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US4705747A Expired / Lapsed US ⏱️ 0.0 years remaining

Color photographic recording material containing a silver halide emulsion and a process for its production

Assignee: Agfa Gevaert AG
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Filing: 1986-02-24
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Granted: 1987-11-10
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Expires: 2006-02-24
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Abstract

Abstract Improved silver halide emulsions are obtained by the combined use of an iridium compound and an imidazole before termination of crystal growth.

Inventors

  • 👤 Sieghart Klotzer
  • 👤 Bruno Mucke
  • 👤 Gunther Mahlberg
  • 👤 Manfred Becker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 06:44
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/09; G03C1/015; G03C2200/00; G03C2200/06

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 112 words
A color photographic recording material containing color couplers and comprising at least one photosensitive silver halide emulsion layer and, optionally, other layers on a layer support, characterized in that the silver halide emulsion contains silver halide crystals with at least 20 mole-% of silver chloride and at most 80 mole-% of silver bromide of which the crystal formation and/or crystal growth were carried out in the presence of an iridium compound and an imidazole corresponding to the following formula ##STR2## in which R 1 , R 2 , R 3 and R 4 may be the same or different and represent hydrogen and/or an optionally substituted alkyl, alkenyl, aryl or aralkyl group.
Claim 2
Dependent Claim 112 words
A color photographic recording material containing color couplers and comprising at least one photosensitive silver halide emulsion layer and, optionally, other layers on a layer support, characterized in that the silver halide emulsion contains silver halide crystals with at least 20 mole-% of silver chloride and at most 80 mole-% of silver bromide of which the crystal formation and/or crystal growth were carried out in the presence of an iridium compound and an imidazole corresponding to the following formula ##STR2## in which R 1 , R 2 , R 3 and R 4 may be the same or different and represent hydrogen and/or an optionally substituted alkyl, alkenyl, aryl or aralkyl group.
Claim 3
Dependent Claim 23 words
A color photographic recording material as claimed in claim 1, characterized in that the iridium compound and the imidazole were used during precipitation.
Claim 4
Dependent Claim 20 words
A color photographic recording material as claimed in claim 1, characterized in that the iridium compound is a water-soluble compound.
Claim 5
Dependent Claim 19 words
A color photographic recording material as claimed in claim 1, characterized in that the iridium compound is a hexachloroiridate.
Claim 6
Dependent Claim 39 words
A color photographic recording material as claimed in claim 1, characterized in that the imidazole is selected from the following group: imidazole, 1-methyl imidazole, 2-methyl imidazole, 1,2-dimethyl imidazole, 1-allyl imidazole, 1-methoxymethyl imidazole, 1-(2-carboxyethyl)-imidazole, 4-(or 5-) methyl imidazole, 2-ethyl-4-methyl imidazole.
Claim 7
Dependent Claim 111 words
A color photographic paper containing color couplers and comprisng at least one photosensitive silver halide emulsion layer and, optionally, other layers on a layer support, characterized in that the silver halide emulsion contains silver halide crystals with at least 20 mole-% of silver chloride and at most 80 mole-% of silver bromide of which the crystal formation and/or crystal growth were carried out in the presence of an iridium compound and an imidazole corresponding to the following formula: ##STR3## in which R 1 , R 2 , R 3 and R 4 may be the same or different and represent hydrogen and/or an optionally substituted alkyl, alkenyl, aryl or aralkyl group.
Claim 8
Dependent Claim 111 words
A color photographic paper containing color couplers and comprisng at least one photosensitive silver halide emulsion layer and, optionally, other layers on a layer support, characterized in that the silver halide emulsion contains silver halide crystals with at least 20 mole-% of silver chloride and at most 80 mole-% of silver bromide of which the crystal formation and/or crystal growth were carried out in the presence of an iridium compound and an imidazole corresponding to the following formula: ##STR3## in which R 1 , R 2 , R 3 and R 4 may be the same or different and represent hydrogen and/or an optionally substituted alkyl, alkenyl, aryl or aralkyl group.
Claim 9
Dependent Claim 90 words
A process for the preparation of a photographic silver halide emulsion, characterized in that the silver halide crystals with at least 20 mole-% of silver chloride and at most 80 mole-% of silver bromide were prepared in the presence of an iridium compound and an imidazole corresponding to the following formula ##STR4## in which R 1 , R 2 , R 3 and R 4 may be the same or different and represent hydrogen and/or an optionally substituted alkyl, alkenyl, aryl or aralkyl group before the termination of crystal growth.
Claim 10
Dependent Claim 90 words
A process for the preparation of a photographic silver halide emulsion, characterized in that the silver halide crystals with at least 20 mole-% of silver chloride and at most 80 mole-% of silver bromide were prepared in the presence of an iridium compound and an imidazole corresponding to the following formula ##STR4## in which R 1 , R 2 , R 3 and R 4 may be the same or different and represent hydrogen and/or an optionally substituted alkyl, alkenyl, aryl or aralkyl group before the termination of crystal growth.

References Cited (Backward Citations)

US4298683A Cited
US4469784A Cited
US4469783A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-11-09 1991-05-11 1991-11-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-11-09 1995-05-11 1995-11-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-11-09 1999-05-11 1999-11-10 $7700.00 Window Closed / Lapsed

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