US4904406A
Expired / Lapsed
US
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Quaternary ammonium compounds for use in bleaching systems
Assignee: Lever Brothers Co
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Filing: 1989-02-21
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Granted: 1990-02-27
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Expires: 2009-02-21
Abstract
Abstract A quaternary ammonium-substituted peroxycarboxylic acid bleach precursor, its quaternary ammonium peroxycarboxylic acid derivative, and bleaching-detergent compositions containing these materials are disclosed herein. The bleach precursor structurally comprises a quaternized ammonium group linked to a carboxyl moiety having a leaving group via an aromatic or heterocyclic bridging group which, upon perhydrolysis in the presence of hydrogen peroxide, generates a highly effective, quaternary ammonium-substituted aromatic or heterocyclic peroxycarboxylic acid bleach.
Inventors
- 👤 James R. Darwent
- 👤 Keith C. Francis
- 👤 John Oakes
- 👤 David W. Thornthwaite
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 22:43
CPC Classifications
C; C07; C07C; C07C229/00; C07C229/02; C07C229/34; C07C309/00; C07C309/01; C07C309/28; C07C309/41; C07C309/42; C07D; C07D213/00; C07D213/02; C07D213/04; C07D213/06; C07D213/16; C07D213/20; C11; C11D; C11D3/00; C11D3/39; C11D3/3902; C11D3/3905; C11D3/3907; C11D3/3917; C11D3/3927
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
194 words
A bleaching-detergent composition comprising: (i) from 2 to 40% by weight of a peroxide bleaching compound capable of yielding hydrogen peroxide in aqueous solution; (ii) from 0.1 to 20% by weight of a peroxycarboxylic acid precursor having the formula: ##STR16## wherein R 1 , R 2 and R 3 are each a radical selected from the group consisting of alkyl, alkenyl, hydroxyalkyl and polyoxyalkylene containing from 1 to 18 carbon atoms; or two or more of R 1 , R 2 and R 3 together with the N-atom form an optionally substituted, nitrogen-containing heterocyclic ring system; R 4 is a bridging group selected from ##STR17## wherein each n can individually be 0, 1 or 2; L is a leaving group, the conjugate acid of which has a pK a in the range of from 4 to 13, and Z - can be a chloride, bromide, hydroxide, nitrate, methosulphate, bisulphate, acetate, sulphate, citrate, borate or phosphate anion; (iii) from 0 to 50% by weight of a surface-active material selected from the group consisting of anionic, nonionic, amphoteric, zwitterionic and cationic surfactants and mixtures thereof; (iv) from 0 to 80% by weight of a detergency builder.
Claim 2
Dependent Claim
194 words
A bleaching-detergent composition comprising: (i) from 2 to 40% by weight of a peroxide bleaching compound capable of yielding hydrogen peroxide in aqueous solution; (ii) from 0.1 to 20% by weight of a peroxycarboxylic acid precursor having the formula: ##STR16## wherein R 1 , R 2 and R 3 are each a radical selected from the group consisting of alkyl, alkenyl, hydroxyalkyl and polyoxyalkylene containing from 1 to 18 carbon atoms; or two or more of R 1 , R 2 and R 3 together with the N-atom form an optionally substituted, nitrogen-containing heterocyclic ring system; R 4 is a bridging group selected from ##STR17## wherein each n can individually be 0, 1 or 2; L is a leaving group, the conjugate acid of which has a pK a in the range of from 4 to 13, and Z - can be a chloride, bromide, hydroxide, nitrate, methosulphate, bisulphate, acetate, sulphate, citrate, borate or phosphate anion; (iii) from 0 to 50% by weight of a surface-active material selected from the group consisting of anionic, nonionic, amphoteric, zwitterionic and cationic surfactants and mixtures thereof; (iv) from 0 to 80% by weight of a detergency builder.
Claim 3
Dependent Claim
86 words
A bleaching-detergent composition according to claim 1, wherein L has the formula: ##STR18## wherein X 1 and X 2 are each individually H or a substituent selected from --SO 3 - M + ; --COO - M + ; --SO 4 - M + ; --(N + R 1 R 2 R 3 )Z - ; --NO 2 ; and C 1 -C 8 alkyl groups, wherein M + is selected from the group consisting of hydrogen, alkali metal, ammonium, or alkyl or hydroxyalkyl-substituted ammonium cation.
Claim 4
Dependent Claim
15 words
A bleaching-detergent composition according to claim 2, wherein the precursor is of the formula: ##STR19##
Claim 5
Dependent Claim
23 words
A bleaching-detergent composition according to claim 3, wherein R 1 , R 2 and R 3 are C 1 -C 4 alkyl groups.
Claim 6
Dependent Claim
19 words
A bleaching-detergent composition according to claim 4, wherein R 1 , R 2 and R 3 are methyl groups.
Claim 7
Dependent Claim
26 words
A bleaching-detergent composition according to claim 1, wherein the pK a of the conjugate acid of L is in the range from about 8 to 10.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-02-26 | 1993-08-28 | 1994-02-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-02-26 | 1997-08-28 | 1998-02-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-02-26 | 2001-08-28 | 2002-02-27 | $7700.00 | Window Closed / Lapsed |