US4910252A
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Siloxane polymer antifouling paint composition containing polysiloxanes
Assignee: Kansai Paint Co Ltd
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Filing: 1988-08-15
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Granted: 1990-03-20
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Expires: 2008-08-15
Abstract
Abstract An antifouling paint composition comprising as a film-forming component a vinyl-type copolymer obtained by copolymerization of (A) 1 to 50% by weight of a specific polymerizable unsaturated polysiloxane compound, (B) 0 to 30% by weight of a specific polymerizable unsaturated alkoxysilane compound, and (C) 20 to 99% by weight of a polymerizable unsaturated vinyl monomer other than the compounds (A) and (B) above.
Inventors
- 👤 Yoiti Yonehara
- 👤 Kiyoshi Nanishi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 05:59
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/16; C09D5/1656; C09D5/1662; C09D5/1668; C09D143/00; C09D143/04; C08; C08L; C08L83/00; C08L83/04
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
322 words
An antifouling paint composition comprising as a film-forming component a vinyl-type copolymer obtained by copolymerization of (A) 1 to 50% by weight of a polymerizable unsaturated polysiloxane compound represented by the formula ##STR26## wherein X 1 represents a group of the formula ##STR27## where R 6 represents a hydrogen atom or a methyl group; R 1 , R 2 , R 3 and R 4 are identical or different and each represents an alkyl group having 1 to 4 carbon atoms, an aryl group or an aralkyl group; R 5 represents a hydroxyalkyl group having 1 to 3 hydroxyl groups and 1 to 6 carbon atoms; a is 0 when X 1 represents the group ##STR28## and an integer of 1 to 5 when X 1 represents the group ##STR29## and b is a number of 3 to 1,000, (B) 0 to 30% by weight of a polymerizable unsaturated alkoxysilane compound represented by the formula ##STR30## wherein X 2 represents a group of the formula ##STR31## where R 8 represents a hydrogen atom or a methyl group; R 7 represents an alkyl group having 1 to 4 carbon atoms; and d is 0 when X 2 represents the group ##STR32## and an integer of 1 to 5 when X 2 represents the group ##STR33## and (C) 20 to 99% by weight of a polymerizable unsaturated vinyl monomer other than the compounds (A) and (B) above, and further comprising 1 to 50 parts by weight, per 100 parts by weight of the vinyl-type copolymer, of a siloxane compound represented by the formula: ##STR34## wherein R 10 , R 11 , R 12 and R 13 are identical or different, and each represents an alkyl group having 1 to 4 carbon atoms, an aryl group or an aralkyl group; p is an integer of 1 to 5; and q is a number of 3 to 1,000 "and said composition being free of silanol-containing compounds".
Claim 2
Dependent Claim
322 words
An antifouling paint composition comprising as a film-forming component a vinyl-type copolymer obtained by copolymerization of (A) 1 to 50% by weight of a polymerizable unsaturated polysiloxane compound represented by the formula ##STR26## wherein X 1 represents a group of the formula ##STR27## where R 6 represents a hydrogen atom or a methyl group; R 1 , R 2 , R 3 and R 4 are identical or different and each represents an alkyl group having 1 to 4 carbon atoms, an aryl group or an aralkyl group; R 5 represents a hydroxyalkyl group having 1 to 3 hydroxyl groups and 1 to 6 carbon atoms; a is 0 when X 1 represents the group ##STR28## and an integer of 1 to 5 when X 1 represents the group ##STR29## and b is a number of 3 to 1,000, (B) 0 to 30% by weight of a polymerizable unsaturated alkoxysilane compound represented by the formula ##STR30## wherein X 2 represents a group of the formula ##STR31## where R 8 represents a hydrogen atom or a methyl group; R 7 represents an alkyl group having 1 to 4 carbon atoms; and d is 0 when X 2 represents the group ##STR32## and an integer of 1 to 5 when X 2 represents the group ##STR33## and (C) 20 to 99% by weight of a polymerizable unsaturated vinyl monomer other than the compounds (A) and (B) above, and further comprising 1 to 50 parts by weight, per 100 parts by weight of the vinyl-type copolymer, of a siloxane compound represented by the formula: ##STR34## wherein R 10 , R 11 , R 12 and R 13 are identical or different, and each represents an alkyl group having 1 to 4 carbon atoms, an aryl group or an aralkyl group; p is an integer of 1 to 5; and q is a number of 3 to 1,000 "and said composition being free of silanol-containing compounds".
Claim 3
Dependent Claim
45 words
The composition of claim 1 wherein the polymerizable unsaturated polysiloxane compound (A) is a compound of formula (I) in which R 1 , R 2 , R 3 and R 4 each represent a methyl group, and b is a number of 30 to 500.
Claim 4
Dependent Claim
26 words
The composition of claim 1 wherein the polymerizable unsaturated alkoxysilane compound (B) is selected from vinyltrimethoxysilane, vinyltriethoxysilane, vinyltripropoxysilane, vinyltributoxysilane, (meth)acryloxymethyltrimethoxysilane, (meth)acryloxyethyltrimethoxysilane, (meth)acryloxypropyltrimethoxysilane, (meth)acryloxypropyltriethoxysilane, (meth)acryloxyethyltriethoxysilane and (meth)acryloxypropyltributoxysilane.
Claim 5
Dependent Claim
14 words
The composition of claim 3 wherein the polymerizable unsaturated alkoxysilane compound (B) is (meth)acryloxypropyltrimethoxysilane.
Claim 6
Dependent Claim
24 words
The composition of claim 1 wherein the polymerizable unsaturated vinyl monomer (C) is a compound containing 1 to 2 radical-polymerizable alpha, betaethylenically unsaturated bonds.
Claim 7
Dependent Claim
50 words
The composition of claim 1 wherein the polymerizable unsaturated vinyl monomer (C) is selected from the group consisting of (C 1-12 alkyl) esters of (meth)acrylic acid, hydroxy(C 2-6 alkyl) esters of (meth)acrylic acid, glycidyl-containing vinyl monomers, carboxy-containing vinyl monomers, (C 2-6 alkenyl) esters of (meth)acrylic acid and vinyl aromatic compounds.
Claim 8
Dependent Claim
23 words
The composition of claim 6 wherein the polymerizable unsaturated vinyl monomer (C) is selected from ethyl (meth)acrylate, butyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate and styrene.
Claim 9
Dependent Claim
50 words
The composition of claim 1 wherein the vinyl-type copolymer is obtained by copolymerizing 5 to 30% by weight of the polymerizable unsaturated polysiloxane compound (A), 3 to 15% by weight of the polymerizable unsaturated alkoxysilane compound (B), and 65 to 92% by weight of the polymerizable unsaturated vinyl monomer (C).
Claim 10
Dependent Claim
24 words
The composition of claim 1 wherein the vinyl-type copolymer has a weight average molecular weight in the range of about 3,000 to about 200,000.
Claim 11
Dependent Claim
22 words
The composition of claim 1 wherein the vinyl-type copolymer has a glass transition temperature in the range of -30° to 100° C.
Claim 12
Dependent Claim
39 words
The composition of claim 12 wherein R 10 , R 11 , R 12 and R 13 each represent a methyl group, p is an integer of 2 to 4, and q is a number of 30 to 500.
Claim 13
Dependent Claim
19 words
The composition of claim 1 which contains the vinyl-type copolymer in a concentration of 30 to 50% by weight.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1993-03-19 | 1993-09-18 | 1994-03-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-03-19 | 1997-09-18 | 1998-03-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-03-19 | 2001-09-18 | 2002-03-20 | $7700.00 | Window Closed / Lapsed |