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US4839078A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergent tablets of uniform composition for dishwashing machines

Assignee: Henkel AG and Co KGaA
•
Filing: 1986-11-17
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Granted: 1989-06-13
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Expires: 2006-11-17
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Abstract

Abstract Tablets having a broad solubility profile containing a mixture of sodium metasilicate nonahydrate and anhydrous sodium metasilicate with a grain size of from 0.2 to 0.8 mm in a ratio by weight of from 1:0.75 to 1:1.2, anhydrous pentasodium triphosphate having a grain diameter of 0.2 to 0.3 mm, and 0.5 to 5% by weight of an active chlorine donor. The ratio by weight of pentasodium triphosphate to metasilicates is about 1:1 to 1:1.7, based on anhydrous substances. The tablets are used in automatic dishwashing machines where they are introduced into a free zone of the machine before the start of the prerinse cycle, at least 10% of the tablets being dissolved by inflowing cold water and at least another 70% being available in the main-wash cycle.

Inventors

  • 👤 Hans Kruse
  • 👤 Jochen Jacobs
  • 👤 Theodor Altenschoepfer
  • 👤 Peter Jeschke

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 22:57
CPC Classifications
C; C11; C11D; C11D17/00; C11D17/0047; C11D17/0065; C11D17/0073; C11D17/0091; C11D3/00; C11D3/02; C11D3/04; C11D3/08; C11D3/395; C11D3/3955

