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US4868100A
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Silver halide photographic light-sensitive material
Assignee: Konica Minolta Inc
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Filing: 1988-08-22
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Granted: 1989-09-19
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Expires: 2008-08-22
Abstract
Abstract A silver halide photographic light-sensitive material is disclosed, which is improved on color reproducibility, image stability and toe gradiation. The photographic material comprises a support having thereon at least one silver halide emulsion layer containing at least one coupler represented by the following Formula I and a water-soluble iridium salt in an amount of from 10 -9 mol to 10 -3 mol per mol of silver halide; Formula I ##STR1## In Formula I, at least one of the groups represented by R 1 , R 2 , R 3 and R 4 contains at least one group represented by the following formula II; Formula II --R.sub.5 --SO.sub.2 --R.sub.6.
Inventors
- 👤 Toyoki Nishijima
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 06:20
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/32; G03C7/36; G03C7/38; G03C7/381; G03C7/382; G03C7/3825; G03C7/3835
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
309 words
A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer containing at least one coupler represented by the the following Formula I and a water soluble iridium salt in an amount of from 10 31 9 mol to 10 -3 mol per mol of silver halide; Formula I ##STR22## wherein X represents a halogen atom or a monovalent organic group capable of being split off upon coupling reaction with the oxidized product of a color developing agent; R 1 , R 2 and R 3 may be the same of different from each other and each represent a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkinyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a residue of spiro-compound, a residue of bridged hydrocarbon compound, an alkoxy group, an aryloxy group, a heterocyclic oxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamido group, an imido group, an ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonyl amino group, an alkoxycarbonyl group, an alkylthio group, an aryloxycarbonyl group, an arylthio group or a heterocyclic thio group; and R 4 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acylamino group, an alkylamino group, an anilino group, an alkoxycarbonyl group or an alkyl thio group; provided that at least one of R 1 , R 2 , R 3 and R 4 contains at least one group represented by the following Formula II; Formula II --R.sub.5 --SO.sub.2 --R.sub.6 wherein R 5 represents an alkylene group or an arylene group; and R 6 represents an alkyl group or an aryl group.
Claim 2
Dependent Claim
309 words
A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer containing at least one coupler represented by the the following Formula I and a water soluble iridium salt in an amount of from 10 31 9 mol to 10 -3 mol per mol of silver halide; Formula I ##STR22## wherein X represents a halogen atom or a monovalent organic group capable of being split off upon coupling reaction with the oxidized product of a color developing agent; R 1 , R 2 and R 3 may be the same of different from each other and each represent a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkinyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a residue of spiro-compound, a residue of bridged hydrocarbon compound, an alkoxy group, an aryloxy group, a heterocyclic oxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamido group, an imido group, an ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonyl amino group, an alkoxycarbonyl group, an alkylthio group, an aryloxycarbonyl group, an arylthio group or a heterocyclic thio group; and R 4 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acylamino group, an alkylamino group, an anilino group, an alkoxycarbonyl group or an alkyl thio group; provided that at least one of R 1 , R 2 , R 3 and R 4 contains at least one group represented by the following Formula II; Formula II --R.sub.5 --SO.sub.2 --R.sub.6 wherein R 5 represents an alkylene group or an arylene group; and R 6 represents an alkyl group or an aryl group.
Claim 3
Dependent Claim
36 words
The material of claim 1, wherein an amount of said coupler contained in said silver halide emulsion layer is with in the range of from 1×10 -3 mol to 1 mol per mol of silver halide.
Claim 4
Dependent Claim
37 words
The material of claim 2, wherein an amount of said coupler contained in said silver halide emulsion layer is with in the range of from 1×10 -2 mol to 8×10 -1 mol per mol of silver halide.
Claim 5
Dependent Claim
31 words
The material of claim 1, wherein an amount of said water-soluble iridium salt is within the range of from 10 -8 mol to 10 -5 mol per mol of silver halide.
Claim 6
Dependent Claim
204 words
The material of claim 1, wherein said silver halide emulsion layer contains a compound represented by the following Formula III in an amount of from 0.001 mol to 0.025 mol per mol of said coupler contained said emulsion layer; Formula III ##STR23## wherein R 21 and R 22 each represent a hydrogen atom, an alkyl group, an aklenyl group, an aryl group, an acyl group, a cycloalkyl group or a heterocyclic group; and R 23 , R 24 , R 25 and R 26 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an aryl group, a cycloalkyl group, an alkoxy group, an aryloxy group, an alkyl thio group, an aryl thio group, an acyl group, an alkylacylamino group, an arylacylamino group, an alkylcarbamoyl group, an arylcarbamoyl group, alkylsulfonamido group, an arylsulfonamido group, an alkylsulfamoyl group, an arylsulfamoyl group, an alkylsufonyl group, an arylsulfonyl group, a nitro group, a cyano group, an alkyloxycarbonyl group, an aryloxycarbonyl group, an alkylacyloxy group or a arylacyloxy group; provided that, when R 23 , R 24 , R 25 and R 26 are hydrogen atoms at the same time, R 21 and R 22 shall not be hydrogen atom in the same time.
Claim 7
Dependent Claim
33 words
The material of claim 5, wherein an amount of said compound contained in said silver halide emulsion layer is within the range of from 0.005 to 0.02 mol per mol of said coupler.
Claim 8
Dependent Claim
19 words
The material of claim 1, wherein silver halide emulsion layer contains a water-soluble silver salt or a silver complex.
Claim 9
Dependent Claim
52 words
The material of claim 7, wherein said water-soluble silver salt or silver complex is one added to said silver halide emulsion at a point of time between the time when preparing of the coating solution of said silver halide emulsion and the time immediately before the coating of said silver halide emulsion.
Claim 10
Dependent Claim
33 words
The material of claim 7, said silver salt or silver complex is to be dissolved in water at 25° C. in an amount of not less than 1 g per litter of water.
Claim 11
Dependent Claim
33 words
The material of claim 9, said silver salt or silver complex is to be dissolved in water at 25° C. in an amount of not less than 3 g per litter of water.
Claim 12
Dependent Claim
35 words
The material of claim 7, wherein said silver salt is silver nitrite, silver nitrate, silver chlorate, silver perchlorate, silver sulfate, silver acetate, silver caproate, silver propionate, silver butyrate, silver valerate, silver isovalerate or silver α-naphtoate.
Claim 13
Dependent Claim
37 words
The material of claim 7, wherein an amount of said water-soluble silver salt added to said silver halide emulsion layer is within the range of from 5×10 -5 mol to 0.3 mol per mol of silver halide.
Claim 14
Dependent Claim
37 words
The material of claim 12, wherein an amount of said water-soluble silver salt added to said silver halide emulsion layer is within the range of from 1×10 -4 mol to 0.1 mol per mol of silver halide.
Claim 15
Dependent Claim
27 words
The material of claim 1, wherein said silver halide emulsion layer comprises silver haide grains having a silver chloride content of not less than 80 mol %.
Claim 16
Dependent Claim
22 words
The material of claim 14, wherein said silver halide grains have a silver bromide content of not more than 10 mol %.
Claim 17
Dependent Claim
31 words
The material of claim 15, wherein said silver halide grains are a silver chlorobromide emulsion having a silver bromide content of from 0 to 5 mol % or a silver chloride.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1992-09-18 | 1993-03-20 | 1993-09-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-09-18 | 1997-03-20 | 1997-09-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-09-18 | 2001-03-20 | 2001-09-19 | $7700.00 | Window Closed / Lapsed |