claim 13
Dependent Claim 82 words
A composition according to claim 1, wherein, in the formula III, X, X 1 and X 2 are oxygen, R 11 is C 2 -C 6 -alkyl, n* is 1 or 2, m is 2 or 1 and M, in the case of m=1, is HN.sup.⊕ (R 13 )(R 14 )(R 15 ) and, in the case of m=2, is HN.sup.⊕ (R 14 ) (R 15 ) or a proton, with the proviso that at most one radical M is a proton.
Claim 14
Dependent Claim 29 words
A composition according to claim 1, wherein the mixture (b) consists of (1) one compound of the formulae I or II and (2) one compound of the formula III.
Claim 15
Dependent Claim 117 words
A composition according to claim 13, wherein, in the compounds of the formulae I or II, a has the value 0, Y is sulfur or oxygen and, in the formula I, R 1 is hydrogen and, in the compounds of the formula III, X, X 1 and X 2 are oxygen, R 11 is C 2 -C 6 -alkyl, n* is the number 1 or 2, m is the number 2 or 1 and M, in the case of m=1, is HN.sup.⊕(R 13 )(R 14 )(R 15 ) and, in the case of m=2, is HN.sup.⊕(R 13 )(R 14 )(R 15 ), or a proton with the proviso that at most one radical M is a proton.
Claim 16
Dependent Claim 79 words
A composition according to claim 13, wherein, in the compounds of the formulae I or II, a has the value 1 to 1.25, Y is sulfur or oxygen and, in the formula I, R 1 is hydrogen, and, in the compounds of the formula III, X and X 2 are sulfur, X 1 is oxygen, R 11 is C 3 -C 8 -alkyl, n* is the number 2, m is the number 1 and M is Zn 2+ .
Claim 17
Dependent Claim 27 words
A composition according to claim 1, wherein the mixture (b) consists of (1) one compound of the formula I and (2) one compound of the formula III.
Claim 18
Dependent Claim 93 words
A composition according to claim 16, wherein, in the compounds of the formula I, a has the value 1 to 1.25, Y is sulfur, R 1 is hydrogen, R 2 is hydrogen, R 3 is hydrogen or C 8 -C 24 -alkyl and R 4 is C 8 -C 24 -alkyl and, in the compounds of the formula III, X and X 2 are sulfur, X 1 is oxygen, R 11 is C 3 -C 8 -alkyl, n* is the number 2, m is the number 1 and M is Zn 2+ .
Claim 19
Dependent Claim 50 words
Process of inhibiting the wear of lubricants or hydraulic oils which consists essentially of incorporating 1) at least one compound of the formulae I or II and 2) at least one compound of the formulae III or IV, according to claim 1, as wear-reducing additives to lubricants or hydraulic oils.

References Cited (Backward Citations)

US3933658A Cited
US3779919A Cited
US3897351A Cited
US4096077A Cited
US4104179A Cited
US3966623A Cited
US4532062A Cited
EP0150957A2 Cited
US4741847A Cited
US4737302A Cited
US4589991A Cited
EP0207737A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-04-16 1993-10-16 1994-04-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-04-16 1997-10-16 1998-04-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-04-16 2001-10-16 2002-04-17 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag