US4151686A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Silicon carbide and silicon bonded polycrystalline diamond body and method of making it
Assignee: General Electric Co
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Filing: 1978-01-09
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Granted: 1979-05-01
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Expires: 1998-01-09
Abstract
Abstract A mass of diamond crystals contacting a mass of elemental silicon are confined within a pressure-transmitting medium. The resulting charge assembly is subjected to a pressure of at least 25 kilobars causing application of isostatic pressure to the contacting masses which dimensionally stabilizes them and increases the density of the mass of diamond crystals. The resulting pressure-maintained charge assembly is heated to a temperature sufficient to melt the silicon and at which no significant graphitization of the diamond occurs whereby the silicon is infiltrated through the interstices between the diamond crystals producing, upon cooling, an adherently bonded integral body.
Inventors
- 👤 Minyoung Lee
- 👤 Robert C. DeVries
- 👤 Lawrence E. Szala
- 👤 Roy E. Tuft
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 19:18
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/622; C04B35/64; C04B35/645; B; B01; B01J; B01J3/00; B01J3/06; B01J3/062; B22; B22F; B22F3/00; B22F3/24; B22F3/26; B24; B24D; B24D3/00; B24D3/02; B24D3/04; B24D3/06; B24D3/08; C04B35/515; C04B35/52; C04B35/626; C04B35/63; C04B35/6303; C04B35/6316; C22; C22C; C22C26/00; B01J2203/00; B01J2203/06; B01J2203/0605; B01J2203/062; B01J2203/063; B01J2203/0635; B01J2203/065; B01J2203/0655; B01J2203/0675; B01J2203/0685; C04B2235/00; C04B2235/02; C04B2235/30; C04B2235/38; C04B2235/3817; C04B2235/3826; C04B2235/42; C04B2235/422; C04B2235/427; C04B2235/428; C04B2235/50; C04B2235/54; C04B2235/5418; C04B2235/5436; C04B2235/60; C04B2235/616; C04B2235/70; C04B2235/72; C04B2235/721; C04B2235/728; C04B2235/80; C04B2235/96
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
278 words
A process for preparing a polycrystalline diamond body which comprises confining a mass of diamond crystals in contact with a mass of elemental silicon within a pressure-transmitting medium producing a charge assembly of pressure-transmitting medium enveloped-diamond and silicon contacting masses, said pressure-transmitting medium transmitting applied pressure substantially isostatically to the confined masses therewithin, applying a pressure of at least about 25 kilobars to said charge assembly causing application of substantially isostatic pressure via the pressure-transmitting medium to said contacting masses dimensionally stabilizing them and compressing the mass of diamond crystals to a density higher than 80% by volume of the resulting compressed mass of diamond crystals, maintaining said applied pressure, heating the pressure-maintained charge assembly to an infiltration temperature sufficient to melt the silicon and at which no significant graphitization of the diamond occurs whereby the resulting liquid silicon is infiltrated throughout the interstices between said compressed mass of diamond crystals, said pressure-transmitting medium being substantially inert to liquid silicon and forcing the liquid silicon to infiltrate through said compressed mass of diamond crystals, said silicon being used in an amount sufficient to fill the interstices of said compressed mass of diamond crystals, ceasing the input of heat into the resulting infiltrated diamond mass, removing said pressure and recovering the resulting polycrystalline diamond body comprised of diamond crystals bonded together by a silicon-atom containing medium comprised of silicon carbide and silicon, said silicon carbide having been formed by reaction of silicon with the diamond and non-diamond elemental carbon which may have been produced from diamond, and wherein the diamond crystals are present in an amount of at least 80% by volume of the total volume of said body.
