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Patent US4874398A successfully refreshed from Google Patents.
US4874398A
Expired / Lapsed
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Diamond compacts and process for making same
Assignee: Australian National University
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Filing: 1985-08-23
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Granted: 1989-10-17
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Expires: 2005-08-23
Abstract
Abstract A process for producing a diamond compact having a compressive strength of at least 10 kbars, the process being performed in the graphite stability field at a maximum pressure of 40 kbars at a temperature of between 1100° C. and 1600° C. for a time which permits plastic deformation of the diamond crystals giving face-to-face contacts there-between and a substantial or complete degree of chemical equilibration between the bonding agent and the diamond crystals. Bonding agents are selected from elements and alloys which produce a bond with diamond having a melting point above 1600° C. and which inhibit the formation of free graphite in the compact.
Inventors
- 👤 Alfred E. Ringwood
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 15:46
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/622; C04B35/626; C04B35/63; C04B35/6303; C04B35/6316; B; B01; B01J; B01J3/00; B01J3/06; B01J3/062; C04B35/515; C04B35/52; C04B35/56; C04B35/5607; C04B35/5626; C04B35/628; C04B35/62802; C04B35/64; C04B35/645; C04B35/65; C22; C22C; C22C26/00; B01J2203/00; B01J2203/06; B01J2203/0605; B01J2203/062; B01J2203/065; B01J2203/0655; B01J2203/0675; B01J2203/0685; C04B2235/00; C04B2235/02; C04B2235/30; C04B2235/38; C04B2235/3817; C04B2235/3826; C04B2235/3839; C04B2235/3843; C04B2235/40; C04B2235/404; C04B2235/42; C04B2235/421; C04B2235/422; C04B2235/427; C04B2235/428; C04B2235/50; C04B2235/54; C04B2235/5418; C04B2235/5436; C04B2235/5463; C04B2235/5472; C04B2235/65; C04B2235/656; C04B2235/70; C04B2235/72; C04B2235/721; C04B2235/728; C04B2235/74; C04B2235/77; C04B2235/80; C04B2235/95; C04B2235/96
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
260 words
A process for producing a diamond compact for cutting, turning drilling, and otherwise working ultra-hard ceramics, carbides and rocks which comprises: (i) intimately mixing a mass of particulate diamond crystals with a solid particulate powder bonding agent in the proportions 60-95 volume percent of diamond to 40-5 volume percent of bonding agent, the bonding agent comprising an element which reacts with carbon to form a stable carbide having a melting point exceeding about 1600° C. or a metallic alloy containing such element; (ii) subjecting the mixture to a temperature in the range of 1100°-1600° C. at a mean confining pressure in the range of 10 kbars to 40 kbars, said combination of mean confining pressure and temperature lying within the graphite stability field; and (iii) maintaining the temperature and pressure conditions of the mixture for a period greater than about 3 minutes to cause said element in the bonding agent to react extensively with carbon in the diamond crystals to form an interstitial carbide phase having a melting point about 1600° C. providing a strong bond between the diamond crystals while inhibiting the formation of free graphite by retrogressive transformation from diamond, said period being sufficient to result in substantial plastic deformation of the diamond crystals whereby contact between the diamond crystals occur over extended mating surfaces and also to result in substantial chemical equilibrium between the bonding agent and the diamond crystals whereby there is produced a thermally stable diamond compact having a minimum melting point above 1600° C. and a compressive strength above 10 kbars at ambient temperature.
Claim 2
Dependent Claim
260 words
A process for producing a diamond compact for cutting, turning drilling, and otherwise working ultra-hard ceramics, carbides and rocks which comprises: (i) intimately mixing a mass of particulate diamond crystals with a solid particulate powder bonding agent in the proportions 60-95 volume percent of diamond to 40-5 volume percent of bonding agent, the bonding agent comprising an element which reacts with carbon to form a stable carbide having a melting point exceeding about 1600° C. or a metallic alloy containing such element; (ii) subjecting the mixture to a temperature in the range of 1100°-1600° C. at a mean confining pressure in the range of 10 kbars to 40 kbars, said combination of mean confining pressure and temperature lying within the graphite stability field; and (iii) maintaining the temperature and pressure conditions of the mixture for a period greater than about 3 minutes to cause said element in the bonding agent to react extensively with carbon in the diamond crystals to form an interstitial carbide phase having a melting point about 1600° C. providing a strong bond between the diamond crystals while inhibiting the formation of free graphite by retrogressive transformation from diamond, said period being sufficient to result in substantial plastic deformation of the diamond crystals whereby contact between the diamond crystals occur over extended mating surfaces and also to result in substantial chemical equilibrium between the bonding agent and the diamond crystals whereby there is produced a thermally stable diamond compact having a minimum melting point above 1600° C. and a compressive strength above 10 kbars at ambient temperature.
Claim 3
Dependent Claim
37 words
A process according to claim 1, wherein said element is silicon which melts under said temperature and pressure conditions and reacts with carbon in the diamond crystals to produce said interstitial carbide phase comprised of silicon carbide.
Claim 4
Dependent Claim
56 words
A process according to claim 2, wherein an elevated temperature up to 1600° C. is applied to the intimate mixture prior to application of pressure in the range of 10 kbars to 40 kbars to maximize the degree of plastic deformation of said diamond crystals and to minimize production of graphite by retrogressive transformation of diamond.
Claim 5
Dependent Claim
27 words
A process according to claim 1, wherein said element is selected from the group comprising titanium, tungsten, molybdenum, niobium, tantalum, zirconium, hafnium, chromium, vanadium, scandium and boron.
