Patent US4900467A successfully refreshed from Google Patents.
US4900467A
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Viscoelastic cleaning compositions with long relaxation times
Assignee: Clorox Co
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Filing: 1988-05-20
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Granted: 1990-02-13
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Expires: 2008-05-20
Abstract
Abstract A thickened aqueous cleaning composition is viscoelastic, with a long relaxation time to provide a thick solution with consumer-acceptable pour properties. The composition has utility as a drain opening composition or as a hard surface cleaner having a cleaning-effective residence time on non-horizontal surfaces. The composition includes a cleaning active, and a binary thickener comprising a betaine or sulfobetaine having a C 14-18 alkyl, or C 10-18 alkylamino or alkylamido group, and an organic, anionic counterion. The composition preferably has a relaxation time of at least about 5 seconds and a relative elasticity between about 10-500 sec/Pa.
Inventors
- 👤 William L. Smith
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 19:47
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/88; C11D1/90; C11D1/92; C11D17/00; C11D17/0008; C11D17/003; C11D3/00; C11D3/395; C11D3/3956
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
103 words
A thickened cleaning composition having a viscoelastic rheology comprising, in aqueous solution (a) an active cleaning compound, present in a cleaning effective amount; and (b) a viscoelastic thickening system consisting essentially of a betaine or sulfobetaine having a C 14-18 alkyl group, or a C 10-18 alkylamino or alkylamido group; and an anionic organic counterion, selected from the group consisting of C 2-6 alkyl carboxylates, aryl carboxylates, C 2-10 alkyl sulphonates, aryl sulphonates, sulfated C 2-10 alkyl alcohols, sulfated aryl alcohols, and mixtures thereof; and wherein the betaine and counterion are present in an amount to thicken and result in a viscoelastic rheology.
Claim 2
Dependent Claim
103 words
A thickened cleaning composition having a viscoelastic rheology comprising, in aqueous solution (a) an active cleaning compound, present in a cleaning effective amount; and (b) a viscoelastic thickening system consisting essentially of a betaine or sulfobetaine having a C 14-18 alkyl group, or a C 10-18 alkylamino or alkylamido group; and an anionic organic counterion, selected from the group consisting of C 2-6 alkyl carboxylates, aryl carboxylates, C 2-10 alkyl sulphonates, aryl sulphonates, sulfated C 2-10 alkyl alcohols, sulfated aryl alcohols, and mixtures thereof; and wherein the betaine and counterion are present in an amount to thicken and result in a viscoelastic rheology.
Claim 3
Dependent Claim
30 words
The composition of claim 1 wherein the active cleaning compound is selected from the group consisting of acids, bases, oxidants, reductants, solvents, enzymes, detergents, and thioorganic compounds, and mixtures thereof.
Claim 4
Dependent Claim
19 words
The composition of claim 1 wherein the counterion is sodium xylene sulfonate, and the betaine is cetyl dimethyl betaine.
Claim 5
Dependent Claim
25 words
The composition of claim 1 wherein the composition has a relative elasticity between about 10-500 sec/Pa, and a relaxation time greater than about 5 seconds.
Claim 6
Dependent Claim
52 words
The composition of claim 4 wherein the active cleaning compound is present in an amount of from about 0.05% to 50% by weight; the betaine is present from about 0.1% to 10.0% by weight; and the counterion is present in a mole ratio to the betaine of between about 1:10 and 3:1.
Claim 7
Dependent Claim
118 words
A thickened viscoelastic drain opening composition comprising, in aqueous solution (a) a drain opening active, selected from the group consisting of acids, bases, oxidants, reductants, solvents, enzymes, detergents, thioorganic compounds, and mixtures thereof; and (b) a viscoelastic thickening system consisting essentially of a betaine or sulfobetaine having a C 14-18 alkyl group, or a C 10-18 alkylamino or alkylamido group; and an anionic organic counterion, selected from the group consisting of C 2-6 alkyl carboxylates, aryl carboxylates, C 2-10 alkyl sulphonates, aryl sulphonates, sulfated C 2-10 alkyl alcohols, sulfated aryl alcohols and mixtures thereof; and wherein the betaine and counterion are present in an amount to thicken and result in a composition relative elasticity between about 10-500 sec/Pa.
Claim 8
Dependent Claim
118 words
A thickened viscoelastic drain opening composition comprising, in aqueous solution (a) a drain opening active, selected from the group consisting of acids, bases, oxidants, reductants, solvents, enzymes, detergents, thioorganic compounds, and mixtures thereof; and (b) a viscoelastic thickening system consisting essentially of a betaine or sulfobetaine having a C 14-18 alkyl group, or a C 10-18 alkylamino or alkylamido group; and an anionic organic counterion, selected from the group consisting of C 2-6 alkyl carboxylates, aryl carboxylates, C 2-10 alkyl sulphonates, aryl sulphonates, sulfated C 2-10 alkyl alcohols, sulfated aryl alcohols and mixtures thereof; and wherein the betaine and counterion are present in an amount to thicken and result in a composition relative elasticity between about 10-500 sec/Pa.
