US4913934A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for making laser Q-switch
Assignee: United States Department of the Army
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Filing: 1988-06-30
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Granted: 1990-04-03
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Expires: 2008-06-30
Abstract
Abstract The present invention provides layered polymeric devices to control the spatial and spectral distribution of energy in optical beams, particularly high-intensity laser beams. These devices include improved versions of prior art thin-film (vacuum-deposited) interference filters, rugate structure anti-reflection coatings, Q-switches, pulse shapers, modulators, optical bistable devices and the like.
Inventors
- 👤 Edward J. Sharp
- 👤 II Richard R. Shurtz
- 👤 Wolfgang Elser
- 👤 Gary L. Wood
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 20:27
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/10; H01S3/11; H01S3/1123; H01S3/113; G; G02; G02B; G02B5/00; G02B5/20; G02B5/28; G02B5/289; H01S3/05; H01S3/08; H01S3/08059
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
222 words
The process of forming a narrow band light radiatio filter form from organic monomers with a first center frequency which can be detuned to a second center frequency by a strong electric field with an intensity level such as that found in an intense laser beam, comprising the steps of: A. forming dielectric materials suitable for the deposition of a structure of superposed thin dielectric layers with various preselected dielectric constants and transparent to said above radiation, wherein the required successive differences in the dielectric constants of adjacent ones of said layers define a preselected sequence to provide a rugate interference form of said filter; B. successively molecularly orienting and depositing said layers on a substrate transparent to said radiation with adjacent layers in contact while varying the material formulation between layer depositions such that said layers have first order susceptibilities to electric polarization of sufficient magnitude to provide said preselected dielectric constants but also have higher order susceptibilities of sufficient magnitude and polarity to provide said layers with slightly altered dielectric constants in the presence of said strong electric field, all of which alter said preselected sequence in a manner that shifts said first center frequency to a second center frequency; and C. treating the resultant structure to improve the bonding between said layers and said substrate while retaining their transparency.
Claim 2
Dependent Claim
222 words
The process of forming a narrow band light radiatio filter form from organic monomers with a first center frequency which can be detuned to a second center frequency by a strong electric field with an intensity level such as that found in an intense laser beam, comprising the steps of: A. forming dielectric materials suitable for the deposition of a structure of superposed thin dielectric layers with various preselected dielectric constants and transparent to said above radiation, wherein the required successive differences in the dielectric constants of adjacent ones of said layers define a preselected sequence to provide a rugate interference form of said filter; B. successively molecularly orienting and depositing said layers on a substrate transparent to said radiation with adjacent layers in contact while varying the material formulation between layer depositions such that said layers have first order susceptibilities to electric polarization of sufficient magnitude to provide said preselected dielectric constants but also have higher order susceptibilities of sufficient magnitude and polarity to provide said layers with slightly altered dielectric constants in the presence of said strong electric field, all of which alter said preselected sequence in a manner that shifts said first center frequency to a second center frequency; and C. treating the resultant structure to improve the bonding between said layers and said substrate while retaining their transparency.
Claim 3
Dependent Claim
29 words
The method according to claim 1 wherein said layers are formed from polymerizable monomers and Step C comprises the step of: C. polymerizing said layers into a single structure.
Claim 4
Dependent Claim
144 words
The method according to claim 2, wherein Steps A and B comprise the following substeps: A. forming a plurality of polymerizeable organic monomers, each having a different susceptibility to electric polarization, said monomers including at least one monomer having a prominent susceptibility at an order greater than one; B1. dissolving each said monomer in a separate volume of highly volatile solvent to produce a set of solutions; B2. pouring a portion from one of said solutions on a clean water surface to form a monolayer or film substantially one molecule thick; B3. evaporating said solvent; B4. transferring the resulting monolayer to a substrate using the dipping technique of Langmuir and Blodgett; B5. repeating steps B1-B4 until the monolayers form a layer of said preselected thickness; and B6. repeating steps B1-B5 with a different ones of said solutions until the rugate filter structure is completed.
Claim 5
Dependent Claim
104 words
The method according to claim 2, wherein Step B comprises the following substeps: B1. dissolving each said monomer in a separate volume of highly volatile solvent to produce a set of solutions; B2. pouring the solution on the surface a rotating substrate so as to spread the mixture by centrifugal force into a thin liquid sublayer; B3. evaporating the solvent to form a solid sublayer; B4. repeating steps B1-B3 until the sublayers form a layer of said preselected thickness; and B5. repeating steps B1-B5 with a different one of the above solutions until the until the above mentioned preselected sequence of layers is completed.
Claim 6
Dependent Claim
59 words
The method according to claim 2, wherein Step B comprises the following substeps: B1. melting one of said monomers; B2. pouring the melted monomer on a rotating subtrate so as to spread said monomer into a thin layer due to centrifugal force; and B3. repeating steps B1 and B2 until the above mentioned preselected sequence of layers is completed.
Claim 7
Dependent Claim
11 words
The method according to claim 2 wherein: said monomers are diacetylenes.
Claim 8
Dependent Claim
11 words
The method according to claim 3, wherein: said monomers are diacetylenes.
Claim 9
Dependent Claim
11 words
The method according to claim 4, wherein: said monomers are diacetylenes.
Claim 10
Dependent Claim
11 words
The method according to claim 5, wherein: said monomers are diacetylenes.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-04-02 | 1993-10-02 | 1994-04-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-04-02 | 1997-10-02 | 1998-04-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-04-02 | 2001-10-02 | 2002-04-03 | $7700.00 | Window Closed / Lapsed |