Patent US4885034A successfully refreshed from Google Patents.
US4885034A
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Method of making a composite TiO2 pigment
Assignee: GEA Group AG
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Filing: 1987-08-24
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Granted: 1989-12-05
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Expires: 2007-08-24
Abstract
Abstract In a process for producing a composite TiO2 pigment which contains a white inert extender, the neutralization is simplified and the need for washing processes is eliminated in that a metatitanic acid suspension, which contains free and combined sulfuric acid and has been purified for the removal of chromophoric elements, is neutralized by an addition of calcium oxide and/or barium oxide in quantities which are stoichiometric with respect to total sulfate, the calcium sulfate and/or barium sulfate is precipitated in an intimate mixture with the metatitanic acid, and the coprecipitate is separated and dried. The precipitated calcium sulfate and/or barium sulfate is contained in the coprecipitate in an amount from 1 to 25% by weight.
Inventors
- 👤 Wolfgang Kreth
- 👤 Wolf-Dieter Griebler
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 04:46
CPC Classifications
C; C09; C09C; C09C1/00; C09C1/0081; C09C1/0084; C01; C01P; C01P2004/00; C01P2004/60; C01P2004/62; C01P2004/80; C01P2004/82; C01P2004/84
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
237 words
A method of producing a composite uncoated TiO 2 pigment having a controlled surface area in the range of 30 to 250 m 2 /g and a controlled particle size in the range of 0.007 to 0.35 microns and containing an inert extender, which comprises the steps of: (a) forming metatitanic acid suspension containing free and combined sulfuric acid and substantially free from chromophoric substances; (b) neutralizing said metatitanic acid suspension with at least one compound selected from the group which consists of calcium oxide, calcium hydroxide, calcium carbonate, barium oxide, barium hydroxide, barium carbonate, and mixtures thereof in an amount substantially stoichiometrically equivalent to the total sulfate of said solution, thereby coprecipitating in an intimate mixture with metatitanic acid at least one inert extender selected from the group which consists of calcium sulfate and barium sulfate; (c) subjecting the coprecipitate formed in step (b) to a hydrothermal treatment by heating said coprecipitate in an autoclave at a temperature of 100° to 500° C. for 30 to 120 minute prior to recovering the coprecipitate and establishing the controlled specific surface area of the coprecipitate of 30 to 250 m 2 /g, the hydrothermal treating temperature being inversely proportional to the specific surface area of the coprecipitate; (d) recovering the coprecipitate formed in steps (b) and (c); and (e) drying the coprecipitate recovered in step (d) to recover the composite TiO 2 pigment prior to coating said pigment.
Claim 2
Independent Claim
237 words
A method of producing a composite uncoated TiO 2 pigment having a controlled surface area in the range of 30 to 250 m 2 /g and a controlled particle size in the range of 0.007 to 0.35 microns and containing an inert extender, which comprises the steps of: (a) forming metatitanic acid suspension containing free and combined sulfuric acid and substantially free from chromophoric substances; (b) neutralizing said metatitanic acid suspension with at least one compound selected from the group which consists of calcium oxide, calcium hydroxide, calcium carbonate, barium oxide, barium hydroxide, barium carbonate, and mixtures thereof in an amount substantially stoichiometrically equivalent to the total sulfate of said solution, thereby coprecipitating in an intimate mixture with metatitanic acid at least one inert extender selected from the group which consists of calcium sulfate and barium sulfate; (c) subjecting the coprecipitate formed in step (b) to a hydrothermal treatment by heating said coprecipitate in an autoclave at a temperature of 100° to 500° C. for 30 to 120 minute prior to recovering the coprecipitate and establishing the controlled specific surface area of the coprecipitate of 30 to 250 m 2 /g, the hydrothermal treating temperature being inversely proportional to the specific surface area of the coprecipitate; (d) recovering the coprecipitate formed in steps (b) and (c); and (e) drying the coprecipitate recovered in step (d) to recover the composite TiO 2 pigment prior to coating said pigment.
Claim 3
Dependent Claim
25 words
The method defined in claim 1 wherein said inert extender is precipitated in said coprecipitate in an amount of 1 to 25% by weight thereof.
Claim 4
Dependent Claim
25 words
The method defined in claim 2 wherein said inert extender is precipitated in said coprecipitate in an amount of 5 to 15% by weight thereof.
Claim 5
Dependent Claim
55 words
The method defined in claim 1, further comprising the step of coating the dry coprecipitate with an oxide hydrate or mixed oxide hydrates of at least one element selected from the group which consists of silicon, aluminum and zirconium in an amount of 0.5 to 10% of the TiO 2 content of the dry coprecipitate.
Claim 6
Dependent Claim
43 words
The method defined in claim 1 wherein the dried coprecipitate of step (e) is aftertreated with a higher fatty acid of a metal salt thereof, or with a organo polysiloxane in an amount of 5 to 20% by weight of the dried coprecipitate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-12-04 | 1993-06-05 | 1993-12-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-12-04 | 1997-06-05 | 1997-12-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-12-04 | 2001-06-05 | 2001-12-05 | $7700.00 | Window Closed / Lapsed |