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US4904726A Expired / Lapsed US ⏱️ 0.0 years remaining

Modified polytetrafluoroethylene resins and blends thereof

Assignee: EIDP Inc
•
Filing: 1988-12-09
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Granted: 1990-02-27
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Expires: 2008-12-09
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Abstract

Abstract Dispersion-process-produced, non-melt-processible, particulate, core-shell, tetrafluoroethylene copolymer comprising recurring units of tetrafluoroethylene and modifying recurring units of at least one ethylenically unsaturated comonomer that is copolymerizable with the tetrafluoroethylene, the number of recurring units of comonomer in the shell being sufficient to enable the copolymer to compound uniformly with an elastomer or plastic without forming visible agglomerates, and blends thereof with elastomeric and plastic resins.

Inventors

  • 👤 Richard A. Morgan
  • 👤 Charles W. Stewart

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 23:09
CPC Classifications
C; C08; C08L; C08L27/00; C08L27/02; C08L27/12; C08L27/18; C08F; C08F214/00; C08F214/18; C08F214/26; C08F259/00; C08F259/08; C08L51/00; C08L51/06; Y; Y10; Y10S; Y10S525/00; Y10S525/902

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 110 words
Blend of (a) an elastomeric resin, and (b) 0.1 to 200 parts per 100 parts of component (a) of a dispersion-process-produced, non-melt-processible, particulate, core-shell, tetrafluoroethylene copolymer, the copolymer being present in said resin in the form of platelets distributed throughout the resin and comprising recurring units of tetrafluoroethylene and modifying recurring units of a comonomer selected from the class consisting of hexafluoropropylene, perfluoro(alkyl vinyl ethers), perfluoro(alkyl vinyl ethers) wherein an alkyl group is replaced with a hexafluoropropylene oxide oligomer, chlorotrifluoroethylene, and a mixture thereof, the number of recurring units of comonomer in the shell being sufficient to enable the copolymer to compound uniformly with said resin without forming visible agglomerates.
Claim 2
Dependent Claim 110 words
Blend of (a) an elastomeric resin, and (b) 0.1 to 200 parts per 100 parts of component (a) of a dispersion-process-produced, non-melt-processible, particulate, core-shell, tetrafluoroethylene copolymer, the copolymer being present in said resin in the form of platelets distributed throughout the resin and comprising recurring units of tetrafluoroethylene and modifying recurring units of a comonomer selected from the class consisting of hexafluoropropylene, perfluoro(alkyl vinyl ethers), perfluoro(alkyl vinyl ethers) wherein an alkyl group is replaced with a hexafluoropropylene oxide oligomer, chlorotrifluoroethylene, and a mixture thereof, the number of recurring units of comonomer in the shell being sufficient to enable the copolymer to compound uniformly with said resin without forming visible agglomerates.
Claim 3
Dependent Claim 29 words
The blend of claim 1 wherein component (a) is an elastomeric resin and component (b) is present in an amount of 1-200 parts per 100 parts of elastomeric resin.
Claim 4
Dependent Claim 28 words
The blend of claim 1 wherein the comonomer of the tetrafluoroethylene copolymer is selected from the class consisting of hexafluoropropylene, perfluoro(alkyl vinyl ethers), and a mixture of them.
Claim 5
Dependent Claim 18 words
The blend of claim 3 wherein the alkyl group of the perfluoro(alkyl vinyl ether) contains 1-4 carbon atoms.
Claim 6
Dependent Claim 22 words
The blend of claim 1 wherein the tetrafluoroethylene copolymer is comprised of at least 0.08 weight percent of recurring units of hexafluoropropylene.
Claim 7
Dependent Claim 25 words
The blend of claim 1 wherein the tetrafluoroethylene copolymer is comprised of greater than 0.02 weight percent of recurring units of a perfluoro(alkyl vinyl ether).
Claim 8
Dependent Claim 8 words
The blend of claim 1 containing a filler.
Claim 9
Dependent Claim 9 words
The blend of claim 1 containing a curing agent.
Claim 10
Dependent Claim 5 words
Cured blend of claim 8.
Claim 11
Dependent Claim 12 words
Blend of claim 2 wherein the elastomer is a vinylidene fluoride/hexafluoroproplylene copolymer.
Claim 12
Dependent Claim 12 words
Blend of claim 2 wherein the elastomer is a vinylidene fluoride/hexafluoropropylene/tetrafluoroethylene copolymer.
Claim 13
Dependent Claim 11 words
Blend of claim 2 wherein the elastomer is a fluorosilicone elastomer.
Claim 14
Dependent Claim 11 words
Blend of claim 2 wherein the elastomer is an ethylene/propylene/diene copolymer.
Claim 15
Dependent Claim 10 words
Blend of claim 2 wherein the elastomer is a polychloroprene.
Claim 16
Dependent Claim 11 words
Blend of claim 2 wherein the elastomer is a styrene/butadiene copolymer.
Claim 17
Dependent Claim 13 words
Blend of claim 2 wherein the elastomer is a tetrafluoroethylene/perfluoro(methyl vinyl ether) copolymer.
Claim 18
Dependent Claim 14 words
Blend of claim 2 wherein the elastomer is a tetrafluoroethylene/perfluoro(methyl vinyl ether)/vinylidene fluoride copolymer.

References Cited (Backward Citations)

US3005795A Cited
US3484503A Cited
US3940455A Cited
US4094949A Cited
US4520170A Cited
US4767821A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-02-26 1993-08-28 1994-02-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-02-26 1997-08-28 1998-02-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-02-26 2001-08-28 2002-02-27 $7700.00 Window Closed / Lapsed

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