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 182 words
A detergent tablet having a uniform composition and a broad solubility profile for use in automatic dishwashing machines, said tablet consisting of alkaline-reacting components selected from the group consisting of alkali metal metasilicate, penta-alkali metal triphosphate, an active chlorine compound, and tabletting aids, wherein said alkali metal metasilicate consists of a mixture of anhydrous sodium metasilicate and sodium metasilicate nonahydrate and said penta-alkali metal triphosphate consists of anhydrous pentasodium triphosphate, and the ratio by weight of said anhydrous sodium metasilicate to said sodium metasilicate nonahydrate is from about 1:0.3 to 1:1.5, and the ratio by weight of said anhydrous pentasodium triphosphate to said anhydrous sodium metasilicate is from about 2:1 to 1:2, wherein at least about 10% by weight of said tablet is dissolved in the pre-rinse cycle of said dishwashing machines by the cold tap water flowing in producing a pH value of at least about 10 in the wash liquor, and wherein at least about 65% by weight of said tablet is available for the main wash cycle of said dishwashing machines by virtue of its solubility in warm water.
Claim 2
Dependent Claim 182 words
A detergent tablet having a uniform composition and a broad solubility profile for use in automatic dishwashing machines, said tablet consisting of alkaline-reacting components selected from the group consisting of alkali metal metasilicate, penta-alkali metal triphosphate, an active chlorine compound, and tabletting aids, wherein said alkali metal metasilicate consists of a mixture of anhydrous sodium metasilicate and sodium metasilicate nonahydrate and said penta-alkali metal triphosphate consists of anhydrous pentasodium triphosphate, and the ratio by weight of said anhydrous sodium metasilicate to said sodium metasilicate nonahydrate is from about 1:0.3 to 1:1.5, and the ratio by weight of said anhydrous pentasodium triphosphate to said anhydrous sodium metasilicate is from about 2:1 to 1:2, wherein at least about 10% by weight of said tablet is dissolved in the pre-rinse cycle of said dishwashing machines by the cold tap water flowing in producing a pH value of at least about 10 in the wash liquor, and wherein at least about 65% by weight of said tablet is available for the main wash cycle of said dishwashing machines by virtue of its solubility in warm water.
Claim 3
Dependent Claim 29 words
A detergent tablet in accordance with claim 1 wherein the ratio by weight of said anhydrous sodium metasilicate to said sodium metasilicate nonahydrate is from about 1:0.75 to 1:1.2.
Claim 4
Dependent Claim 26 words
A detergent tablet in accordance with claim 1 wherein said anhydrous penta-sodium triphosphate has an average grain diameter of from about 0.2 to about 0.3 mm.
Claim 5
Dependent Claim 26 words
A detergent tablet in accordance with claim 1 wherein said anhydrous sodium metasilicate has a grain size distribution of between about 0.01 to about 2.0 mm.
Claim 6
Dependent Claim 44 words
A detergent tablet in accordance with claim 1 wherein said mixture of anhydrous sodium metasilicate, sodium metasilicate nonahydrate and said anhydrous pentasodium triphosphate is present in an amount of from about 88 to about 98% by weight, based on the weight of said tablet.
Claim 7
Dependent Claim 34 words
A detergent tablet in accordance with claim 1 wherein said active chlorine compound is present in an amount of from about 0.5 to about 5.0% by weight, based on the weight of said tablet.
Claim 8
Dependent Claim 16 words
A detergent tablet in accordance with claim 6 wherein said active chlorine compound comprises trichloroisocyanuric acid.
Claim 9
Dependent Claim 33 words
A detergent tablet in accordance with claim 1 wherein said tabletting aids are present in an amount of from about 0.5 to about 7.0% by weight, based on the weight of said tablet.
Claim 10
Dependent Claim 191 words
A detergent tablet having a uniform composition and a broad solubility profile for use in automatic dishwashing machines, said tablet consisting of from about 88 to about 98% by weight of a mixture of anhydrous sodium metasilicate, sodium metasilicate nonahydrate and anhydrous penta-sodium triphosphate; from about 0.5 to about 5.0% by weight of an active chlorine compound; and from about 0.5 to about 7.0% by weight of tabletting aids; all weights being based on the weight of said tablet, and the ratio by weight of said anhydrous sodium metasilicate to said sodium metasilicate nonahydrate is from about 1:0.3 to 1:1.5, and the ratio by weight of said anhydrous pentasodium triphosphate to said anhydrous sodium metasilicate is from about 2:1 to 1:2, wherein at least about 10% by weight of said tablet is dissolved in the pre-rinse cycle of said dishwashing machines by the cold tap water flowing in producing a pH value of at least about 10 in the wash liquor, and wherein at least about 65% by weight of said tablet is available for the main wash cycle of said dishwashing machines by virtue of its solubility in warm water.
Claim 11
Dependent Claim 191 words
A detergent tablet having a uniform composition and a broad solubility profile for use in automatic dishwashing machines, said tablet consisting of from about 88 to about 98% by weight of a mixture of anhydrous sodium metasilicate, sodium metasilicate nonahydrate and anhydrous penta-sodium triphosphate; from about 0.5 to about 5.0% by weight of an active chlorine compound; and from about 0.5 to about 7.0% by weight of tabletting aids; all weights being based on the weight of said tablet, and the ratio by weight of said anhydrous sodium metasilicate to said sodium metasilicate nonahydrate is from about 1:0.3 to 1:1.5, and the ratio by weight of said anhydrous pentasodium triphosphate to said anhydrous sodium metasilicate is from about 2:1 to 1:2, wherein at least about 10% by weight of said tablet is dissolved in the pre-rinse cycle of said dishwashing machines by the cold tap water flowing in producing a pH value of at least about 10 in the wash liquor, and wherein at least about 65% by weight of said tablet is available for the main wash cycle of said dishwashing machines by virtue of its solubility in warm water.