Claim 2
Dependent Claim
278 words
A process for preparing a polycrystalline diamond body which comprises confining a mass of diamond crystals in contact with a mass of elemental silicon within a pressure-transmitting medium producing a charge assembly of pressure-transmitting medium enveloped-diamond and silicon contacting masses, said pressure-transmitting medium transmitting applied pressure substantially isostatically to the confined masses therewithin, applying a pressure of at least about 25 kilobars to said charge assembly causing application of substantially isostatic pressure via the pressure-transmitting medium to said contacting masses dimensionally stabilizing them and compressing the mass of diamond crystals to a density higher than 80% by volume of the resulting compressed mass of diamond crystals, maintaining said applied pressure, heating the pressure-maintained charge assembly to an infiltration temperature sufficient to melt the silicon and at which no significant graphitization of the diamond occurs whereby the resulting liquid silicon is infiltrated throughout the interstices between said compressed mass of diamond crystals, said pressure-transmitting medium being substantially inert to liquid silicon and forcing the liquid silicon to infiltrate through said compressed mass of diamond crystals, said silicon being used in an amount sufficient to fill the interstices of said compressed mass of diamond crystals, ceasing the input of heat into the resulting infiltrated diamond mass, removing said pressure and recovering the resulting polycrystalline diamond body comprised of diamond crystals bonded together by a silicon-atom containing medium comprised of silicon carbide and silicon, said silicon carbide having been formed by reaction of silicon with the diamond and non-diamond elemental carbon which may have been produced from diamond, and wherein the diamond crystals are present in an amount of at least 80% by volume of the total volume of said body.
Claim 3
Dependent Claim
19 words
The process according to claim 1 wherein said infiltration temperature ranges from about 1300° C. to about 1400° C.
Claim 4
Dependent Claim
17 words
The process according to claim 1 wherein said applied pressure ranges from 35 kilobars to 55 kilobars.
Claim 5
Dependent Claim
20 words
The process of claim 1 wherein said diamond crystals are size-graded ranging from about 1 micron to about 60 microns.
Claim 6
Dependent Claim
122 words
A polycrystalline diamond body comprised of a mass of diamond crystals adherently bonded together by a silicon atom-containing bonding medium comprised of silicon carbide and elemental silicon, said diamond crystals ranging in size from about 1 micron to about 1000 microns, the density of said diamond crystals ranging from about 80% by volume to about 95% by volume of said body, said silicon atom-containing bonding medium being present in an amount ranging up to about 20% by volume of said body, said bonding medium being distributed at least substantially uniformly throughout said body, the portion of said bonding medium in contact with the surfaces of said diamonds being at least substantially silicon carbide, said diamond body being at least substantially pore free.
Claim 7
Dependent Claim
122 words
A polycrystalline diamond body comprised of a mass of diamond crystals adherently bonded together by a silicon atom-containing bonding medium comprised of silicon carbide and elemental silicon, said diamond crystals ranging in size from about 1 micron to about 1000 microns, the density of said diamond crystals ranging from about 80% by volume to about 95% by volume of said body, said silicon atom-containing bonding medium being present in an amount ranging up to about 20% by volume of said body, said bonding medium being distributed at least substantially uniformly throughout said body, the portion of said bonding medium in contact with the surfaces of said diamonds being at least substantially silicon carbide, said diamond body being at least substantially pore free.
Claim 8
Dependent Claim
27 words
The polycrystalline diamond body according to claim 5 wherein the density of said diamond crystals ranges from about 80% to about 90% by volume of said body.
Claim 9
Dependent Claim
21 words
The polycrystalline diamond body according to claim 5 wherein said crystals are size-graded ranging from 1 micron to about 60 microns.
Claim 10
Dependent Claim
30 words
The polycrystalline diamond body according to claim 5 wherein silicon carbide is present in an amount ranging from about 2% by volume to about 18% by volume of said body.
Claim 11
Dependent Claim
14 words
The process according to claim 1 wherein said pressure-transmitting medium is hexagonal boron nitride.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-04-30 | 1982-10-30 | 1983-05-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-04-30 | 1986-10-30 | 1987-05-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-04-30 | 1990-10-30 | 1991-05-01 | $7700.00 | Window Closed / Lapsed |