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Composite material containing a layered silicate

Assignee: Toyota Central R&D Labs Inc
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Filing: 1988-03-04
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Granted: 1989-12-26
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Expires: 2008-03-04
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Abstract

Abstract A composite material comprising a resin other than polyamide resin and a layered silicate dispersed therein, said layered silicate having a layer thickness of 7 to 12 ANGSTROM and an interlayer distance of 30 ANGSTROM or above. Owing to the layered silicate uniformly dispersed in the resin matrix, the composite material is superior in mechanical characteristics and heat resistance. It also has good water resistance and chemical resistance.

Inventors

  • 👤 Arimitsu Usuki
  • 👤 Tadashi Mizutani
  • 👤 Yoshiaki Fukushima
  • 👤 Megumi Fujimoto
  • 👤 Kenzo Fukumori
  • 👤 Yoshitsugu Kojima
  • 👤 Norio Sato
  • 👤 Toshio Kurauchi
  • 👤 Osami Kamigaito

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:00
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/34; C01; C01B; C01B33/00; C01B33/20; C01B33/36; C01B33/38; C01B33/44; C04; C04B; C04B14/00; C04B14/02; C04B14/04; C04B14/10; C04B14/20; C04B14/206; C04B24/00; C04B24/40; C04B24/42; C04B24/425; C04B26/00; C04B26/02; C08F; C08F2/00; C08F2/44; C08K9/00; C08K9/04; C10; C10M; C10M113/00; C10M113/16; C10M169/00; C08K2201/00; C08K2201/014; C10M2201/00; C10M2201/10; C10M2201/102; C10M2201/103; C10M2201/14; C10M2201/145; C10M2205/00; C10M2205/003; C10M2209/00; C10M2209/02; C10M2209/10; C10M2209/101; C10M2215/00; C10M2215/02

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 75 words
A composite material, which comprises: (a) at least one resin selected from the group consisting of a vinyl-based polymeric compound, a thermosetting resin and a rubber, and (b) a layered silicate uniformly dispersed in said resin, said layered silicate having a layer thickness of about 7 to 12 Å and an interlayer distance of at least about 30 Å, wherein said at least one resin is connected to said layered silicate through an intermediate therebetween.
Claim 2
Dependent Claim 75 words
A composite material, which comprises: (a) at least one resin selected from the group consisting of a vinyl-based polymeric compound, a thermosetting resin and a rubber, and (b) a layered silicate uniformly dispersed in said resin, said layered silicate having a layer thickness of about 7 to 12 Å and an interlayer distance of at least about 30 Å, wherein said at least one resin is connected to said layered silicate through an intermediate therebetween.
Claim 3
Dependent Claim 15 words
The composite material as claimed in claim 1, wherein said intermediate is an ionic bond.
Claim 4
Dependent Claim 32 words
The composite material as claimed in claim 1 wherein said layered silicate is negatively charged and one negative charge occupies an area of 25 to 200 Å 2 on the layer surface.
Claim 5
Dependent Claim 30 words
The composite material as claimed in claim 1 wherein the content of said layered silicate is 0.05 to 150 parts by weight per 100 parts by weight of the resin.
Claim 6
Dependent Claim 59 words
The composite material as claimed in claim 1 wherein the composite material comprises a complex and solid rubber, said complex being composed of liquid rubber having a positively charged group and the layered silicate uniformly dispersed therein, the interlayer distance of said layered silicate being greater than 30 Å and the liquid rubber being dissolved in the solid rubber.
Claim 7
Dependent Claim 22 words
A composite material as claimed in claim 5, wherein the liquid rubber is one which has a molecular weight greater than 1000.
Claim 8
Dependent Claim 36 words
The composite material as claimed in claim 5, wherein the layered silicate is contained in the complex in an amount of 20 to 1000 parts by weight per 100 parts by weight of the liquid rubber.
Claim 9
Dependent Claim 32 words
The composite material as claimed in claim 5, wherein the solid rubber is at least one selected from the croup consisting of natural rubber, synthetic rubber, thermoplastic elastomer, and a blend thereof.
Claim 10
Dependent Claim 16 words
The composite material as claimed in claim 5, wherein the solid rubber is a diene rubber.
Claim 11
Dependent Claim 23 words
The composite material as claimed in claim 5, wherein the solid rubber is one which has a molecular weight not less than 10000.
Claim 12
Dependent Claim 30 words
The composite material as claimed in claim 5, wherein the content of said complex is 1 to 10 parts by weight per 100 parts by weight of the solid rubber.
Claim 13
Dependent Claim 13 words
The composite material as claimed in claim 1, which further comprises carbon black.
Claim 14
Dependent Claim 29 words
The composite material as claimed in claim 12, wherein the content of carbon black is 0 to 100 parts by weight for 100 parts by weight of solid rubber.
Claim 15
Dependent Claim 13 words
The composite material as claimed in claim 1, wherein said resin is rubber.
Claim 16
Dependent Claim 17 words
The composite material as claimed in claim 1, wherein said layered silicate is a smectite clay mineral.
Claim 17
Dependent Claim 78 words
A composite material, which comprises: (a) at least one resin selected from the group consisting of a vinyl-based polymeric compound and a thermosetting resin, and (b) a layered silicate uniformly dispersed in said resin, wherein said layered silicate has a layer thickness of about 7 to 12 Å and an interlayer distance of at least about 30 Å, and wherein said at least one resin is connected to said layered silicate through the side chains of said resin.
Claim 18
Dependent Claim 78 words
A composite material, which comprises: (a) at least one resin selected from the group consisting of a vinyl-based polymeric compound and a thermosetting resin, and (b) a layered silicate uniformly dispersed in said resin, wherein said layered silicate has a layer thickness of about 7 to 12 Å and an interlayer distance of at least about 30 Å, and wherein said at least one resin is connected to said layered silicate through the side chains of said resin.
Claim 19
Dependent Claim 62 words
A composite material, which comprises: (a) solid rubber, and (b) a layered silicate uniformly dispersed in said resin, wherein said layered silicate has a layer thickness of about 7 to 12 Å, and an interlayer distance of at least about 30 Å, and wherein said solid rubber is connected with said layered silicate through a liquid rubber dissolved in said sloid rubber.
Claim 20
Dependent Claim 62 words
A composite material, which comprises: (a) solid rubber, and (b) a layered silicate uniformly dispersed in said resin, wherein said layered silicate has a layer thickness of about 7 to 12 Å, and an interlayer distance of at least about 30 Å, and wherein said solid rubber is connected with said layered silicate through a liquid rubber dissolved in said sloid rubber.

References Cited (Backward Citations)

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US4400485A Cited
US4434075A Cited
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US4560715A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-12-25 1993-06-26 1993-12-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-12-25 1997-06-26 1997-12-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-12-25 2001-06-26 2001-12-26 $7700.00 Window Closed / Lapsed

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