Claim 12
Dependent Claim 223 words
A dishwashing process comprising introducing a detergent tablet into a zone of an automatic dishwashing machine which exposes said tablet to the dissolving power of the inflowing stream of cold water during the pre-rinse cycle of said machine, said detergent tablet having a uniform composition and a broad solubility profile for use in automatic dishwashing machines, said tablet consisting of alkaline-reacting components selected from the group consisting of alkali metal metasilicate, penta-alkali metal triphosphate, an active chlorine compound, and tabletting aids, wherein said alkali metal metasilicate consists of a mixture of anhydrous sodium metasilicate and sodium metasilicate nonahydrate and said penta-alkali metal triphosphate consists of anhydrous penta-sodium triphosphate, and the ratio by weight of said anhydrous sodium metasilicate to said sodium metasilicate nonahydrate is from about 1:0.3 to 1:1.5, and the ratio by weight of said anhydrous pentasodium triphosphate to said anhydrous sodium metasilicate is from about 2:1 to 1:2, and starting said machine, whereby at least about 10% by weight of said tablet is dissolved in the pre-rinse cycle of said dishwashing machines by the cold water flowing in producing a pH value of at least about 10 in the wash liquor, and wherein at least about 65% by weight of said tablet is available for the main wash cycle of said dishwashing machines by virtue of its solubility in warm water.
Claim 13
Dependent Claim 223 words
A dishwashing process comprising introducing a detergent tablet into a zone of an automatic dishwashing machine which exposes said tablet to the dissolving power of the inflowing stream of cold water during the pre-rinse cycle of said machine, said detergent tablet having a uniform composition and a broad solubility profile for use in automatic dishwashing machines, said tablet consisting of alkaline-reacting components selected from the group consisting of alkali metal metasilicate, penta-alkali metal triphosphate, an active chlorine compound, and tabletting aids, wherein said alkali metal metasilicate consists of a mixture of anhydrous sodium metasilicate and sodium metasilicate nonahydrate and said penta-alkali metal triphosphate consists of anhydrous penta-sodium triphosphate, and the ratio by weight of said anhydrous sodium metasilicate to said sodium metasilicate nonahydrate is from about 1:0.3 to 1:1.5, and the ratio by weight of said anhydrous pentasodium triphosphate to said anhydrous sodium metasilicate is from about 2:1 to 1:2, and starting said machine, whereby at least about 10% by weight of said tablet is dissolved in the pre-rinse cycle of said dishwashing machines by the cold water flowing in producing a pH value of at least about 10 in the wash liquor, and wherein at least about 65% by weight of said tablet is available for the main wash cycle of said dishwashing machines by virtue of its solubility in warm water.
Claim 14
Dependent Claim 29 words
A dishwashing process in accordance with claim 10 wherein the ratio by weight of said anhydrous sodium metasilicate to said sodium metasilicate nonahydrate is from about 1:0.75 to 1:1.2.
Claim 15
Dependent Claim 26 words
A dishwashing process in accordance with claim 10 wherein said anhydrous penta-sodium triphosphate has an average grain diameter of from about 0.2 to about 0.3 mm.
Claim 16
Dependent Claim 26 words
A dishwashing process in accordance with claim 10 wherein said anhydrous sodium metasilicate has a grain size distribution of between about 0.01 to about 2.0 mm.
Claim 17
Dependent Claim 44 words
A dishwashing process in accordance with claim 10 wherein said mixture of anhydrous sodium metasilicate, sodium metasilicate nonahydrate and said anhydrous penta-sodium triphosphate is present in an amount of from about 88 to about 98% by weight, based on the weight of said tablet.
Claim 18
Dependent Claim 34 words
A dishwashing process in accordance with claim 10 wherein said active chlorine compound is present in an amount of from about 0.5 to about 5.0% by weight, based on the weight of said tablet.
Claim 19
Dependent Claim 16 words
A dishwashing process in accordance with claim 15 wherein said active chlorine compound comprises trichloroisocyanuric acid.
Claim 20
Dependent Claim 33 words
A dishwashing process in accordance with claim 10 wherein said tabletting aids are present in an amount of from about 0.5 to about 7.0% by weight, based on the weight of said tablet.
Claim 21
Dependent Claim 69 words
A dishwashing process in accordance with claim 10 wherein said tablet comprises from about 88 to about 98% be weight of a mixture of anhydrous sodium metasilicate, sodium metasilicate nonahydrate and anhydrous penta-sodium triphosphate; from about 0.5 to about 5.0% by weight of an active chlorine compound; and from about 0.5 to about 7.0% by weight of tabletting aids; all weights being based on the weight of said tablet.

References Cited (Backward Citations)

US2412819A Cited
US3247123A Cited
US3390092A Cited
US4219436A Cited
US4219435A Cited
US4518516A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-06-12 1992-12-12 1993-06-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-06-12 1996-12-12 1997-06-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-06-12 2000-12-12 2001-06-13 $7700.00 Window Closed / Lapsed

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