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US4897212A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergent tablets for dishwashing machines

Assignee: Henkel AG and Co KGaA
•
Filing: 1988-11-21
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Granted: 1990-01-30
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Expires: 2008-11-21
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Abstract

Abstract A detergent tablet for a dishwashing machine wherein at least about 10% by weight of the tablet is dissolved in the pre-rinse cycle of said machine. The tablet comprises a mixture of hydrated sodium metasilicate, anhydrous sodium metasilicate, anhydrous penta-alkali metal tripolyphosphate wherein the ratio by weight of the anhydrous tripolyphosphate to the anhydrous sodium metasilicate is from about 1:2 to 2:1, an active chlorine compound, and a tabletting aid comprising a mixture of from about 1 to about 5% by weight of sodium acetate and from about 2 to about 6% by weight of spray-dried sodium zeolite NaA, based on the weight of the tablet.

Inventors

  • 👤 Hans Kruse
  • 👤 Jochen Jacobs

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 16:45
CPC Classifications
C; C11; C11D; C11D7/00; C11D7/02; C11D7/04; C11D7/10; C11D7/16; C11D17/00; C11D17/0047; C11D17/0065; C11D17/0073; C11D17/0091; C11D7/14

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 148 words
A detergent tablet for a dishwashing machine wherein at least about 10% by weight of said tablet is dissolved in the prerinse cycle of said machine, said tablet consisting of from about 85 to about 96% by weight of a mixture of sodium metasilicate pentahydrate, anhydrous sodium metasilicate, and anhydrous pentaalkali metal tripolyphosphate wherein the ratio by weight of said anhydrous tripolyphosphate to said anhydrous sodium metasilicate is from about 1:2 to 2:1 and the ratio by weight of said anhydrous sodium metasilicate to said sodium metasilicate pentahydrate is from about 0:1 to 4:1, from about 0.5 to about 5.0% by weight of an active chlorine compound, and a tabletting aid consisting of a mixture of from about 1 to about 5% by weight of sodium acetate and from about 2 to about 6% by weight of spray-dried sodium zeolite NaA, based on the weight of said tablet.
Claim 2
Dependent Claim 148 words
A detergent tablet for a dishwashing machine wherein at least about 10% by weight of said tablet is dissolved in the prerinse cycle of said machine, said tablet consisting of from about 85 to about 96% by weight of a mixture of sodium metasilicate pentahydrate, anhydrous sodium metasilicate, and anhydrous pentaalkali metal tripolyphosphate wherein the ratio by weight of said anhydrous tripolyphosphate to said anhydrous sodium metasilicate is from about 1:2 to 2:1 and the ratio by weight of said anhydrous sodium metasilicate to said sodium metasilicate pentahydrate is from about 0:1 to 4:1, from about 0.5 to about 5.0% by weight of an active chlorine compound, and a tabletting aid consisting of a mixture of from about 1 to about 5% by weight of sodium acetate and from about 2 to about 6% by weight of spray-dried sodium zeolite NaA, based on the weight of said tablet.
Claim 3
Dependent Claim 33 words
A detergent tablet as in claim 1 wherein said tripolyphosphate comprises pentasodium tripolyphosphate, and the weight ratio of said pentasodium tripolyphosphate to said anhydrous sodium metasilicate is from about 1:1 to about 1:1.7.
Claim 4
Dependent Claim 21 words
A detergent tablet as in claim 1 wherein said anhydrous tripolyphosphate has an average particle size greater than about 0.1 mm.
Claim 5
Dependent Claim 26 words
A detergent tablet as in claim 1 wherein said active chlorine compound is selected from trichloroisocyanuric acid, dichloroisocyanuric acid, and the sodium or potassium salt thereof.
Claim 6
Dependent Claim 24 words
A detergent tablet as in claim 1 wherein said tablet has a specific gravity of from about 1.2 to about 2 g/cm 3 .
Claim 7
Dependent Claim 20 words