Claim 9
Dependent Claim
13 words
The composition of claim 6 wherein the organic counterion is an aryl sulfonate.
Claim 10
Dependent Claim
38 words
The composition of claim 6 wherein the composition has a percentage diluted of less than about 25%, as determined by pouring a first quantity of composition into a second quantity of standing water and measuring undiluted product delivered.
Claim 11
Dependent Claim
107 words
A thickened viscoelastic drain opening composition comprising, in aqueous solution (a) an alkali metal hydroxide; (b) an alkali metal hypochlorite; and (c) a viscoelastic thickening system, consisting essentially of a C 14-18 alkyl betaine or sulfobetaine; and an anionic organic counterion, selected from the group consisting of C 2-6 alkyl carboxylates, aryl carboxylates, C 2-10 alkyl sulphonates, aryl sulphonates, sulfated C 2-10 alkyl alcohols, sulfated aryl alcohols and mixtures thereof; and wherein (c) is present in an amount sufficient to thicken and result in a relative elasticity between about 10-500 sec/Pa, a density greater than that of water, and a viscosity of at least about 20 cP.
Claim 12
Dependent Claim
107 words
A thickened viscoelastic drain opening composition comprising, in aqueous solution (a) an alkali metal hydroxide; (b) an alkali metal hypochlorite; and (c) a viscoelastic thickening system, consisting essentially of a C 14-18 alkyl betaine or sulfobetaine; and an anionic organic counterion, selected from the group consisting of C 2-6 alkyl carboxylates, aryl carboxylates, C 2-10 alkyl sulphonates, aryl sulphonates, sulfated C 2-10 alkyl alcohols, sulfated aryl alcohols and mixtures thereof; and wherein (c) is present in an amount sufficient to thicken and result in a relative elasticity between about 10-500 sec/Pa, a density greater than that of water, and a viscosity of at least about 20 cP.
Claim 13
Dependent Claim
33 words
The drain opening composition of claim 9 and further including 0 to about 5 weight percent of an alkali metal silicate, and 0 to about 5 weight percent of an alkali metal carbonate.
Claim 14
Dependent Claim
38 words
The composition of claim 9 wherein the composition has a percentage diluted of less than about 25%, as determined by pouring a first quantity of composition into a second quantity of standing water and measuring undiluted product delivered.
Claim 15
Dependent Claim
60 words
The composition of claim 9 wherein component (a) is present in an amount of from about 0.5 to 20 weight percent; component (b) is present in an amount of from about 1 to 15 weight percent; the betaine is present from about 0.1 to 10 weight percent; and the counterion is present from about 0.01 to about 10 weight percent.
Claim 16
Dependent Claim
104 words
A thickened viscoelastic hypochlorite composition comprising, in aqueous solution (a) a hypochlorite-producing source, present in an amount sufficient to produce a bleaching-effective amount of hypochlorite; and (b) a viscoelastic thickening system, consisting essentially of a C 14-18 alkyl betaine or sulfobetaine; and an anionic organic bleach-resistant counterion, selected from the group consisting of C 2-6 alkyl carboxylates, aryl carboxylates, C 2-10 alkyl sulphonates, aryl sulphonates, C 2-10 sulfated alkyl alcohols, aryl alcohols, and mixtures thereof; and wherein (c) is present in an amount to thicken and result in a relative elasticity between about 10-500 sec/Pa, and a viscosity of at least about 20 cP.
Claim 17
Dependent Claim
104 words
A thickened viscoelastic hypochlorite composition comprising, in aqueous solution (a) a hypochlorite-producing source, present in an amount sufficient to produce a bleaching-effective amount of hypochlorite; and (b) a viscoelastic thickening system, consisting essentially of a C 14-18 alkyl betaine or sulfobetaine; and an anionic organic bleach-resistant counterion, selected from the group consisting of C 2-6 alkyl carboxylates, aryl carboxylates, C 2-10 alkyl sulphonates, aryl sulphonates, C 2-10 sulfated alkyl alcohols, aryl alcohols, and mixtures thereof; and wherein (c) is present in an amount to thicken and result in a relative elasticity between about 10-500 sec/Pa, and a viscosity of at least about 20 cP.
Claim 18
Dependent Claim
54 words
The composition of claim 13 wherein component (a) is present from about 0.1 to 15 weight percent; component (b) is present from about 0.1 to 10 weight percent; the betaine is present from about 0.01 to 10 weight percent; and a mole ratio of betaine to the counterion is between about 10:1 and 1:3.
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