Patent US4889948A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4889948A Expired / Lapsed US ⏱️ 0.0 years remaining

Acrylate ester ether derivatives

Assignee: University of Southern Mississippi
•
Filing: 1987-08-18
•
Granted: 1989-12-26
•
Expires: 2007-08-18
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A process for synthesizing ethers of alkyl alpha(hydroxymethyl)-acrylate by reacting alkyl acrylate and formaldehyde in the presence of a DABCO catalyst. The ethers may be used as cross-linking agents for thermoplastic polymers. Further, these ethers in turn enable synthesis of cyclopolymers that may show promising biological activity.

Inventors

  • 👤 Lon J. Mathias
  • 👤 Selim H. Kusefoglu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 09:08
CPC Classifications
C; C08; C08F; C08F16/00; C08F16/12; C08F16/32

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 35 words
A vinyl monomer of the formula: ##STR9## wherein n is an integer from 0 to 4 and R is a member selected from the group consisting of carboxy, carboxyalkyl, carbonylalkyl, cyano, carboxamide, and substituted carboxamide.
Claim 2
Dependent Claim 35 words
A vinyl monomer of the formula: ##STR9## wherein n is an integer from 0 to 4 and R is a member selected from the group consisting of carboxy, carboxyalkyl, carbonylalkyl, cyano, carboxamide, and substituted carboxamide.
Claim 3
Dependent Claim 10 words
The vinyl monomer of claim 1 wherein n is 0.
Claim 4
Dependent Claim 10 words
The vinyl monomer of claim 1 wherein n is 1.
Claim 5
Dependent Claim 10 words
The vinyl monomer of claim 1 wherein n is 2.
Claim 6
Dependent Claim 20 words
The vinyl monomer of claim 1 wherein R is a member selected from the group consisting of carboxy and carboxymethyl.
Claim 7
Dependent Claim 32 words
A method of preparing the vinyl monomer of claim 1 comprising reacting an acrylate ester with formaldehyde in the presence of 1,4-diazabicyclo [2.2.2]-octane and separating the monomer from the resulting reaction mixture.
Claim 8
Dependent Claim 30 words
A method of preparing the vinyl monomer of claim 1 comprising heating alkyl alpha-(hydroxymethyl) acrylate in the presence of 1,4-diazabicyclo [2.2.2.]-octane and separating the monomer from the resulting reaction mixture.

References Cited (Backward Citations)

US3066165A Cited
US3288883A Cited
US3743669A Cited
EP0184731A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-12-25 1993-06-26 1993-12-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-12-25 1997-06-26 1997-12-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-12-25 2001-06-26 2001-12-26 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag