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US4895964A
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Quarternary ammonium pendant siloxane copolymers
Assignee: General Electric Co
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Filing: 1988-07-01
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Granted: 1990-01-23
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Expires: 2008-07-01
Abstract
Abstract Process for the manufacture of quaternary ammonium pendant siloxane copolymers by the reaction of epoxy pendant siloxane copolymers with a tertiary amine acid salt using a catalytic amount of a free tertiary amine as the catalyst.
Inventors
- 👤 Anthony J. Margida
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 11:53
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/38; C08G77/382; C08G77/388
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
224 words
A process for producing a quarternary ammonium pendant siloxane copolymer containing in the copolymer backbone the quarternary ammonium pendant siloxy unit of the structure: ##STR18## or the siloxy unit: ##STR19## or the siloxy unit: ##STR20## which comprises reacting an epoxy pendant siloxane copolymer containing in the copolymer backbone the epoxy pendant siloxy unit of the structure: ##STR21## or the siloxy unit: ##STR22## or the siloxy unit: ##STR23## with a tertiary amine acid salt of the general formula R 3 '"N·HX in contact with a catalytic amount of free tertiary amine catalyst of the general formula R 3 '"N, said catalytic amount being at a ratio of from about 0.0005:1 to about 0.05:1 free tertiary amine equivalent to tertiary amine acid salt equivalent, wherein R is an alkyl group having from 1 to 3 carbon atoms; R" is hydrogen or methyl; R'" is a hydrocarbyl group having from 1 to about 20 carbon atoms; X represents the charged anion of the inorganic or organic acid of the acid component used in preparation of the tertiary amine acid salt; r has a value of from 1 to about 10; m has a value of from 2 to about 4; n has a value of from 0 to about 10; y has a value of 1 or 2; and z has a value of 1 to 3.
Claim 2
Dependent Claim
224 words
A process for producing a quarternary ammonium pendant siloxane copolymer containing in the copolymer backbone the quarternary ammonium pendant siloxy unit of the structure: ##STR18## or the siloxy unit: ##STR19## or the siloxy unit: ##STR20## which comprises reacting an epoxy pendant siloxane copolymer containing in the copolymer backbone the epoxy pendant siloxy unit of the structure: ##STR21## or the siloxy unit: ##STR22## or the siloxy unit: ##STR23## with a tertiary amine acid salt of the general formula R 3 '"N·HX in contact with a catalytic amount of free tertiary amine catalyst of the general formula R 3 '"N, said catalytic amount being at a ratio of from about 0.0005:1 to about 0.05:1 free tertiary amine equivalent to tertiary amine acid salt equivalent, wherein R is an alkyl group having from 1 to 3 carbon atoms; R" is hydrogen or methyl; R'" is a hydrocarbyl group having from 1 to about 20 carbon atoms; X represents the charged anion of the inorganic or organic acid of the acid component used in preparation of the tertiary amine acid salt; r has a value of from 1 to about 10; m has a value of from 2 to about 4; n has a value of from 0 to about 10; y has a value of 1 or 2; and z has a value of 1 to 3.
Claim 3
Dependent Claim
127 words
A process as claimed in claim 1 wherein said quarternary ammonium pendant siloxane copolymer has the general formula: MD.sub.c D*.sub.d D.sup.x.sub.e.sup.E'.sub.d E.sub.d *M" (III) and said epoxy pendant siloxane copolymer has the general formula: MD.sub.c D".sub.d D.sup.x.sub.e E.sub.d E.sub.d " M' (I) wherein: M=R.sub.3 SiO--, M'=R.sub.3 Si--, ##STR24## D*, D", E, E.sup.*, E', E", R, R'", HX, m and n are as defined in claim 1; and R' is hydrogen or alkyl having from 1 to about 4 carbon atoms; b has a value of from 1 to about 75; c has a value of from 0 to about 1,000; e has a value of from 0 to about 50; and the sum of the d values is a positive number of from 1 to about 200.
Claim 4
Dependent Claim
53 words
A process as claimed in claim 2 wherein said quarternary ammonium pendant siloxane copolymer has the general formula: MD.sub.c D*.sub.d M' (IV) and said epoxy pendant siloxane copolymer has the general formula: MD.sub.c D".sub.d M' (II) wherein M, D, D * , D", M', c and d are as defined in claim 2.
Claim 5
Dependent Claim
32 words
A process as claimed in claim 1 wherein said catalytic amount is at a ratio of from about 0.001:1 to about 0.005:1 free tertiary amine equivalent to tertiary amine acid salt equivalent.
Claim 6
Dependent Claim
32 words
A process as claimed in claim 2 wherein said catalytic amount is at a ratio of from about 0.001:1 to about 0.005:1 free tertiary amine equivalent to tertiary amine acid salt equivalent.
Claim 7
Dependent Claim
32 words
A process as claimed in claim 3 wherein said catalytic amount is at a ratio of from about 0.001:1 to about 0.005:1 free tertiary amine equivalent to tertiary amine acid salt equivalent.
Claim 8
Dependent Claim
23 words
A process as claimed in claim 1 wherein R and R'" are methyl, R" is hydrogen, m is 3 and X is chlorine.
Claim 9
Dependent Claim
33 words
A process as claimed in claim 2 wherein R and R'" are methyl, R' and R" are hydrogen, (C m H 2m O) is (C 2 H 4 O) and X is chlorine.
Claim 10
Dependent Claim
19 words
A process as claimed in claim 8 wherein (C m H 2m O) is (C 3 H 6 O).
Claim 11
Dependent Claim
25 words
A process as claimed in claim 3 wherein the R and R'" groups are methyl, R" is hydrogen, m is 3 and X is chlorine.
Claim 12
Dependent Claim
35 words
A process as claimed in claim 3, wherein the M group is (CH 3 ) 3 SiO--, the D group is ##STR25## the D" group is ##STR26## and M' is (CH 3 ) 3 Si--.
Claim 13
Dependent Claim
21 words
A process as claimed in claim 11 wherein the catalyst is trimethylamine and the tertiary amine acid salt is trimethylamine hydrochloride.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-01-22 | 1993-07-24 | 1994-01-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-01-22 | 1997-07-24 | 1998-01-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-01-22 | 2001-07-24 | 2002-01-23 | $7700.00 | Window Closed / Lapsed |