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US4868100A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic light-sensitive material

Assignee: Konica Minolta Inc
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Filing: 1988-08-22
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Granted: 1989-09-19
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Expires: 2008-08-22
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Abstract

Abstract A silver halide photographic light-sensitive material is disclosed, which is improved on color reproducibility, image stability and toe gradiation. The photographic material comprises a support having thereon at least one silver halide emulsion layer containing at least one coupler represented by the following Formula I and a water-soluble iridium salt in an amount of from 10 -9 mol to 10 -3 mol per mol of silver halide; Formula I ##STR1## In Formula I, at least one of the groups represented by R 1 , R 2 , R 3 and R 4 contains at least one group represented by the following formula II; Formula II --R.sub.5 --SO.sub.2 --R.sub.6.

Inventors

  • 👤 Toyoki Nishijima

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 06:07
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/32; G03C7/36; G03C7/38; G03C7/381; G03C7/382; G03C7/3825; G03C7/3835

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 309 words
A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer containing at least one coupler represented by the the following Formula I and a water soluble iridium salt in an amount of from 10 31 9 mol to 10 -3 mol per mol of silver halide; Formula I ##STR22## wherein X represents a halogen atom or a monovalent organic group capable of being split off upon coupling reaction with the oxidized product of a color developing agent; R 1 , R 2 and R 3 may be the same of different from each other and each represent a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkinyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a residue of spiro-compound, a residue of bridged hydrocarbon compound, an alkoxy group, an aryloxy group, a heterocyclic oxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamido group, an imido group, an ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonyl amino group, an alkoxycarbonyl group, an alkylthio group, an aryloxycarbonyl group, an arylthio group or a heterocyclic thio group; and R 4 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acylamino group, an alkylamino group, an anilino group, an alkoxycarbonyl group or an alkyl thio group; provided that at least one of R 1 , R 2 , R 3 and R 4 contains at least one group represented by the following Formula II; Formula II --R.sub.5 --SO.sub.2 --R.sub.6 wherein R 5 represents an alkylene group or an arylene group; and R 6 represents an alkyl group or an aryl group.
Claim 2
Dependent Claim 309 words
A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer containing at least one coupler represented by the the following Formula I and a water soluble iridium salt in an amount of from 10 31 9 mol to 10 -3 mol per mol of silver halide; Formula I ##STR22## wherein X represents a halogen atom or a monovalent organic group capable of being split off upon coupling reaction with the oxidized product of a color developing agent; R 1 , R 2 and R 3 may be the same of different from each other and each represent a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkinyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a residue of spiro-compound, a residue of bridged hydrocarbon compound, an alkoxy group, an aryloxy group, a heterocyclic oxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamido group, an imido group, an ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonyl amino group, an alkoxycarbonyl group, an alkylthio group, an aryloxycarbonyl group, an arylthio group or a heterocyclic thio group; and R 4 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acylamino group, an alkylamino group, an anilino group, an alkoxycarbonyl group or an alkyl thio group; provided that at least one of R 1 , R 2 , R 3 and R 4 contains at least one group represented by the following Formula II; Formula II --R.sub.5 --SO.sub.2 --R.sub.6 wherein R 5 represents an alkylene group or an arylene group; and R 6 represents an alkyl group or an aryl group.
Claim 3
Dependent Claim 36 words
The material of claim 1, wherein an amount of said coupler contained in said silver halide emulsion layer is with in the range of from 1×10 -3 mol to 1 mol per mol of silver halide.
Claim 4
Dependent Claim 37 words
The material of claim 2, wherein an amount of said coupler contained in said silver halide emulsion layer is with in the range of from 1×10 -2 mol to 8×10 -1 mol per mol of silver halide.
Claim 5
Dependent Claim 31 words
The material of claim 1, wherein an amount of said water-soluble iridium salt is within the range of from 10 -8 mol to 10 -5 mol per mol of silver halide.
Claim 6
Dependent Claim 204 words
The material of claim 1, wherein said silver halide emulsion layer contains a compound represented by the following Formula III in an amount of from 0.001 mol to 0.025 mol per mol of said coupler contained said emulsion layer; Formula III ##STR23## wherein R 21 and R 22 each represent a hydrogen atom, an alkyl group, an aklenyl group, an aryl group, an acyl group, a cycloalkyl group or a heterocyclic group; and R 23 , R 24 , R 25 and R 26 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an aryl group, a cycloalkyl group, an alkoxy group, an aryloxy group, an alkyl thio group, an aryl thio group, an acyl group, an alkylacylamino group, an arylacylamino group, an alkylcarbamoyl group, an arylcarbamoyl group, alkylsulfonamido group, an arylsulfonamido group, an alkylsulfamoyl group, an arylsulfamoyl group, an alkylsufonyl group, an arylsulfonyl group, a nitro group, a cyano group, an alkyloxycarbonyl group, an aryloxycarbonyl group, an alkylacyloxy group or a arylacyloxy group; provided that, when R 23 , R 24 , R 25 and R 26 are hydrogen atoms at the same time, R 21 and R 22 shall not be hydrogen atom in the same time.
Claim 7
Dependent Claim 33 words
The material of claim 5, wherein an amount of said compound contained in said silver halide emulsion layer is within the range of from 0.005 to 0.02 mol per mol of said coupler.
Claim 8
Dependent Claim 19 words
The material of claim 1, wherein silver halide emulsion layer contains a water-soluble silver salt or a silver complex.
Claim 9
Dependent Claim 52 words
The material of claim 7, wherein said water-soluble silver salt or silver complex is one added to said silver halide emulsion at a point of time between the time when preparing of the coating solution of said silver halide emulsion and the time immediately before the coating of said silver halide emulsion.
Claim 10
Dependent Claim 33 words
The material of claim 7, said silver salt or silver complex is to be dissolved in water at 25° C. in an amount of not less than 1 g per litter of water.
Claim 11
Dependent Claim 33 words
The material of claim 9, said silver salt or silver complex is to be dissolved in water at 25° C. in an amount of not less than 3 g per litter of water.
Claim 12
Dependent Claim 35 words
The material of claim 7, wherein said silver salt is silver nitrite, silver nitrate, silver chlorate, silver perchlorate, silver sulfate, silver acetate, silver caproate, silver propionate, silver butyrate, silver valerate, silver isovalerate or silver α-naphtoate.
Claim 13
Dependent Claim 37 words
The material of claim 7, wherein an amount of said water-soluble silver salt added to said silver halide emulsion layer is within the range of from 5×10 -5 mol to 0.3 mol per mol of silver halide.
Claim 14
Dependent Claim 37 words
The material of claim 12, wherein an amount of said water-soluble silver salt added to said silver halide emulsion layer is within the range of from 1×10 -4 mol to 0.1 mol per mol of silver halide.
Claim 15
Dependent Claim 27 words
The material of claim 1, wherein said silver halide emulsion layer comprises silver haide grains having a silver chloride content of not less than 80 mol %.
Claim 16
Dependent Claim 22 words
The material of claim 14, wherein said silver halide grains have a silver bromide content of not more than 10 mol %.
Claim 17
Dependent Claim 31 words
The material of claim 15, wherein said silver halide grains are a silver chlorobromide emulsion having a silver bromide content of from 0 to 5 mol % or a silver chloride.

References Cited (Backward Citations)

US4469783A Cited
US4548899A Cited
US4695533A Cited
US4705747A Cited
US4746603A Cited
US4791052A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-09-18 1993-03-20 1993-09-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-09-18 1997-03-20 1997-09-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-09-18 2001-03-20 2001-09-19 $7700.00 Window Closed / Lapsed

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