US4917809A
Expired / Lapsed
US
⏱️ 0.0 years remaining
High-temperature lubricants
Assignee: BASF Corp
•
Filing: 1987-11-02
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Granted: 1990-04-17
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Expires: 2007-11-02
Abstract
Abstract A composition comprising (a) one or more lubricants or hydraulic based on mineral oil or synthetic oils and (b) 0.05 to 5% by weight, relative to the total weight of the lubricant composition or hydraulic oil composition, of a mixture of (1) at least one compound of the formula I or II ##STR1## in which Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 as well as a are as defined in patent claim 1 and (2) at least one compound of the formulae III or IV ##STR2## in which X, X 1 , X 2 , R 11 , R 12 , m, n, n*, k, b and M are as defined in patent claim 1.
Inventors
- 👤 Horst Zinke
- 👤 Rolf Schumacher
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 01:08
CPC Classifications
C; C10; C10M; C10M141/00; C10M141/10; C10M135/00; C10M135/32; C10M135/36; C10M137/00; C10M137/02; C10M137/04; C10M137/06; C10M137/08; C10M137/10; C10M2219/00; C10M2219/09; C10M2219/10; C10M2219/102; C10M2219/104; C10M2219/106; C10M2219/108; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/041; C10M2223/042; C10M2223/043; C10M2223/045; C10M2223/047; C10M2223/049; C10M2223/10; C10N; C10N2010/00; C10N2010/04; C10N2040/00; C10N2040/08
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
525 words
A composition consisting essentially of (a) one or more lubricants or hydraulic oils based on mineral oil or synthetic oils and (b) 0.05 to 5% by weight, relative to the total weight of the lubricant composition or hydraulic oil composition, of a mixture of (1) at least one compound of the formula I or II ##STR16## in which Y is --O--, --S--, --NH-- or --NR 9 --, with R 9 being C 1 -C 12 -alkyl, Z is --CR 8 -- or --N-- and R 1 is hydrogen, C 1 -C 12 -alkyl, C 1 -C 4 -alkoxy, C 2 -C 24 -alkoxycarbonyl or nitro, R 2 is hydrogen or unsubstituted or OH-substituted C 1 -C 24 -alkyl, R 3 is hydrogen, C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl, R 4 is C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl, or R 3 and R 4 together are a --C(R 10 )═N--CH 2 -CH 2 - radical, with R 10 being hydrogen, C 1 -C 17 -alkyl or C 2 -C 17 -alkenyl, and R 5 is hydrogen, --SH or C 1 -C 22 -alkyl, R 6 is hydrogen, R 7 is hydrogen or R 6 and R 7 together are a direct bond, R 8 is hydrogen or C 1 -C 22 -alkyl or phenyl, or R 7 and R 8 together are carbonyl and a has the value 0 or 1 to 2, and (2) at least one compound of the formulae III or IV ##STR17## in which X, X 1 and X 2 independently of one another are oxygen or sulfur, R 11 and R 12 are identical or different and are each C 1 -C 12 -alkyl which may be interrupted by --O--, --S-- or --C(O)O --, unsubstituted or C 1 -C 12 -alkyl-substituted phenyl or naphthyl, unsubstituted or C 1 -C 4 -alkyl-substituted C 5 -C 12 -cycloalkyl or C 7 -C 13 -aralkyl, and n is the number 1, 2 or 3, n* is the number 1 or 2, m is the number 1 or 2, k is the number 1 or 2 and b is the number 0 or 1, and, in the case of n or n* being 2 or also n being 3, the radicals R 11 are identical or different or two radicals R 11 can, together with the two heteroatoms X 1 and the P atom to which they are linked, form a 5-membered or 6-membered ring, and in which M is a k-valent metal cation, a proton or a compound HN + R 13 R 14 R 15 , R 13 being hydrogen or unsubstituted or OH-substituted C 1 -C 30 -alkyl, R 14 being hydrogen or C 1 -C 30 -alkyl and R 15 being C 1 -C 30 -alkyl or C 18 -alkenyl, or R 14 and R 15 together forming a -C(R 16 )═N--CH 2 -CH 2 -- radical and R 16 being hydrogen, C 1 -C 17 -alkyl or C 2 -C 17 -alkenyl, with the proviso that, if m is 2 and k is 1, two different radicals M are possible.