A detergent tablet as in claim 1 wherein said tablet has a diameter-to-height ratio of from about 0.6 to 1.5:1.
Claim 8
Dependent Claim 18 words
A detergent tablet as in claim 1 wherein said tablet weighs from about 20 to about 30 grams.
Claim 9
Dependent Claim 191 words
The process of washing dishware in an automatic domestic dishwashing machine comprising introducing a detergent tablet into a zone of said machine which exposes said tablet to the dissolving power of a stream of cold tapwater before the start of the pre-rinse cycle, and starting the automatically controlled dishwashing process wherein at least about 10% by weight of said tablet is dissolved in the pre-rinse cycle of said machine, said tablet consisting of from about 85 to about 95% by weight of a mixture of sodium metasilicate pentahydrate, anhydrous sodium metasilicate, and anhydrous penta-alkali metal tripolyphosphate wherein the ratio by weight of said anhydrous tripolyphosphate to said anhydrous sodium metasilicate is from about 1:2 to 2:1 and the ratio by weight of said anhydrous sodium metasilicate to said hydrated sodium metasilicate pentahydrate is from about 0:1 to 4:1, from about 0.5 to about 5.0% by weight of an active chlorine compound, and a tabletting aid consisting of a mixture of from about 1 to about 5% by weight of sodium acetate and from 2 to about 6% by weight of spray-dried sodium zeolite NaA, based on the weight of said tablet.
Claim 10
Dependent Claim 191 words
The process of washing dishware in an automatic domestic dishwashing machine comprising introducing a detergent tablet into a zone of said machine which exposes said tablet to the dissolving power of a stream of cold tapwater before the start of the pre-rinse cycle, and starting the automatically controlled dishwashing process wherein at least about 10% by weight of said tablet is dissolved in the pre-rinse cycle of said machine, said tablet consisting of from about 85 to about 95% by weight of a mixture of sodium metasilicate pentahydrate, anhydrous sodium metasilicate, and anhydrous penta-alkali metal tripolyphosphate wherein the ratio by weight of said anhydrous tripolyphosphate to said anhydrous sodium metasilicate is from about 1:2 to 2:1 and the ratio by weight of said anhydrous sodium metasilicate to said hydrated sodium metasilicate pentahydrate is from about 0:1 to 4:1, from about 0.5 to about 5.0% by weight of an active chlorine compound, and a tabletting aid consisting of a mixture of from about 1 to about 5% by weight of sodium acetate and from 2 to about 6% by weight of spray-dried sodium zeolite NaA, based on the weight of said tablet.
Claim 11
Dependent Claim 32 words
The process as in claim 8 wherein said tripolyphosphate comprises pentasodium tripolyphosphate, and the weight ratio of said pentasodium tripolyphosphate to said anhydrous sodium metasilicate is from about 1:1 to about 1:1.7.
Claim 12
Dependent Claim 20 words
The process as in claim 8 wherein said anhydrous tripolyphosphate has an average particle size greater than about 0.1 mm.
Claim 13
Dependent Claim 25 words
The process as in claim 8 wherein said active chlorine compound is selected from trichloroisocyanuric acid, dichloroisocyanuric acid, and the sodium or potassium salt thereof.
Claim 14
Dependent Claim 23 words
The process as in claim 8 wherein said tablet has a specific gravity of from about 1.2 to about 2 g/cm 3 .
Claim 15
Dependent Claim 19 words
The process as in claim 8 wherein said tablet has a diameter-to-height ratio of from about 0.6 to 1.5:1.
Claim 16
Dependent Claim 17 words
The process as in claim 8 wherein said tablet weighs from about 20 to about 30 grams.

References Cited (Backward Citations)

US4839078A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-01-29 1993-07-31 1994-01-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-01-29 1997-07-31 1998-01-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-01-29 2001-07-31 2002-01-30 $7700.00 Window Closed / Lapsed

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