Claim 6
Dependent Claim
39 words
A process according to claim 4, wherein said element reacts with carbon in the diamond crystals in the solid state to form said interstitial carbide phase by solid state reaction during the application of said temperature and pressure conditions.
Claim 7
Dependent Claim
33 words
A process according to claim 4, wherein an elevated temperature up to 1600° C. is applied to the ultimate mixture prior to application of pressure within the range 10 kbars to 40 kbars.
Claim 8
Dependent Claim
32 words
A process according to claim 1, wherein the applied pressure is in the range of 15 to 30 kbars and the applied temperature is in the range 1200° C. to 1600° C.
Claim 9
Dependent Claim
31 words
A process according to claim 1, wherein the intimate mixing is performed by applying the bonding agent to the surfaces of the diamond crystals in the form of coatings or films.
Claim 10
Dependent Claim
19 words
A process according to claim 1, wherein said temperature and pressure conditions are maintained for more than 5 minutes.
Claim 11
Dependent Claim
256 words
A process for producing a diamond compact for cutting, turning drilling, and otherwise working ultra-hard ceramics, carbides and rocks which comprises: (i) intimately mixing a mass of particulate diamond crystals with a solid particulate powder bonding agent in the proportions 60-95 volume percent of diamond to 40-5 volume percent of bonding agent, the bonding agent comprising a metal which does not form a stable carbide but which when heated in contact with a diamond surface becomes strongly bonded to that surface by a mechanism which includes acceptance of carbon into solid solution in its crystal lattice, and which does not melt at temperatures below 1600° C. when in contact with carbon; (ii) subjecting the mixture to a temperature in the range of 1100°-1600° C. at a mean confining pressure of between 10 kbars to 40 kbars, said combination of mean confining pressure and temperature lying within the graphite stability field; and (iii) maintaining the temperature and pressure conditions on the mixture for a period greater than about 3 minutes to cause said metal to accept carbon from the diamond crystals into solid solution thereby to become strongly bonded to the diamond crystals while inhibiting the formation of free graphite by retrogressive transformation from diamond, said period being sufficient to result in substantial plastic deformation of the diamond crystals whereby contacts between the diamond crystals occur over extended mating surfaces and there is produced a, thermally stable diamond compact having a minimum melting point above 1600° C. and a compressive strength above 10 kbars at ambient temperature.
Claim 12
Dependent Claim
256 words
A process for producing a diamond compact for cutting, turning drilling, and otherwise working ultra-hard ceramics, carbides and rocks which comprises: (i) intimately mixing a mass of particulate diamond crystals with a solid particulate powder bonding agent in the proportions 60-95 volume percent of diamond to 40-5 volume percent of bonding agent, the bonding agent comprising a metal which does not form a stable carbide but which when heated in contact with a diamond surface becomes strongly bonded to that surface by a mechanism which includes acceptance of carbon into solid solution in its crystal lattice, and which does not melt at temperatures below 1600° C. when in contact with carbon; (ii) subjecting the mixture to a temperature in the range of 1100°-1600° C. at a mean confining pressure of between 10 kbars to 40 kbars, said combination of mean confining pressure and temperature lying within the graphite stability field; and (iii) maintaining the temperature and pressure conditions on the mixture for a period greater than about 3 minutes to cause said metal to accept carbon from the diamond crystals into solid solution thereby to become strongly bonded to the diamond crystals while inhibiting the formation of free graphite by retrogressive transformation from diamond, said period being sufficient to result in substantial plastic deformation of the diamond crystals whereby contacts between the diamond crystals occur over extended mating surfaces and there is produced a, thermally stable diamond compact having a minimum melting point above 1600° C. and a compressive strength above 10 kbars at ambient temperature.
Claim 13
Dependent Claim
11 words
A process according to claim 10 wherein said metal is rhenium.
Claim 14
Dependent Claim
22 words
A process according to claim 10, wherein said metal is selected from the group consisting of rhodium, ruthenium, iridium, osmium and platinum.
Claim 15
Dependent Claim
59 words
A process according to claim 10, wherein an elevated temperature up to 1600° C. is applied to the intimate mixture prior to the application of pressure in the range of 10 kbars to 40 kbars whereby to maximize the degree of plastic deformation of the diamond crystals and to minimize formation of free carbon by retrogressive transformation of diamond.
Claim 16
Dependent Claim
33 words
A process according to claim 10, wherein the applied pressure is in the range of 15 to 30 kbars and the applied temperature is in the range of 1200° C. to 1600° C.
Claim 17
Dependent Claim
31 words
A process according to claim 10, wherein the intimate mixing is performed by applying the bonding agent to the surfaces of the diamond crystals in the form of coatings or films.
Claim 18
Dependent Claim
19 words
A process according to claim 10, wherein said temperature and pressure conditions are maintained for more than 5 minutes.
Claim 19
Dependent Claim
18 words
A process as in claim 1 wherein the bonding agent has a particle size less than 50 microns.
Claim 20
Dependent Claim
18 words
A process as in claim 10 wherein the bonding agent has a particle size less than 50 microns.
References Cited (Backward Citations)
US3574580A
Cited
US4142869A
Cited
US4124401A
Cited
US4167399A
Cited
US4168957A
Cited
US4151686A
Cited
US4241135A
Cited
US4231195A
Cited
US4259090A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-10-16 | 1993-04-17 | 1993-10-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-10-16 | 1997-04-17 | 1997-10-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-10-16 | 2001-04-17 | 2001-10-17 | $7700.00 | Window Closed / Lapsed |