Claim 2
Dependent Claim
525 words
A composition consisting essentially of (a) one or more lubricants or hydraulic oils based on mineral oil or synthetic oils and (b) 0.05 to 5% by weight, relative to the total weight of the lubricant composition or hydraulic oil composition, of a mixture of (1) at least one compound of the formula I or II ##STR16## in which Y is --O--, --S--, --NH-- or --NR 9 --, with R 9 being C 1 -C 12 -alkyl, Z is --CR 8 -- or --N-- and R 1 is hydrogen, C 1 -C 12 -alkyl, C 1 -C 4 -alkoxy, C 2 -C 24 -alkoxycarbonyl or nitro, R 2 is hydrogen or unsubstituted or OH-substituted C 1 -C 24 -alkyl, R 3 is hydrogen, C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl, R 4 is C 1 -C 24 -alkyl or C 2 -C 24 -alkenyl, or R 3 and R 4 together are a --C(R 10 )═N--CH 2 -CH 2 - radical, with R 10 being hydrogen, C 1 -C 17 -alkyl or C 2 -C 17 -alkenyl, and R 5 is hydrogen, --SH or C 1 -C 22 -alkyl, R 6 is hydrogen, R 7 is hydrogen or R 6 and R 7 together are a direct bond, R 8 is hydrogen or C 1 -C 22 -alkyl or phenyl, or R 7 and R 8 together are carbonyl and a has the value 0 or 1 to 2, and (2) at least one compound of the formulae III or IV ##STR17## in which X, X 1 and X 2 independently of one another are oxygen or sulfur, R 11 and R 12 are identical or different and are each C 1 -C 12 -alkyl which may be interrupted by --O--, --S-- or --C(O)O --, unsubstituted or C 1 -C 12 -alkyl-substituted phenyl or naphthyl, unsubstituted or C 1 -C 4 -alkyl-substituted C 5 -C 12 -cycloalkyl or C 7 -C 13 -aralkyl, and n is the number 1, 2 or 3, n* is the number 1 or 2, m is the number 1 or 2, k is the number 1 or 2 and b is the number 0 or 1, and, in the case of n or n* being 2 or also n being 3, the radicals R 11 are identical or different or two radicals R 11 can, together with the two heteroatoms X 1 and the P atom to which they are linked, form a 5-membered or 6-membered ring, and in which M is a k-valent metal cation, a proton or a compound HN + R 13 R 14 R 15 , R 13 being hydrogen or unsubstituted or OH-substituted C 1 -C 30 -alkyl, R 14 being hydrogen or C 1 -C 30 -alkyl and R 15 being C 1 -C 30 -alkyl or C 18 -alkenyl, or R 14 and R 15 together forming a -C(R 16 )═N--CH 2 -CH 2 -- radical and R 16 being hydrogen, C 1 -C 17 -alkyl or C 2 -C 17 -alkenyl, with the proviso that, if m is 2 and k is 1, two different radicals M are possible.
Claim 3
Dependent Claim
19 words
A composition according to claim 1, wherein, in the formula I, R 1 is hydrogen and Y is --S--.
Claim 4
Dependent Claim
21 words
A composition according to claim 1, wherein, in the formula II, R 6 together with R 7 is a direct bond.
Claim 5
Dependent Claim
26 words
A composition according to claim 1, wherein, in the formulae I or II, R 2 is hydrogen or unsubstituted or OH-substituted C 1 -C 4 -alkyl.
Claim 6
Dependent Claim
40 words
A composition according to claim 1, wherein, in the formulae I or II, R 2 is hydrogen and R 3 and R 4 independently of one another are each C 8 -C 24 -alkyl or C 8 -C 24 -alkenyl.
Claim 7
Dependent Claim
35 words
A composition according to claim 1, wherein, in the formulae I or II, R 2 and R 3 are hydrogen and R 4 is C 8 -C 24 -alkyl or C 8 -C 24 -alkenyl.
