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Quarternary ammonium pendant siloxane copolymers

Assignee: General Electric Co
•
Filing: 1988-07-01
•
Granted: 1990-01-23
•
Expires: 2008-07-01
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Abstract

Abstract Process for the manufacture of quaternary ammonium pendant siloxane copolymers by the reaction of epoxy pendant siloxane copolymers with a tertiary amine acid salt using a catalytic amount of a free tertiary amine as the catalyst.

Inventors

  • 👤 Anthony J. Margida

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 11:53
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/38; C08G77/382; C08G77/388

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 224 words
A process for producing a quarternary ammonium pendant siloxane copolymer containing in the copolymer backbone the quarternary ammonium pendant siloxy unit of the structure: ##STR18## or the siloxy unit: ##STR19## or the siloxy unit: ##STR20## which comprises reacting an epoxy pendant siloxane copolymer containing in the copolymer backbone the epoxy pendant siloxy unit of the structure: ##STR21## or the siloxy unit: ##STR22## or the siloxy unit: ##STR23## with a tertiary amine acid salt of the general formula R 3 '"N·HX in contact with a catalytic amount of free tertiary amine catalyst of the general formula R 3 '"N, said catalytic amount being at a ratio of from about 0.0005:1 to about 0.05:1 free tertiary amine equivalent to tertiary amine acid salt equivalent, wherein R is an alkyl group having from 1 to 3 carbon atoms; R" is hydrogen or methyl; R'" is a hydrocarbyl group having from 1 to about 20 carbon atoms; X represents the charged anion of the inorganic or organic acid of the acid component used in preparation of the tertiary amine acid salt; r has a value of from 1 to about 10; m has a value of from 2 to about 4; n has a value of from 0 to about 10; y has a value of 1 or 2; and z has a value of 1 to 3.
Claim 2
Dependent Claim 224 words
A process for producing a quarternary ammonium pendant siloxane copolymer containing in the copolymer backbone the quarternary ammonium pendant siloxy unit of the structure: ##STR18## or the siloxy unit: ##STR19## or the siloxy unit: ##STR20## which comprises reacting an epoxy pendant siloxane copolymer containing in the copolymer backbone the epoxy pendant siloxy unit of the structure: ##STR21## or the siloxy unit: ##STR22## or the siloxy unit: ##STR23## with a tertiary amine acid salt of the general formula R 3 '"N·HX in contact with a catalytic amount of free tertiary amine catalyst of the general formula R 3 '"N, said catalytic amount being at a ratio of from about 0.0005:1 to about 0.05:1 free tertiary amine equivalent to tertiary amine acid salt equivalent, wherein R is an alkyl group having from 1 to 3 carbon atoms; R" is hydrogen or methyl; R'" is a hydrocarbyl group having from 1 to about 20 carbon atoms; X represents the charged anion of the inorganic or organic acid of the acid component used in preparation of the tertiary amine acid salt; r has a value of from 1 to about 10; m has a value of from 2 to about 4; n has a value of from 0 to about 10; y has a value of 1 or 2; and z has a value of 1 to 3.
Claim 3
Dependent Claim 127 words
A process as claimed in claim 1 wherein said quarternary ammonium pendant siloxane copolymer has the general formula: MD.sub.c D*.sub.d D.sup.x.sub.e.sup.E'.sub.d E.sub.d *M" (III) and said epoxy pendant siloxane copolymer has the general formula: MD.sub.c D".sub.d D.sup.x.sub.e E.sub.d E.sub.d " M' (I) wherein: M=R.sub.3 SiO--, M'=R.sub.3 Si--, ##STR24## D*, D", E, E.sup.*, E', E", R, R'", HX, m and n are as defined in claim 1; and R' is hydrogen or alkyl having from 1 to about 4 carbon atoms; b has a value of from 1 to about 75; c has a value of from 0 to about 1,000; e has a value of from 0 to about 50; and the sum of the d values is a positive number of from 1 to about 200.
Claim 4
Dependent Claim 53 words
A process as claimed in claim 2 wherein said quarternary ammonium pendant siloxane copolymer has the general formula: MD.sub.c D*.sub.d M' (IV) and said epoxy pendant siloxane copolymer has the general formula: MD.sub.c D".sub.d M' (II) wherein M, D, D * , D", M', c and d are as defined in claim 2.
Claim 5
Dependent Claim 32 words
A process as claimed in claim 1 wherein said catalytic amount is at a ratio of from about 0.001:1 to about 0.005:1 free tertiary amine equivalent to tertiary amine acid salt equivalent.
Claim 6
Dependent Claim 32 words
A process as claimed in claim 2 wherein said catalytic amount is at a ratio of from about 0.001:1 to about 0.005:1 free tertiary amine equivalent to tertiary amine acid salt equivalent.
Claim 7
Dependent Claim 32 words
A process as claimed in claim 3 wherein said catalytic amount is at a ratio of from about 0.001:1 to about 0.005:1 free tertiary amine equivalent to tertiary amine acid salt equivalent.
Claim 8
Dependent Claim 23 words
A process as claimed in claim 1 wherein R and R'" are methyl, R" is hydrogen, m is 3 and X is chlorine.
Claim 9
Dependent Claim 33 words
A process as claimed in claim 2 wherein R and R'" are methyl, R' and R" are hydrogen, (C m H 2m O) is (C 2 H 4 O) and X is chlorine.
Claim 10
Dependent Claim 19 words
A process as claimed in claim 8 wherein (C m H 2m O) is (C 3 H 6 O).
Claim 11
Dependent Claim 25 words
A process as claimed in claim 3 wherein the R and R'" groups are methyl, R" is hydrogen, m is 3 and X is chlorine.
Claim 12
Dependent Claim 35 words
A process as claimed in claim 3, wherein the M group is (CH 3 ) 3 SiO--, the D group is ##STR25## the D" group is ##STR26## and M' is (CH 3 ) 3 Si--.
Claim 13
Dependent Claim 21 words
A process as claimed in claim 11 wherein the catalyst is trimethylamine and the tertiary amine acid salt is trimethylamine hydrochloride.

References Cited (Backward Citations)

US3203969A Cited
US4006176A Cited
US4013574A Cited
US4492802A Cited
US4421932A Cited
US4417066A Cited
EP0107088A1 Cited
US4503242A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-01-22 1993-07-24 1994-01-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-01-22 1997-07-24 1998-01-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-01-22 2001-07-24 2002-01-23 $7700.00 Window Closed / Lapsed

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