Claim 8
Dependent Claim
34 words
A composition according to claim 1, wherein, in the formulae I or II, R 2 is 2-hydroxyethyl and R 3 together with R 4 is a -C(R 10 )═N--CH 2 -CH 2 -- radical.
Claim 9
Dependent Claim
45 words
A composition according to claim 1, wherein, in the formulae III or IV, R 11 is C 1 -C 12 -alkyl which may be interrupted by --O--, --S-- or --C(O)O, or unsubstituted or C 1 -C 12 -alkyl-substituted phenyl or naphthyl, or cyclohexyl or benzyl.
Claim 10
Dependent Claim
45 words
A composition according to claim 1, wherein, in the formulae III or IV, R 12 is C 1 -C 12 -alkyl which may be interrupted by --O--, --S-- or --C(O)O--, or unsubstituted or C 1 -C 12 -alkyl-substituted phenyl or naphthyl, or cyclohexyl or benzyl.
Claim 11
Dependent Claim
25 words
A composition according to claim 1, wherein, in the formula III, M is a proton, Zn 2+ or HN.sup.⊕(R 13 )(R 14 )(R 15 )
Claim 12
Dependent Claim
40 words
A composition according to claim 1, wherein, in the formula III, X and X 2 are sulfur, X 1 is oxygen, R 11 is C 3 -C 8 -alkyl, n* is 2, m is 1 and M is Zn 2+
Claim 13
Dependent Claim
82 words
A composition according to claim 1, wherein, in the formula III, X, X 1 and X 2 are oxygen, R 11 is C 2 -C 6 -alkyl, n* is 1 or 2, m is 2 or 1 and M, in the case of m=1, is HN.sup.⊕ (R 13 )(R 14 )(R 15 ) and, in the case of m=2, is HN.sup.⊕ (R 14 ) (R 15 ) or a proton, with the proviso that at most one radical M is a proton.
Claim 14
Dependent Claim
29 words
A composition according to claim 1, wherein the mixture (b) consists of (1) one compound of the formulae I or II and (2) one compound of the formula III.
Claim 15
Dependent Claim
117 words
A composition according to claim 13, wherein, in the compounds of the formulae I or II, a has the value 0, Y is sulfur or oxygen and, in the formula I, R 1 is hydrogen and, in the compounds of the formula III, X, X 1 and X 2 are oxygen, R 11 is C 2 -C 6 -alkyl, n* is the number 1 or 2, m is the number 2 or 1 and M, in the case of m=1, is HN.sup.⊕(R 13 )(R 14 )(R 15 ) and, in the case of m=2, is HN.sup.⊕(R 13 )(R 14 )(R 15 ), or a proton with the proviso that at most one radical M is a proton.
Claim 16
Dependent Claim
79 words
A composition according to claim 13, wherein, in the compounds of the formulae I or II, a has the value 1 to 1.25, Y is sulfur or oxygen and, in the formula I, R 1 is hydrogen, and, in the compounds of the formula III, X and X 2 are sulfur, X 1 is oxygen, R 11 is C 3 -C 8 -alkyl, n* is the number 2, m is the number 1 and M is Zn 2+ .
Claim 17
Dependent Claim
27 words
A composition according to claim 1, wherein the mixture (b) consists of (1) one compound of the formula I and (2) one compound of the formula III.
Claim 18
Dependent Claim
93 words
A composition according to claim 16, wherein, in the compounds of the formula I, a has the value 1 to 1.25, Y is sulfur, R 1 is hydrogen, R 2 is hydrogen, R 3 is hydrogen or C 8 -C 24 -alkyl and R 4 is C 8 -C 24 -alkyl and, in the compounds of the formula III, X and X 2 are sulfur, X 1 is oxygen, R 11 is C 3 -C 8 -alkyl, n* is the number 2, m is the number 1 and M is Zn 2+ .
Claim 19
Dependent Claim
50 words
Process of inhibiting the wear of lubricants or hydraulic oils which consists essentially of incorporating 1) at least one compound of the formulae I or II and 2) at least one compound of the formulae III or IV, according to claim 1, as wear-reducing additives to lubricants or hydraulic oils.
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